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chemistry, multidisciplinary (7) 7
oxidation (6) 6
ketones (5) 5
peroxides (5) 5
chemistry, organic (4) 4
peroxide (4) 4
ammonium-nitrate (3) 3
carbonyl-compounds (3) 3
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selective oxidation (3) 3
silica gel (3) 3
1,3-dicarbonyl compounds (2) 2
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cerium (2) 2
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artemisinin dimers (1) 1
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azide (1) 1
baeyer-villiger reaction (1) 1
baeyer-villiger-oxidation (1) 1
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barbituric acids (1) 1
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biomolecules (1) 1
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Angewandte Chemie International Edition, ISSN 1433-7851, 03/2018, Volume 57, Issue 13, pp. 3372 - 3376
The instability of hydroxy peroxyesters, the elusive Criegee intermediates of the Baeyer–Villiger rearrangement, can be alleviated by selective deactivation of... 
peroxides | reactive intermediates | stereoelectronics | Baeyer–Villiger reaction | anomeric effects | OXIDATION | FRAGMENTATION | CHEMISTRY, MULTIDISCIPLINARY | MONOOXYGENASES | OXYGEN | KETONES | ORGANIC PEROXIDES | C-NUCLEOSIDE SYNTHESIS | LACTONES | ESTERS | HYDROGEN-PEROXIDE | Baeyer-Villiger reaction | Ketoesters | Deactivation | Stability | Hydrogen peroxide | Intermediates
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 07/2019, Volume 361, Issue 13, pp. 3173 - 3181
Malonyl peroxides act both as oxidants and reagents for C−O coupling in reactions with methyl and silyl enol ethers. In the proposed conditions, the oxidative... 
Oxidation | Peroxides | Cross-coupling | Ketones | Enols | PHTHALOYL PEROXIDE | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | H HYDROXYLATION | SYN-DIHYDROXYLATION | DIRECT ALPHA-HYDROXYLATION | ASYMMETRIC DIHYDROXYLATION | CYCLIC DIACYL PEROXIDES | HYDROGEN-PEROXIDE | CHEMISTRY, APPLIED | IN-SITU | Hydroxylation | Coupling (molecular) | Cycloaddition | Acids | Oxidants | Reagents | Oxidizing agents | Coupling | Ethers
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 02/2019, Volume 84, Issue 3, pp. 1448 - 1460
The electrochemically induced cross-dehydrogenative C-O coupling of beta-diketones and beta-ketoesters (C-H reagents) with carboxylic acids (O-H reagents) was... 
ANTIFUNGAL MICONAZOLE ACTIVITY | ELECTROORGANIC CHEMISTRY | REAGENT | KETO-ESTERS | REDUCTION | DICARBONYL COMPOUNDS | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | BOND FORMATION | ENANTIOSELECTIVE ALPHA-HYDROXYLATION | ANODIC-OXIDATION
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 03/2019, Volume 60, Issue 13, pp. 920 - 924
[Display omitted] •Kharasch reaction in non-Kharasch conditions.•Metal-free peroxidation.•Barbituric acids. It was discovered that the Kharasch peroxidation of... 
Barbituric acids | Kharasch peroxidation | Oxidative C[sbnd]O coupling | Tert-butyl hydroperoxide | Oxidative C–]O coupling | C-SP3-H BONDS | CARBON | Oxidative C-O coupling | OXIDATIVE ACTIVATION | CHEMISTRY, ORGANIC | ENANTIOSELECTIVE PEROXIDATION | FUNCTIONALIZATION | ALKENES | IN-VITRO | ANTIMALARIAL ACTIVITY | N BOND FORMATION | H BONDS
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 01/2017, Volume 58, Issue 4, pp. 352 - 354
[Display omitted] •Synthesis of α-bromoesters from aldehydes.•Solvent free mild conditions.•One-pot procedure. A two-step, one-pot reaction of aldehydes with... 
Oxidation | Cerium (IV) ammonium nitrate (CAN) | Aldehydes | Bromination | 2-Bromoesters | Esterification | SELECTIVE OXIDATION | MECHANISM | CATALYZED OXIDATION | CONVERSION | CHEMISTRY, ORGANIC | FACILE OXIDATION | AROMATIC-ALDEHYDES | PRIMARY ALCOHOLS | BENZYL ALCOHOLS | METHYL-ESTERS | WATER | Cerium | Ammonium nitrate | Lithium compounds | Esters
Journal Article
Mendeleev Communications, ISSN 0959-9436, 01/2019, Volume 29, Issue 1, p. 55
Silica gel was found to mediate decarboxylation of tetracarbonyl compounds with a free carboxylic group prepared from [beta]-dicarbonyl compounds and malonyl... 
Control | Usage | Carboxylation | Substitution reactions | Equipment and supplies | Silica gel
Journal Article
RSC Advances, ISSN 2046-2069, 2018, Volume 8, Issue 50, pp. 28632 - 28636
In this work we found that a H2O2–HBr(aq) system allows synthesis of α-monobromo ketones and α,α′-dibromo ketones from aliphatic and secondary benzylic... 
Journal Article
Mendeleev Communications, ISSN 0959-9436, 01/2019, Volume 29, Issue 1, pp. 55 - 56
[Display omitted] Silica gel was found to mediate decarboxylation of tetracarbonyl compounds with a free carboxylic group prepared from β-dicarbonyl compounds... 
