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Angewandte Chemie (International ed.), ISSN 1433-7851, 2015, Volume 54, Issue 1, pp. 359 - 362
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2014, Volume 53, Issue 22, pp. 5689 - 5693
The realization of a phosphine‐stabilized diborene, Et3P⋅(Mes)BB(Mes)⋅PEt3 (4), by KC8 reduction of Et3P⋅B2Mes2Br2 in benzene enabled the evaluation and... 
diborane | oxidation | radical cation | diborene | reduction | B=B DOUBLE-BOND | HETEROCYCLIC CARBENE | MOLECULE | REACTIVITY | PI-BOND | CHEMISTRY, MULTIDISCIPLINARY | REARRANGEMENT | TRIPLE-BOND | STABLE COMPOUND | CHEMISTRY | GENERATION | Oxidation-reduction reaction | Analysis | Chemical properties | Boron | Oxidation | Reduction | Electronic structure | Cationic | Cations | Lewis base | Electrode potentials | Radicals
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2014, Volume 53, Issue 28, pp. 7360 - 7363
Utilizing a cyclic (alkyl)(amino)carbene (CAAC) as a ligand, neutral CAAC‐stabilized radicals containing a boryl functionality could be prepared by reduction... 
carbenes | structure elucidation | radicals | reduction | boron | ELECTRON SIGMA-BOND | ANION | BORYL RADICALS | DIBORENES | REACTIVITY | COORDINATION | BORANES | CHEMISTRY, MULTIDISCIPLINARY | REDUCTIONS | ALKYL AMINO CARBENES | GENERATION | Reduction | Boron | Mathematical analysis | X-rays | Inert | Derivatives | Density | Radicals | Adducts
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2018, Volume 24, Issue 1, pp. 266 - 273
A series of NHC‐supported 1,2‐dithienyldiborenes was synthesized from the corresponding (dihalo)thienylborane NHC precursors. NMR and UV/Vis spectroscopic... 
spectroscopy | boron | diborenes | electron donors | N-heterocyclic carbenes | INSERTION | AB-INITIO | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | POTENTIAL CURVES | BORON MULTIPLE BONDS | CHALCOGENS | LIGANDS | BORYLENE | GENERATION | Coplanarity | Stability | Nuclear magnetic resonance--NMR | Crystallography | Destabilization | Electrons
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2015, Volume 54, Issue 14, pp. 4362 - 4366
A number of unprecedented photophysical phenomena were observed in the study of luminescent π‐diborene complexes of Cu and Ag. These observations included... 
intersystem crossing | coinage metals | fluorescence | boron | diborenes
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2013, Volume 19, Issue 40, pp. 13402 - 13407
The synthesis of base‐stabilized boryl and borylene complexes is reported. An N‐heterocyclic carbene (NHC)‐stabilized iron–dihydroboryl complex was prepared by... 
carbenes | borylene complexes | iron | boryl complexes | boron | SUBSTITUTION | COORDINATION SPHERE | REACTIVITY | PLATINUM | STRUCTURAL-CHARACTERIZATION | REACTION CHEMISTRY | CHEMISTRY, MULTIDISCIPLINARY | BOND ACTIVATION | LIGAND | TRANSITION-METAL-BORYL | Methane | Iron | Anions | Synthesis | Cationic | Halides | Lewis base | Carbenes
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2011, Volume 50, Issue 20, pp. 4704 - 4707
The taming of borylene: Dehalogenation of BHCl2⋅IMe (IMe=1,3‐dimethylimidazol‐2‐ylidene) leads to a carbene‐stabilized elusive BH borylene. A syn‐selective... 
borylenes | reactive species | boron | dehalogenation | COMPLEXES | CHEMISTRY | CHEMISTRY, MULTIDISCIPLINARY | Boron Compounds - chemistry | Quantum Theory | Boron Compounds - chemical synthesis | Magnetic Resonance Spectroscopy | Models, Molecular | Crystallography, X-Ray | Molecular Structure
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 09/2012, Volume 51, Issue 39, pp. 9931 - 9934
Journal Article
ISSN 1359-7345, 10/2015, Volume 51, Issue 88, pp. 15917 - 1592
...ChemComm COMMUNICATION Synthesis of cyclic diborenes with unprecedented cis-configuration† Cite this: Chem. Commun., 2015, 51, 15917 Philipp Bissinger, Holger... 
Journal Article
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, ISSN 1433-7851, 03/2015, Volume 54, Issue 14, pp. 4362 - 4366
A number of unprecedented photophysical phenomena were observed in the study of luminescent pi-diborene complexes of Cu and Ag. These observations included... 
PALLADIUM COMPLEXES | coinage metals | COORDINATION | SILVER(I) | MAIN-GROUP ELEMENTS | CHEMISTRY, MULTIDISCIPLINARY | diborenes | DEPENDENCE | intersystem crossing | fluorescence | AZOBENZENE | PHOTOPHYSICS | DINITROGEN | boron | DOUBLE-BOND | Silver | Boron | Olefins | Luminescence | Fluorescence | Spin-orbit interactions | Coordination compounds | Copper | Carbon
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2011, Volume 133, Issue 47, pp. 19044 - 19047
A novel NHC adduct of a dihalodiborane(4), 1, is reduced by KC8 with formation of the five-membered boracycle 2. The reaction most likely proceeds via C–H... 
LEWIS-BASE ADDUCTS | SUBSTITUTION | ANION | TRANSITION-METAL-COMPLEXES | REACTIVITY | CHEMISTRY | COORDINATION | RADICALS | CHEMISTRY, MULTIDISCIPLINARY | ALPHA,BETA-UNSATURATED CONJUGATED COMPOUNDS | BORYLLITHIUM | Borane | Chemical properties | Structure | Carbenes | Hydrogen bonding | Analysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2013, Volume 52, Issue 27, pp. 7038 - 7041
Boron at the top: Reaction of IMes⋅BBr3 (IMes=1,3‐bis(2,4,6‐trimethylphenyl) imidazol‐2‐ylidene) with Na[Co(CO)4] afforded the trimetalloboride... 
carbenes | borylene ligands | cobalt | boron | boride ligands
Journal Article
Organometallics, ISSN 0276-7333, 09/2010, Volume 29, Issue 17, pp. 3987 - 3990
Irradiation of various carbonyl complexes in the presence of 1,3-dimethylimidazol-2-ylideneborane (IMe·BH3) afforded the new borane complexes... 
COPPER(I) | N-HETEROCYCLIC CARBENE | BORON | REACTIVITY | CHEMISTRY, ORGANIC | MAGNETIC-RESONANCE SPECTRA | LEWIS BASE ADDUCTS | BOND | BORANE COMPLEXES | DERIVATIVES | BORYL | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2015, Volume 51, Issue 88, pp. 15917 - 15920
The first cyclic and -configured diborenes are prepared in a convenient one-pot synthesis. The first examples of -configured diborenes – and the first cyclic... 
REDUCTION | BORON TRIPLE BOND | CHEMISTRY, MULTIDISCIPLINARY | Ligands | Chelating | Synthesis | Precursors
Journal Article