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chemistry, organic (44) 44
diastereoselective syntheses, enantioselective syntheses (37) 37
chemistry, multidisciplinary (28) 28
catalysis (27) 27
chemistry (26) 26
organic chemistry (24) 24
metallurgy (21) 21
apparatus therefor (19) 19
general methods of organic chemistry (19) 19
palladium (18) 18
catalysis, phase‐transfer catalysis (15) 15
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asymmetric catalysis (14) 14
c‐c bond formation (14) 14
ligands (14) 14
index medicus (13) 13
tropos (13) 13
alcohols (12) 12
activation (11) 11
chirality (11) 11
copper (11) 11
pd catalyst (11) 11
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enantiomers (10) 10
resolution (10) 10
chemical tests and reagents (9) 9
fluorine (9) 9
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ketones (8) 8
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ene reaction (7) 7
esters (7) 7
nucleophilic trifluoromethylation (7) 7
synthesis (7) 7
aldehydes (6) 6
alkylation (6) 6
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bearing (6) 6
chemical or physical processes, e.g. catalysis or colloidchemistry (6) 6
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ene reactions (6) 6
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physical or chemical processes or apparatus in general (6) 6
pyrrole derivatives (6) 6
their relevant apparatus (6) 6
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trifluoromethylation (6) 6
addition reactions (5) 5
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arenes (5) 5
asymmetric-synthesis (5) 5
chemical properties (5) 5
copper-mediated difluoromethylation (5) 5
cycloaddition reactions (5) 5
dicationic palladium complexes (5) 5
diels-alder reaction (5) 5
difluoromethylation (5) 5
efficient precursor (5) 5
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glyoxylate (5) 5
hydroxycarboxylic acids (5) 5
hydroxycarboxylic acids and esters (5) 5
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organic chemistry, review (5) 5
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centers (4) 4
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epoxidation (4) 4
fluorides (4) 4
fluoroform (4) 4
gold (4) 4
halogenated carboxylic acids and esters (4) 4
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kinetic resolution (4) 4
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European Journal of Organic Chemistry, ISSN 1434-193X, 07/2016, Volume 2016, Issue 19, pp. 3166 - 3170
The catalytic hydrocarboxylation of styrenes derivatives and α,β‐unsaturated carbonyl compounds with CO2 (101.3 kPa) in the presence of an air‐stable rhodium... 
Hydrides | Carboxylic acids | Hydrocarboxylation | Rhodium | Asymmetric catalysis | TRANSFORMATION | FUNCTIONALIZED ORGANOZINC REAGENTS | ACIDS | CO2 | REACTIVITY | CHEMISTRY, ORGANIC | ALDEHYDES | ALKYNES | REDUCTIVE ALDOL REACTION | DIRECT CARBOXYLATION | DERIVATIVES | Bisphenol-A | Chemical tests and reagents | Analysis | Olefins | Carbon dioxide
Journal Article
Organic Letters, ISSN 1523-7060, 12/2010, Volume 12, Issue 24, pp. 5716 - 5719
Journal Article
Beilstein Journal of Organic Chemistry, ISSN 1860-5397, 12/2015, Volume 11, Issue 1, pp. 2661 - 2670
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 10/2012, Volume 48, Issue 90, pp. 11050 - 11069
All enantiopure atropisomeric (atropos) ligands essentially require enantiomeric resolution or synthetic transformation from a chiral pool. In sharp contrast,... 
Asymmetry | Catalysts | Chirality | Ligands | Transformations | Catalysis | Enantiomers | Bearing
Journal Article
Organic Letters, ISSN 1523-7060, 08/2016, Volume 18, Issue 15, pp. 3686 - 3689
The combination of difluoroiodomethane and zinc dust or diethylzinc can readily lead to (difluoromethyl)zinc reagents. Therefore, the first copper-catalyzed... 
HALIDES | PERFLUOROALKYL | MEDIATED DIFLUOROMETHYLATION | TRIFLUOROMETHYL | ACIDS | CHEMISTRY, ORGANIC | BROMIDES
Journal Article
Organic Letters, ISSN 1523-7060, 08/2016, Volume 18, Issue 15, pp. 3690 - 3693
The palladium-catalyzed Negishi cross-coupling reaction of aryl iodides and bromides with (difluoromethyl)zinc reagent bearing a diamine such as TMEDA is... 
