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Science, ISSN 0036-8075, 03/2018, Volume 359, Issue 6379, pp. 1016 - 1021
Intramolecular insertion of metal nitrenes into carbon-hydrogen bonds to form gamma-lactam rings has traditionally been hindered bycompeting isocyanate... 
OXIDATION | ALKENES | AMIDO TRANSFER | AMINES | BOND AMINATION | MULTIDISCIPLINARY SCIENCES | PORPHYRINS | COMPLEXES | RUTHENIUM | ARYL AZIDES | AMINATION REACTIONS | Catalysts | Migration | Insertion | Amino acids | Amides | Carboxylic acids | Nitrogen | Hydrogen bonding | Hydrogen bonds | Chemical bonds | Density functional theory | Iridium | Catalysis | Carbonyls | Organic compounds
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2006, Volume 128, Issue 23, pp. 7476 - 7485
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2016, Volume 138, Issue 42, pp. 14020 - 14029
The mechanism of the Ir­(III)- and Rh­(III)-mediated C–N coupling reaction, which is the key step for catalytic C–H amidation, was investigated in an... 
ROOM-TEMPERATURE | SULFONYL AZIDES | NITROGEN-SOURCE | SANDWICH IRIDIUM COMPLEX | OXYGEN-ATOM TRANSFER | NITRENE TRANSFER-REACTIONS | CARBON-HYDROGEN BONDS | DISSOCIATIVE MECHANISM | CHEMISTRY, MULTIDISCIPLINARY | C-H AMINATION | N-HETEROCYCLES | Azoles (Class of compounds) | Stoichiometry | Usage | Amides | Chemical reactions | Research | Chemical properties
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2018, Volume 57, Issue 47, pp. 15517 - 15522
Metal‐free, visible‐light‐induced site‐selective heteroarylation of remote C(sp3)−H bonds has been accomplished through the design of N‐alkoxyheteroarenium... 
reaction mechanisms | C−H activation | radicals | heterocycles | photochemistry | ACTIVATION | ALKYLATION | PHOTOCATALYZED SYNTHESIS | HYDROGEN-ATOM | FRAGMENTATION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | PHOTOREDOX CATALYSIS | FUNCTIONALIZATION | QUINOLINONES | C-H activation | METAL-FREE | Translocation | Salts | Substrates
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2008, Volume 130, Issue 48, pp. 16231 - 16240
The resting state of the recently reported water oxidation catalyst [tpyRu(II)−OH2]2L3+ (tpy = terpyridine; L = bipyridylpyrazolylic anion) ([2,2] 3+ ) must be... 
Journal Article
Nature Chemistry, ISSN 1755-4330, 02/2018, Volume 10, Issue 2, pp. 218 - 224
Direct arylation of C-H bonds is in principle a powerful way of preparing value-added molecules that contain carbon-aryl fragments. Unfortunately, currently... 
MILD | ACTIVATION | CROSS-COUPLING REACTION | MECHANISM | TRANSMETALATION | COMPLEXES | ARYL SILANES | SALTS | ARYLSILANES | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS | Coupling (molecular) | Cross coupling | Aromatic compounds | Chemical bonds | Chemical reactions | Density functional theory | Oxidation | Catalysis | Iridium | Substrates | Intermediates | Carbon | Room temperature
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2019, Volume 25, Issue 40, p. n/a
A new method for tri‐functionalizing allenes was successfully developed based on diborylation/cyanation with bis(pinacolato)diboron (B2pin2) and... 
copper catalysis | cyanation | selectivities | trifunctionalization | borylation | density functional theory | Density functionals | Copper | Stereoselectivity | Chemical reactions | Catalysis
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2015, Volume 21, Issue 4, pp. 1780 - 1789
The mechanism of the nitrene‐group transfer reaction from an organic azide to isonitrile catalyzed by a ZrIV d0 complex carrying a redox‐active ligand was... 
quantum chemistry | density functional calculations | zirconium | charge transfer | Zirconium | Density functional calculations | Quantum chemistry | Charge transfer | Chemical tests and reagents | Nitrogen | Analysis | Ligands
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2018, Volume 57, Issue 21, pp. 6242 - 6246
Journal Article
Science, ISSN 0036-8075, 03/2016, Volume 351, Issue 6280, pp. 1424 - 1427
Despite steady progress in catalytic methods for the borylation of hydrocarbons, methane has not yet been subject to this transformation. Here we report the... 
FUNCTIONALIZATION | ACTIVATION | HYDROCARBONS | CONVERSION | MULTIDISCIPLINARY SCIENCES | ORGANOMETALLIC CHEMISTRY | COMPLEXES | ACETIC-ACID | C-H BONDS | CH4 | FRONTIER | Methane | Catalysis | Properties | Methods | Cyclohexane | Chemical reactions | Catalysts
Journal Article
ChemSusChem, ISSN 1864-5631, 03/2015, Volume 8, Issue 5, pp. 844 - 852
The mechanism of water oxidation performed by a recently discovered cobalt complex [Co(Py5)(OH2)](ClO4)2 (1;... 
cobalt | solar fuels | water oxidation | photocatalysis | density functional theory
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2019, Volume 58, Issue 6, pp. 1727 - 1731
The direct, catalytic substitution of unactivated alcohols remains an undeveloped area of organic synthesis. Moreover, catalytic activation of this difficult... 
indoline | iron | sulfonamides | asymmetric synthesis | alcohol substitution | SOLVOLYSIS | OXIDATION-REDUCTION | ALKYLATION | STEREOCHEMISTRY | NUCLEOPHILIC-SUBSTITUTION REACTIONS | HYDROAMINATION | CHEMISTRY, MULTIDISCIPLINARY | ASYMMETRIC HYDROGENATION | Heterocyclic compounds | Sulfonamides | Alcohol | Iron | Catalysis | Chemical synthesis | Alcohols | Direct conversion
Journal Article
by Moon, Y and Park, B and Kim, I and Kang, G and Shin, S and Kang, D and Baik, MH and Hong, S
NATURE COMMUNICATIONS, ISSN 2041-1723, 09/2019, Volume 10, Issue 1, pp. 4117 - 9
The development of intermolecular alkene aminopyridylation has great potential for quickly increasing molecular complexity with two valuable groups. Here we... 
FUNCTIONALIZATION | QUINOLINONES | ELECTRON-TRANSFER | ALKYLATION | MULTIDISCIPLINARY SCIENCES | ARYLATION | PHOTOCATALYZED SYNTHESIS | PYRIDYLATION | CARBOAZIDATION | METAL-FREE | UNACTIVATED ALKENES | Pyridines | Salts | Transformation | Alkenes | Regioselectivity | Photocatalysis | Pyridinium | Nitrogen | Electrostatic properties | Amino radical | Substrates | Complexity | Reagents | Functional groups
Journal Article