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Journal of the American Chemical Society, ISSN 0002-7863, 11/2008, Volume 130, Issue 47, pp. 15982 - 15989
A rhodium-catalyzed silylation reaction of carbon−cyano bonds using disilane has been developed. Under these catalytic conditions, carbon−cyano bonds in aryl,... 
CARBONYLATIVE 2+2 CYCLOADDITION | ORGANIC-MOLECULES | TRANSITION-METAL-COMPLEXES | CYCLIZATION REACTIONS | C-C BOND | ARYL HALIDES | SUBSTITUTED BENZOYLTRIMETHYLSILANES | BENZOYL CHLORIDES | H SILYLATION | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemical reviews, ISSN 0009-2665, 01/2020
During the past decades, synthetic organic chemistry discovered that directing group assisted C-H activation is a key tool for the expedient and siteselective... 
Journal Article
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, ISSN 0037-9980, 2015, Volume 73, Issue 9, pp. 923 - 924
Journal Article
ISSN 1359-7345, 8/2019, Volume 55, Issue 67, pp. 9983 - 9986
The reaction of ortho -methyl-substituted aromatic amides with maleimides in the presence of Pd(OAc) 2 and AgOAc results in C-H alkylation at the ortho -methyl... 
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2019, Volume 55, Issue 67, pp. 9983 - 9986
The reaction of ortho-methyl-substituted aromatic amides with maleimides in the presence of Pd(OAc)2 and AgOAc results in C–H alkylation at the ortho-methyl... 
Substitutes | Hydrogen bonds | Amides | Alkylation
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2011, Volume 133, Issue 33, pp. 12984 - 12986
The first catalytic alkynylation of unactivated C(sp3)–H bonds has been accomplished. The method allows for the straightforward introduction of an ethynyl... 
FUNCTIONALIZATION | ACTIVATION | GACL3-CATALYZED ORTHO-ETHYNYLATION | COUPLING REACTIONS | ARYLATION | TERMINAL ALKYNES | COPPER | CARBON-HYDROGEN BONDS | DIRECT ALKYNYLATION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | Alkynes - chemistry | Catalysis | Palladium - chemistry | Carboxylic Acids - chemistry
Journal Article
Chemical Science, ISSN 2041-6520, 9/2017, Volume 8, Issue 9, pp. 6650 - 6655
We report the development of a new system for C–H functionalizations catalyzed by nickel complexes. The findings show that aromatic amides with a simple... 
Chemistry
Journal Article
ISSN 2041-6520, 8/2017, Volume 8, Issue 9, pp. 665 - 6655
The Ni-catalyzed reaction of aromatic amides with alkynes in the presence of KOBu t involves C-H/N-H oxidative annulation to give 1(2 H )-isoquinolinones. A... 
Journal Article
Organic Letters, ISSN 1523-7060, 01/2012, Volume 14, Issue 1, pp. 354 - 357
The palladium-catalyzed direct alkynylation of C–H bonds in aromatic carboxylic acid derivatives is described. The use of 8-aminoquinoline as a directing group... 
UNACTIVATED C(SP)-H BONDS | ACTIVATION | GACL3-CATALYZED ORTHO-ETHYNYLATION | COUPLING REACTIONS | ARYLATION | SONOGASHIRA REACTION | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | COPPER | CARBON-HYDROGEN BONDS | C-H BONDS
Journal Article
Organic Letters, ISSN 1523-7060, 08/2009, Volume 11, Issue 15, pp. 3250 - 3252
Palladium-catalyzed ortho-alkynylation of aromatic C−H bonds in anilides is described. Preliminary mechanistic studies reveal that electrophilic palladation is... 
FUNCTIONALIZATION | ACETANILIDES | ACTIVATION | GACL3-CATALYZED ORTHO-ETHYNYLATION | DIRECT ARYLATION | TRIISOPROPYLSILYLACETYLENE | CHEMISTRY, ORGANIC | CARBON-HYDROGEN BONDS | ALKYNES | HETEROAROMATIC-COMPOUNDS | INDOLES
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2019, Volume 55, Issue 90, pp. 13610 - 13613
The nickel-catalyzed reductive cleavage of esters in the absence of an external reductant, which involves the cleavage of an inert acyl C–O bond in O-alkyl... 