IODIDES | PERFLUOROALKYL | DIFLUOROCARBENE | COPPER-MEDIATED DIFLUOROMETHYLATION | CONSTRUCTION | CHEMISTRY, ORGANIC | SYNTHETIC APPLICATION | CENTERS | BROMIDES
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 12/2015, Volume 21, Issue 49, p. 17565
A chiral dicationic palladium complex is found to be an efficient Lewis acid catalyst for the synthesis of [alpha]-fluoromethyl-substituted tertiary alcohols... 
Palladium catalysts | Palladium | Alcohols
Journal Article
Beilstein Journal of Organic Chemistry, ISSN 1860-5397, 03/2018, Volume 14, Issue 1, pp. 576 - 582
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2012, Volume 48, Issue 9, pp. 115 - 1169
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 08/2016, Volume 2016, Issue 23, pp. 4099 - 4104
Journal Article
Organic Letters, ISSN 1523-7060, 10/2015, Volume 17, Issue 19, pp. 4882 - 4885
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 03/2014, Volume 20, Issue 10, pp. 2750 - 2754
Journal Article
Organic Letters, ISSN 1523-7060, 10/2015, Volume 17, Issue 20, pp. 4996 - 4999
The trifluoromethylation of carbonyl compounds is accomplished by the stable (trifluoromethyl)zinc reagent generated and then isolated from CF3I and ZnEt2,... 
NUCLEOPHILIC TRIFLUOROMETHYLATION | EFFICIENT PRECURSOR | ORGANIC-SYNTHESIS | CROSS-COUPLING REACTIONS | ENANTIOSELECTIVE TRIFLUOROMETHYLATION | GEM-DIFLUOROOLEFINATION | CATALYZED TRIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | FUNCTIONAL-GROUPS | SYNTHETIC APPLICATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2009, Volume 48, Issue 33, pp. 6073 - 6077
The axial chirality of tropos gold–biphep (biphep=bis(phosphanyl)biphenyl) complexes, which is controlled by a chiral anion such as (S)‐2 (=X*−), is imprinted... 
gold | chiral auxiliaries | intramolecular hydroamination | atropisomerism | Intramolecular hydroamination | Gold | Atropisomerism | Chiral auxiliaries | ACTIVATION | HYDROGENATION | RESOLUTION | LEWIS-ACID CATALYSIS | BIPHENYLPHOSPHINE BIPHEP LIGAND | CHEMISTRY, MULTIDISCIPLINARY | CYCLOADDITION | AMPLIFICATION | TROPOS | PD CATALYST
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2012, Volume 134, Issue 25, pp. 10329 - 10332
A highly stereoselective catalytic alkylation sequence for the synthesis of highly functionalized and versatile five-membered-ring compounds bearing all-carbon... 
CATALYTIC ENANTIOSELECTIVE CONSTRUCTION | SUBSTITUTION | REAGENTS | STEREOSELECTIVE CONSTRUCTION | IMPROVEMENT | MADINDOLINE | CENTERS | CHEMISTRY, MULTIDISCIPLINARY | CONJUGATE ADDITION | Cyclic hydrocarbons | Analysis | Chemical bonds | Catalysis | Chemical properties | Copper | Alkylation
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 10/2015, Volume 17, Issue 19, pp. 4882 - 4885
Difluoromethylation on sp(3) carbon of various nitrile compounds with lithium base and fluoroform (CF3H), which is an ideal difluoromethylating reagent, is... 
NUCLEOPHILIC TRIFLUOROMETHYLATION | EFFICIENT PRECURSOR | ACTIVATION | DIFLUOROCARBENE | IMINES | COPPER-MEDIATED DIFLUOROMETHYLATION | CONSTRUCTION | CHEMISTRY, ORGANIC | ARYL | ALDEHYDES
Journal Article
European Radiology, ISSN 0938-7994, 10/2017, Volume 27, Issue 10, pp. 4054 - 4063
Journal Article