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Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 48, pp. 15896 - 15901
Sterically unencumbered diborenes based on a benzylphosphine chelate undergo diboration reactions with bis(catecholato)diboron in the absence of a catalyst to... 
low-valent compounds | chain structures | diboration | isomers | boron | HYDROBORATION | TETRACHLORIDE | REACTIVITY | DIBORON COMPOUNDS | BORANE | CHEMISTRY, MULTIDISCIPLINARY | BORATION | BONDS | CHEMISTRY | Phosphine | Chelates
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 37, pp. 11263 - 11267
Deprotonation of [(cAAC)BH2(CN)] provided clean access to the stable boryl anion, [(cAAC)BH(CN)]−. Whereas the addition of soft electrophiles occurred at the... 
borylenes | boryl anions | Group 14 elements | ambiphilic reactivity | umpolung | NUCLEOPHILIC BORON | DEPROTONATION | SUBSTITUTION | COMPLEXES | REACTIVITY | CRYSTAL | ADDUCT | CHEMISTRY, MULTIDISCIPLINARY | CARBENES | CHEMISTRY | DIBORON | Animal behavior | Nitriles | Boron
Journal Article
Chemistry : a European journal, ISSN 1521-3765, 2019, Volume 25, Issue 32, pp. 7679 - 7688
The stability of tetracationic triarylboranes in dilute aqueous solution was investigated by tuning the steric demand of the linker in a... 
boranes | luminescence | fluorescence | boron | imaging | Anthracene | Stability | Aqueous solutions | Lysosomes | Fluorescence | Chromophores | Conjugation | Optimization
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2019, Volume 58, Issue 29, pp. 9782 - 9786
The transfer hydrogenation of N‐heterocyclic carbene (NHC)‐supported diborenes with dimethylamine borane proceeds with high selectivity for the... 
amine borane dehydrocoupling | transfer hydrogenation | DFT mechanism | diboranes | diborene | HYDROBORATION | AMMONIA-BORANE | CHEMISTRY, MULTIDISCIPLINARY | Hydrogenation | Boron | Selectivity | Deuteration | Reaction mechanisms
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2017, Volume 23, Issue 50, pp. 12387 - 12398
The synthesis of mono‐NHC alane adducts of the type (NHC)⋅AlH3 (NHC=Me2Im (1), Me2ImMe (2), iPr2Im (3 and [D3]‐3), iPr2ImMe (4), Dipp2Im (10);... 
carbenes | alanes | aluminum | Al−H activation | ring expansion | ROOM-TEMPERATURE | X-RAY CRYSTALLOGRAPHY | COMPLEXES | DIBORON COMPOUNDS | DFT CALCULATIONS | CHEMISTRY, MULTIDISCIPLINARY | Al-H activation | TERTIARY PHOSPHINE ADDUCTS | LIGAND | B-H | C-H | Aluminum compounds | Heterocyclic compounds | Hydrogen bonds | Carbenes | Expansion | Dipping | Ring opening | Adducts
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 05/2015, Volume 21, Issue 19, pp. 7082 - 7098
Lewis base adducts of tetra‐alkoxy diboron compounds, in particular bis(pinacolato)diboron (B2pin2), have been proposed as the active source of nucleophilic... 
metal‐free borylation | cross‐coupling | boron | Lewis bases | boronic acids | metal-free borylation | cross-coupling | Diazo compounds | Nuclear magnetic resonance spectroscopy | Surface active agents | Chemical tests and reagents | Analysis | Spectrum analysis | Nuclear magnetic resonance--NMR
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2014, Volume 53, Issue 21, pp. 5453 - 5457
Despite the synthesis of a boryl anion by Yamashita et al. in 2006, compounds that show boron‐centered nucleophilicity are still rare and sought‐after... 
radicals | anions | boron | Lewis bases | boroles | REDUCTION | FORM | NUCLEAR-MAGNETIC-RESONANCE | COMPLEXES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | Substitution reactions | Electron transport | Analysis | Boron | Spectroscopy | Anions | Synthesis | Iodides | Halides | X-rays | Crystallography | Radicals
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 04/2016, Volume 52, Issue 28, pp. 5019 - 5022
Structural characterization of unsupported, two metal centres bridging methyl groups is rare. They have been proposed as transmetalation intermediates in... 
Journal Article
ISSN 1359-7345, 11/2016, Volume 52, Issue 9, pp. 13249 - 13252
The reaction of the vicinal biscarbenoid Pip-C&z.tbd;C-Pip with dimethyltin dichloride yields a unique tetraamino-substituted cyclobutadienyl system featuring... 
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2015, Volume 54, Issue 44, pp. 13090 - 13094
Cation–π interactions are one of the most important classes of noncovalent bonding, and are seen throughout biology, chemistry, and materials science. However,... 
lithium | sodium | boron | cation–π interactions | alkali metals | cation-π interactions
Journal Article