Esters | Amides | Cleavage | Nickel | Rings (mathematics)
Journal Article
ISSN 2041-6520, 3/2019, Volume 1, Issue 11, pp. 3242 - 3248
The reaction of N-heteroaromatic compounds, such as 2-aryl-pyrrole, benzimidazole, imidazole, indole, and pyrazole derivatives, with alkynes in the presence of... 
Journal Article
Chemical Science, ISSN 2041-6520, 01/2019, Volume 10, Issue 11, pp. 3242 - 3248
The reaction of N-heteroaromatic compounds, such as 2-aryl-pyrrole, benzimidazole, imidazole, indole, and pyrazole derivatives, with alkynes in the presence of... 
Organic chemistry | Heterocyclic compounds | Aromatic compounds | Imidazole | Chemical reactions | Catalytic activity | Nickel | Catalysis | Crystallography | Pyrazole | Functional groups | Alkynes
Journal Article
Chemical science, ISSN 2041-6520, 09/2017, Volume 8, Issue 9, pp. 6650 - 6655
The Ni-catalyzed reaction of aromatic amides with alkynes in the presence of KOBu involves C-H/N-H oxidative annulation to give 1(2 )-isoquinolinones. A key to... 
Journal Article
Chemical Science, ISSN 2041-6520, 2017, Volume 8, Issue 9, pp. 6650 - 6655
The Ni-catalyzed reaction of aromatic amides with alkynes in the presence of KOBut involves C-H/N-H oxidative annulation to give 1(2H)-isoquinolinones. A key... 
DIRECTING GROUPS | ALIPHATIC AMIDES | FUNCTIONALIZATION | UNACTIVATED C(SP)-H BONDS | C(SP)-H BONDS | ACTIVATION | TOLUENE DERIVATIVES | DIRECT ARYLATION | BIDENTATE | DECARBONYLATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2019, Volume 25, Issue 28, pp. 6915 - 6919
The alkylation of C−H bonds (hydroarylation) in aromatic amides with non‐activated 1‐alkenes using a rhodium catalyst and assisted by an 8‐aminoquinoline... 
carbenes | quinolinamide | C−H activation | non-activated alkenes | rhodium | ACTIVATION | COMPLEX | CRYSTAL-STRUCTURE | IMINES | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES | FUNCTIONALIZATION | MILD | C-H activation | BIDENTATE | RING | HYDROARYLATION | Rhodium | Amides | Olefins | Deuterium | Alkenes | Carboxylic acids | Alkylation | Intermediates
Journal Article
by He, QY and Ano, Y and Chatani, N
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 08/2019, Volume 55, Issue 67, pp. 9983 - 9986
The reaction of ortho-methyl-substituted aromatic amides with maleimides in the presence of Pd(OAc)(2) and AgOAc results in C-H alkylation at the ortho-methyl... 
DISELENIDES | AMINATION | CHALCOGENATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Synlett, ISSN 0936-5214, 12/2012, Volume 23, Issue 19, pp. 2763 - 2767
Abstract The ruthenium-catalyzed direct alkynylation of arenes with the chelation assistance of nitrogen-containing heterocycles including pyridine,... 
cluster | ruthenium | alkyne | C-H activation | chelation | heteroarene | HALIDES | ACTIVATION | C-H BOND | GACL3-CATALYZED ORTHO-ETHYNYLATION | COMPLEXES | DIRECT ORTHO ARYLATION | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | COPPER | CARBON-HYDROGEN BONDS | CLEAVAGE
Journal Article
Chemistry Letters, ISSN 0366-7022, 7/2019, Volume 48, Issue 7, pp. 726 - 729
To obtain enantioenriched chiral organic molecules, numerous optical resolution and asymmetric synthetic methods have been developed to date. Herein, we... 
Static chiral molecule | RECOGNITION | DERACEMIZATION | Dynamic asymmetric induction | Dynamic chiral molecule | CHROMATOGRAPHIC RESOLUTION | DERIVATIVES | CELLULOSE | CHEMISTRY, MULTIDISCIPLINARY | HPLC | Asymmetry | Organic chemistry
Journal Article
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