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Organic Letters, ISSN 1523-7060, 10/2015, Volume 17, Issue 19, pp. 4658 - 4661
A 1,4-addition with the nucleophilic center generated at the ortho carbon atom of an aromatic ketone in the presence of the highly reactive α-C–H bond, using a... 
CATALYZED ASYMMETRIC 1,4-ADDITION | FUNCTIONALIZATION | ALKENES | CARBON | MECHANISM | ACIDS | SCOPE | METHYLENECYCLOPROPANES | CHEMISTRY, ORGANIC | HYDROARYLATION | CONJUGATE ADDITION
Journal Article
Organic Letters, ISSN 1523-7060, 11/2016, Volume 18, Issue 21, pp. 5496 - 5499
A novel mode of achieving site selectivity between C-2 and C-4 positions in the indole framework by altering the property of the ketone directing group is... 
DIRECT C2-OLEFINATION | OLEFINATION | O BOND | GROUP STRATEGY | BOND FUNCTIONALIZATION | REGIOSELECTIVE SYNTHESIS | ERGOT ALKALOIDS | ACTIVATION/CYCLIZATION | CHEMISTRY, ORGANIC | PYRROLES | C-H ACTIVATION
Journal Article
Organic Letters, ISSN 1523-7060, 10/2015, Volume 17, Issue 19, pp. 4662 - 4665
Synthesis of 3-(indol-2-yl)­succinimide derivatives is presented using a directing group strategy. Selective functionalization of C-2 in the presence of highly... 
DIRECTING GROUP | FUNCTIONALIZATION | ALKENES | DIRECT C2-OLEFINATION | ATOM ECONOMY | RING-OPENING REACTIONS | REGIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | BOND ACTIVATION | DERIVATIVES | ORTHO-ALKENYLATION
Journal Article
Chemical Communications: Chem Comm, ISSN 1359-7345, 06/2017, Volume 53, Issue 46, pp. 6251 - 6254
A Rh(iii)-catalyzed C-H activation followed by conjugate addition to maleimides, using carboxylic acid as a traceless/deciduous directing group, to formally... 
Conjugates | Aromatic compounds | Acrylic acid | Chemical bonds | Activation | Derivatives | Carboxylic acids | Nucleophiles
Journal Article
Chemical Communications, ISSN 1359-7345, 2017, Volume 53, Issue 46, pp. 6251 - 6254
A Rh( III)-catalyzed C-H activation followed by conjugate addition to maleimides, using carboxylic acid as a traceless/deciduous directing group, to formally... 
FUNCTIONALIZATION | PALLADIUM | CATALYZED VINYLATION | C-H BOND | ARYLATION | 1,4-ADDITION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | HYDROARYLATION | BENZOIC-ACIDS | CARBOXYLIC-ACIDS
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 07/2016, Volume 81, Issue 14, pp. 6056 - 6065
Maleimide has been used as a selective coupling partner to generate conjugate addition products exclusively. The typical Heck-type oxidative coupling that... 
RUTHENIUM-CATALYZED HYDROARYLATION | FUNCTIONALIZATION | CHEMICAL-REACTIONS | ORGANIC-SYNTHESIS | BENZAMIDES | SCOPE | ASSISTANCE | METHYLENECYCLOPROPANES | CHEMISTRY, ORGANIC | OLEFINS | CLEAVAGE | Chemical bonds | Usage | Ruthenium | Chemical properties | Catalysis
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 02/2018, Volume 83, Issue 4, pp. 1810 - 1818
A double C–H activation and double insertion process to achieve the synthesis benzo­[e]­indole frameworks has been disclosed. This type of benzannulation is... 
FUNCTIONALIZATION | CATALYZED REACTIONS | MALEIMIDES | ACETYLENE | ERGOT ALKALOIDS | CHEMISTRY | CHEMISTRY, ORGANIC | BOND FORMATION | PHENYLAZOLES | INTERNAL ALKYNES | C-H ACTIVATION | Ring formation (Chemistry) | Chemical properties | Analysis | Indole | Benzene
Journal Article
Asian Journal of Organic Chemistry, ISSN 2193-5807, 07/2018, Volume 7, Issue 7, pp. 1338 - 1342
Maleimides are not known to undergo oxidative‐Heck reaction because they lack a syn‐periplanar β‐hydrogen atom. Herein, we report a C−H activation‐based... 
oxidative Heck reaction | Synthetic methods | directing group | RhIII-Catalyst | maleimides
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 03/2017, Volume 58, Issue 9, pp. 803 - 824
[Display omitted] •Recent advances on CDC reactions for CC bond formations.•CDC reactions are the closest to an ideal reaction that researchers have... 
C[sbnd]C bond formation | CDC | C[sbnd]HC[sbnd]H functionalization | Radical reactions | Oxidative coupling
Journal Article
Asian Journal of Organic Chemistry, ISSN 2193-5807, 07/2018, Volume 7, Issue 7, pp. 1338 - 1342
Maleimides are not known to undergo oxidative-Heck reaction because they lack a syn-periplanar beta-hydrogen atom. Herein, we report a C-H activation-based... 
oxidative Heck reaction | Synthetic methods | directing group | Catalyst | maleimides | DESIGN | ARYLATION | CHEMISTRY, ORGANIC | ALKYNES | SALTS | FREE-RADICALS | POTENT | BIOLOGICAL EVALUATION | INHIBITORS | ANHYDRIDES | Rh-III-Catalyst | UNSATURATED SYSTEMS
Journal Article
ChemInform, ISSN 0931-7597, 02/2016, Volume 47, Issue 9, pp. no - no
The scope of the title reaction is broadened towards pyrrole (IV) and maleates (VIII) as substrates. 
catalysis, phase‐transfer catalysis | indole derivatives, isoindole derivatives | pyrrole derivatives | C‐C bond formation | Thiophene | Catalysis
Journal Article
ChemInform, ISSN 0931-7597, 02/2016, Volume 47, Issue 9, pp. no - no
Maleimides add to the ortho‐position of aryl ketones to furnish regioselectively the o‐(succinimid‐3‐yl)aryl ketones in good to high yields. 
thiophene derivatives | ketones (benzene compounds) | catalysis, phase‐transfer catalysis | pyrrole derivatives | C‐C bond formation | Ketones | Thiophene | Catalysis
Journal Article
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