OXIDATION | DIHYDROXYLATION | ORGANOCATALYSTS | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
New Journal of Chemistry, ISSN 1144-0546, 2014, Volume 38, Issue 4, pp. 1493 - 1502
A facile method, which does not require special equipment, was developed for the preparation of microsized cerium chloride by the thermal treatment of CeCl3... 
ORGANIC-CHEMISTRY | AMMONIUM-NITRATE | ASYMMETRIC-SYNTHESIS | SODIUM-IODIDE | ALPHA-HYDROXYLATION | 1,3-DICARBONYL COMPOUNDS | DICARBONYL COMPOUNDS | CECL3-CENTER-DOT-7HO-NAI SYSTEM | CHEMISTRY, MULTIDISCIPLINARY | CONJUGATE ADDITION | GENERAL-METHOD
Journal Article
Mendeleev Communications, ISSN 0959-9436, 03/2019, Volume 29, Issue 2, pp. 132 - 134
[Display omitted] Malonyl peroxides were used for the one-pot construction of hybrid structures by conjugation of heterocycle (3H-pyrazol-3-one,... 
ARTEMISININ DIMERS | HIGH-STABILITY | PLASMODIUM-FALCIPARUM | TRIOXANE DIMERS | BIOMOLECULES | AZIDE | ANTITUMOR ACTIVITIES | ANTIMALARIAL | SELECTIVITY | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | Oxidation-reduction reaction | Peroxides | Chemical properties
Journal Article
08/2018, Volume 8, Issue 5, pp. 28632 - 28636
In this work we found that a H 2 O 2 -HBr(aq) system allows synthesis of α-monobromo ketones and α,α′-dibromo ketones from aliphatic and secondary benzylic... 
Journal Article
ISSN 1144-0546, 3/2014, Volume 38, Issue 4, pp. 1493 - 152
A facile method, which does not require special equipment, was developed for the preparation of microsized cerium chloride by the thermal treatment of CeCl 3... 
Journal Article
Angewandte Chemie, ISSN 0044-8249, 03/2018, Volume 130, Issue 13, pp. 3430 - 3434
The instability of hydroxy peroxyesters, the elusive Criegee intermediates of the Baeyer–Villiger rearrangement, can be alleviated by selective deactivation of... 
Stereoelektronik | Anomere Effekte | Baeyer-Villiger-Reaktion | Peroxide | Reaktive Zwischenstufen
Journal Article
by Chatrchyan, S and Khachatryan, V and Sirunyan, A.M and Tumasyan, A and Mossolov, V and Shumeiko, N and Cornelis, T and Ochesanu, S and Roland, B and Staykova, Z and Van Haevermaet, H and Van Mechelen, P and Van Spilbeeck, A and Alves G.a, G.a and Junior, M.C.M and Martins, T and Pol, M.E and Vaz, M and Alda Junior, W.L and Carvalho, W and Chinellato, J and De Oliveira Martins, C and Matos Figueiredo, D and Manganote, E and Molina, J and Mundim, L and Nogima, H and Prado Da Silva, W.L and Santoro, A and Zachi, A and Finger, M and Finger Jr, M and Tsamalaidze, Z and Borras, K and Gunnelini, P and Jung, H and Knutsson, A and Lutz, B and Ribeiro Cipriano, P.M and Sen, N and Baus, C and Katkov, I and Ulrich, R and Wohrmann, H and Panagiotou, A and Bencze, G and Horvath, D and Beri, S.B and Gupta, R and Kaur, M and Mittal, M and Nishu, N and Saini, L.K and Banerjee, S and Bhattacharya, S and Gomber, B and Jain, Sh and Khurana, R and Sharan, M and Aziz, T and Maity, M and Majumder, G and Mazumdar, K and Mohanty, G.B and Sudhakar, K and Banerjee, S and Dugad, S and Etesami, S.M and Fahim, A and Jafari, A and Paktinat Mehdiabadi, S and Zeinali, M and Penzo, A and Afanasyev A, A and Bunin, P and Ershov, Y and Fedoseev, O and Gavrilenko, M and Golutvin, I and Gorbunov, I and Konoplynikov, V and Malakhov, A and Moisenz, P and Smirnov, V and Volodko, A and Zarubin, A and Andreev, Y and Dermenev, A and Krasnikov, N and Pashenkov, A and Tlisov, D and Toropin, A and Epshteyn, V and Erofeeva, M and Gavrilov, V and Kossov, M and Kudinov, I and Lychkovskaya, N and Popov, V and Safronov, G and ... and CMS HCAL Collaboration
Journal of Instrumentation, ISSN 1748-0221, 10/2012, Volume 7, Issue 10, pp. 1 - 19
A readout box prototype for the CMS Hadron Forward calorimeter upgrade was built and tested in the CERN H2 beamline. The prototype was designed to enable... 
Cherenkov and transition radiation | Cherenkov detectors | Calorimeters | Photon detectors for UV visible and IR photons (vacuum) | Photon detectors for UV, visible and IR photons (vacuum) | DESIGN | INSTRUMENTS & INSTRUMENTATION | Hadrons | Electronics | CERN | Instrumentation | Anodes | Prototypes
Journal Article