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ACS Catalysis, ISSN 2155-5435, 10/2018, Volume 8, Issue 10, pp. 9560 - 9566
Sulfonamides are profoundly important in pharmaceutical design. C–N cross-coupling of sulfonamides is an effective method for fragment coupling and structure... 
catalysis | copper | boronic ester | boronic acid | sulfonamide | Chan-Lam | ACIDS | COPPER(II) | CHEMISTRY, PHYSICAL | SPECIATION CONTROL | ARYLBORONIC ESTERS | PHENOLS | TRANSMETALATION | ACETATE
Journal Article
Proceedings of the National Academy of Sciences - PNAS, ISSN 0027-8424, 11/2010, Volume 107, Issue 48, pp. 20661 - 20665
The catalytic generation of chiral ester enolate equivalents from α,β-unsaturated aldehydes with chiral N-hetereocyclic carbene catalysts makes possible highly enantioselective hetero-Diels-Alder reactions... 
Amines | Catalysts | Diels Alder reactions | Chemical bases | Esters | Catalysis | Aldehydes | Carbenes | Chromatography | Cyclopentanes | TRIAZOLIUM | KETENES | CONVERSION | MULTIDISCIPLINARY SCIENCES | catalysis | ENALS | HOMOENOLATE | CYCLOADDITION | KETONES | asymmetric synthesis | reaction mechanism | ACTIVATED CARBOXYLATES | DIRECT ANNULATIONS | Physical Sciences
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2006, Volume 45, Issue 8, pp. 1248 - 1252
Additive‐free: The chemoselective amide‐bond‐forming ligation between N‐alkylhydroxylamines and α... 
chemoselectivity | peptides | amides | ketoacids | ligation reactions | Ligation reactions | Amides | Ketoacids | Peptides | Chemoselectivity | AZIDES | STAUDINGER LIGATION | ACIDS | CHEMISTRY | ACTIVATED CARBOXYLATES | CHEMISTRY, MULTIDISCIPLINARY | CATALYTIC GENERATION
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2010, Volume 132, Issue 26, pp. 8810 - 8812
... dihydropyranones via an N-heterocyclic carbene catalyzed variant of the Claisen rearrangement. Unlike other azolium-catalyzed reactions, this process requires no added base... 
MICHAEL REACTION | ALCOHOLS | ANNULATIONS | TUMOR PROMOTERS | ESTERS | ACTIVATED CARBOXYLATES | ALDEHYDES | GENERATION | STEREOSELECTIVE-SYNTHESIS | CLAVULANIC ACID | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2016, Volume 55, Issue 4, pp. 1553 - 1556
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2012, Volume 134, Issue 29, pp. 12098 - 12103
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2006, Volume 128, Issue 47, pp. 15088 - 15089
Chiral N-heterocyclic carbene (NHC) catalyzed redox reactions of racemic α-chloroaldehydes lead to the generation of chiral enolates suitable for highly enantioselective inverse-electron-demand 1-oxodiene Diels−Alder reactions... 
INVERSE-ELECTRON-DEMAND | ALPHA-CHLORINATION | ETHERS | ACTIVATED CARBOXYLATES | CARBONYL-COMPOUNDS | ALDEHYDES | GENERATION | CHEMISTRY, MULTIDISCIPLINARY | GAMMA-BUTYROLACTONES | DIRECT ANNULATIONS | ENALS | Alkenes - chemistry | Lactones - chemical synthesis | Hydrocarbons - chemistry | Heterocyclic Compounds - chemistry | Methane - analogs & derivatives | Stereoisomerism | Ketones - chemistry | Methane - chemistry | Catalysis | Aldehydes - chemistry | Research | Diels-Alder reaction | Observations | Carbenes
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2014, Volume 79, Issue 7, pp. 2809 - 2815
Saturated N-heterocycles are prevalent in biologically active molecules and are increasingly attractive scaffolds in the development of new pharmaceuticals... 
ENANTIOSELECTIVE SYNTHESIS | ALPHA-ARYLATION | TERTIARY-AMINES | MORPHOLINES | SNAP REAGENTS | NITROGEN | CHEMISTRY, ORGANIC | ELECTRON-DEFICIENT ALKENES | H BOND FUNCTIONALIZATION | RADICAL-ADDITION | CATALYTIC ASYMMETRIC-SYNTHESIS | Chemical properties | Research | Chemical synthesis | Heterocyclic aromatic compounds
Journal Article
Organic Letters, ISSN 1523-7060, 07/2018, Volume 20, Issue 13, pp. 4044 - 4047
The cross-coupling of α-aminoalkyltrifluoroborates and Grignard reagents to form N,N-substituted α-tertiary amines (ATAs) is reported... 
IMINIUM SALTS | REARRANGEMENT | ORGANIC-SYNTHESIS | ASYMMETRIC-SYNTHESIS | ALPHA-(ACYLAMINO)BENZYLBORONIC ESTERS | CHEMISTRY, ORGANIC | OLEFINS | POTASSIUM ACYLTRIFLUOROBORATES KATS | KETIMINES | DERIVATIVES | PHOTOREDOX CATALYSIS
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 02/2014, Volume 47, Issue 2, pp. 696 - 707
Catalytic reactions promoted by N-heterocyclic carbenes (NHCs) have exploded in popularity since 2004 when several reports described new fundamental reactions that extended beyond the long-studied generation of acyl anion equivalents... 
DIELS-ALDER REACTIONS | ENANTIOSELECTIVE SYNTHESIS | ALPHA,BETA-UNSATURATED ALDEHYDES | EFFICIENT SYNTHESIS | ACTIVATED CARBOXYLATES | STEREOSELECTIVE-SYNTHESIS | CLAISEN REARRANGEMENT | ENAMINE CHEMISTRY | CHEMISTRY, MULTIDISCIPLINARY | GAMMA-BUTYROLACTONES | DIRECT ANNULATIONS | Azoles (Class of compounds) | Chemical properties | Research | Carbenes | Anions | Transition metals | Equivalence | Catalysts | Chemists | Byproducts | Selectivity | Catalysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2014, Volume 136, Issue 51, pp. 17726 - 17729
The combination of cyclic ketones and stannyl amine protocol (SnAP) reagents affords saturated, spirocyclic N-heterocycles under operationally simple reaction conditions... 
ARYL RADICAL CYCLIZATION | BUILDING-BLOCKS | STEREOSELECTIVE-SYNTHESIS | INHIBITORS | CHEMISTRY, MULTIDISCIPLINARY | DISCOVERY | FAMILY | Amines - chemistry | Chemistry Techniques, Synthetic | Spiro Compounds - chemical synthesis | Ketones - chemistry | Indicators and Reagents - chemistry | Drug Discovery | Spiro Compounds - chemistry
Journal Article
Nature chemistry, ISSN 1755-4330, 2014, Volume 6, Issue 4, pp. 310 - 314
Interest in saturated N-heterocycles as scaffolds for the synthesis of bioactive molecules is increasing... 
H BOND ACTIVATION | FUNCTIONALIZATION | CARBON | AMINES | IMINES | NITROGEN | RADICALS | HYDROAMINATION | HETEROAROMATIC-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article