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catalysis (11) 11
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Journal Article
Current Topics in Medicinal Chemistry, ISSN 1568-0266, 2014, Volume 14, Issue 7, pp. 966 - 978
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 08/2015, Volume 80, Issue 16, pp. 8449 - 8457
Journal Article
Synlett, ISSN 0936-5214, 12/2016, Volume 27, Issue 20, pp. 2747 - 2755
Journal Article
ChemCatChem, ISSN 1867-3880, 01/2019, Volume 11, Issue 1, pp. 324 - 332
Chiral metal complexes catalyze enantioselective carbonyl propargylation via reductive coupling or as hydrogen auto‐transfer processes, in which reactant... 
Hydrogen transfer | Propargylation | Ruthenium | Enantioselective | Rhodium | Dehydrogenation | Iridium | ACID | C BOND FORMATION | CHEMISTRY, PHYSICAL | CONJUGATED ALKYNES | ALDEHYDES | ASYMMETRIC PROPARGYLATION | KETONES | HOMOPROPARGYLIC ALCOHOLS | 1,3-ENYNES | STEREOSELECTIVE-SYNTHESIS | ruthenium | dehydrogenation | hydrogen transfer | rhodium | enantioselective
Journal Article
SCIENCE, ISSN 0036-8075, 08/2017, Volume 357, Issue 6353, pp. 779 - 781
Journal Article
Organic Letters, ISSN 1523-7060, 11/2013, Volume 15, Issue 21, pp. 5578 - 5581
The development of new synthetic fluorination reactions has important implications in medicinal, agricultural, and materials chemistries. Given the prevalence... 
NUCLEOPHILIC TRIFLUOROMETHYLATION | CHLORODIFLUOROACETATE | ACID | ANALOGS | DIFLUOROCARBENE PRECURSORS | ARYL HALIDES | CHEMISTRY, ORGANIC | ORGANIC HALIDES | GENERATION | FLUORINATION | DERIVATIVES | Propanols - chemistry | Copper - chemistry | Stereoisomerism | Acetates - chemistry | Hydrocarbons, Fluorinated - chemistry | Molecular Structure | Catalysis | Methylation
Journal Article
Synthesis, ISSN 0039-7881, 07/2014, Volume 46, Issue 14, pp. 1938 - 1946
Abstract The development of efficient methods for accessing fluo­rinated functional groups is desirable. Herein, we report a two-step method that utilizes... 
special topic | catalysis | copper | trifluoromethylation | decarboxylation | alkynes | NUCLEOPHILIC TRIFLUOROMETHYLATION | REAGENT | SYSTEM | MEDIATED TRIFLUOROMETHYLATION | CHEMISTRY, ORGANIC | TRIFLUOROACETATE | HETEROAROMATIC-COMPOUNDS | BROMIDES | ARYL HALIDES | BOND | FLUOROFORM
Journal Article
Organic Letters, ISSN 1523-7060, 05/2015, Volume 17, Issue 10, pp. 2506 - 2509
Journal Article
Organic letters, ISSN 1523-7060, 5/2015, Volume 17, Issue 10, pp. 2506 - 2509
“Cu–CF 3 ” species have been used historically for a broad spectrum of nucleophilic trifluoromethylation reactions. Although recent advancements have employed... 
Journal Article
The Journal of organic chemistry, ISSN 0022-3263, 02/2019, Volume 84, Issue 4, pp. 2061 - 2071
A new bench-stable trifluoromethylation reagent, phenyl bromodifluoroacetate, converts readily available alcohols to trifluoromethanes in a Cu-catalyzed... 
CHEMISTRY, ORGANIC | ORGANIC HALIDES | FLUORINATION | DECARBOXYLATIVE TRIFLUOROMETHYLATION | DIFLUOROCARBENE | TEBUFENPYRAD ANALOGS
Journal Article
Science (New York, N.Y.), ISSN 0036-8075, 8/2017, Volume 357, Issue 6353, pp. 779 - 781
Current catalytic processes involving C-C bond activation rely on π-unsaturated coupling partners. Exploiting the concept of transfer hydrogenative coupling,... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2018, Volume 140, Issue 12, pp. 4372 - 4379
Heme-based tryptophan dioxygenases are established immunosuppressive metalloproteins with significant biomedical interest. Here, we synthesized two mechanistic... 
OXIDATION | ACTIVATION | ENZYME | SPECTROSCOPY | KYNURENINE PATHWAY | REACTION-MECHANISM | BIOSYNTHESIS | INDOLEAMINE 2,3-DIOXYGENASE | SUPERFAMILY | N-FORMYLKYNURENINE | CHEMISTRY, MULTIDISCIPLINARY | Tryptophan | Chemical properties | Catalysis | Analysis | Amino compounds
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2017, Volume 82, Issue 24, pp. 13751 - 13755
Benzocyclobutenones 1a–1g undergo cycloreversion at 150 °C in m-xylene solvent to form transient α-oxo-ortho-quinodimethanes or “ortho-quinoid ketene... 
FUNCTIONALIZATION | ORTHO-QUINONE METHIDE | ENANTIOSELECTIVE SYNTHESIS | ENONES | CHEMISTRY | CHEMISTRY, ORGANIC | ORTHO-QUINODIMETHANE | CARBONYL-COMPOUNDS | REGIOSELECTIVITY | O-QUINODIMETHANES | SPIROOXINDOLES
Journal Article
Current topics in medicinal chemistry, 2014, Volume 14, Issue 7, p. 966
Fluorinated organic compounds have a long history in medicinal chemistry, and synthetic methods to access target fluorinated compounds are undergoing a... 
Animals | Carboxylic Acids - chemistry | Decarboxylation | Humans | Halogenation | Hydrocarbons, Fluorinated - chemistry | Chemistry, Pharmaceutical
Journal Article
The Journal of organic chemistry, ISSN 0022-3263, 03/2020
We report the conversion of aryl methyl ethers and phenols into six fluoroalkyl analogues through late-stage functionalization of a natural product-derived... 
Journal Article
eBook
ChemInform, ISSN 0931-7597, 12/2015, Volume 47, Issue 3, pp. no - no
The use of KI and DMF/MeCN as solvent mixture enables the efficient Cu‐catalyzed decarboxylative trifluoromethylation of benzylic bromodifluoroacetates. 
catalysis, phase‐transfer catalysis | halogen compounds (benzene compounds) | C‐C bond formation | Copper | Catalysis
Journal Article
ChemInform, ISSN 0931-7597, 09/2015, Volume 46, Issue 38, pp. no - no
The ability of bipyridyl‐derived ligands to control the regioselectivity of Cu‐catalyzed nucleophilic trifluoromethylation reactions of propargyl electrophiles... 
allenes (benzene compounds) | catalysis, phase‐transfer catalysis | C‐C bond formation | Copper | Catalysis
Journal Article
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