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1. Full Text A new iron age
by Bolm, Carsten
Nature Chemistry, ISSN 1755-4330, 08/2009, Volume 1, Issue 5, pp. 420 - 420
CHEMISTRY, MULTIDISCIPLINARY | Iron - chemistry | Catalysis
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2. Activating unreactive substrates
: the role of secondary interactions
by Bolm, Carsten and Hahn, F. Ekkehardt
2009, ISBN 9783527318230, xxii, 459
The use of secondary interactions for the activation of non-reactive substrates constitutes a new and modern approach in catalysis. This first comprehensive... 
Catalysis | Activation (Chemistry)
Book
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3. Full Text Regioselective Syntheses of 1,2‐Benzothiazines by Rhodium‐Catalyzed Annulation Reactions
by Cheng, Ying and Bolm, Carsten
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2015, Volume 54, Issue 42, pp. 12349 - 12352
Rhodium‐catalyzed directed carbene insertions into aromatic CH bonds of S‐aryl sulfoximines lead to intermediates, which upon dehydration provide... 
carbenes | CH activation | diazo compounds | heterocycles | rhodium | C-H activation | CALPAIN-I INHIBITORS | INSERTION | ONE-POT | BOND FORMATION | DIAZO-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | N-TOSYLHYDRAZONES | FUNCTIONALIZATION | BENZOTHIAZINE LIGAND | RH(III)-CATALYZED SYNTHESIS | Stereoisomerism | Organometallic Compounds - chemistry | Molecular Structure | Catalysis | Thiazines - chemical synthesis | Thiazines - chemistry | Rhodium - chemistry | Rhodium | Nitrogen | Diazo compounds | Organic chemistry | Insertion | Byproducts | Chemical reactions | Transformations | Tolerances | Dehydration | Carbenes
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4. Full Text Vanadium-catalyzed asymmetric oxidations
by Bolm, Carsten
Coordination Chemistry Reviews, ISSN 0010-8545, 2003, Volume 237, Issue 1, pp. 245 - 256
Chirally modified vanadium complexes have been used as catalysts in enantioselective epoxidations of allylic alcohols and asymmetric sulfide to sulfoxide... 
Sulfoxides | Enantioselectivity | Epoxides | Asymmetric catalysis | Vanadium | enantioselectivity | DIELS-ALDER REACTIONS | SULFOXIDE LIGANDS | asymmetric catalysis | TERT-BUTYL HYDROPEROXIDE | CHEMISTRY, INORGANIC & NUCLEAR | ENANTIOCONTROLLABLE COORDINATING ELEMENT | PLANAR-CHIRAL FERROCENES | ALLYLIC ALCOHOLS | KINETIC RESOLUTION | AMINO-ACIDS | vanadium | epoxides | sulfoxides | HIGHLY ENANTIOSELECTIVE OXIDATION | ORGANIC HYDROPEROXIDES
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5. Full Text [Cp∗RhCl 2 ] 2 : Mechanosynthesis and applications in C-H bond functionalisations under ball-milling conditions
by Hernández, José G and Bolm, Carsten
Chemical Communications, ISSN 1359-7345, 08/2015, Volume 51, Issue 63, pp. 12582 - 12584
A mechanochemical synthesis of [Cp*RhCl2]2 has been developed. Under LAG conditions the organometallic complex can be prepared in a shorter reaction time... 
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6. Full Text Sub-Mol % catalyst loading and ligand-acceleration in the coppercatalyzed coupling of aryl Iodides and terminal alkyenes
by Zuidema, Erik and Bolm, Carsten
Chemistry - A European Journal, ISSN 0947-6539, 04/2010, Volume 16, Issue 14, pp. 4181 - 4185
Diamines | Low catalyst loading sonogashira reaction | Castro-Stephens reaction | Copper | Alkynes
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7. Full Text Light‐Induced Ruthenium‐Catalyzed Nitrene Transfer Reactions: A Photochemical Approach towards N‐Acyl Sulfimides and Sulfoximines
by Bizet, Vincent and Buglioni, Laura and Bolm, Carsten
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2014, Volume 53, Issue 22, pp. 5639 - 5642
1,4,2‐Dioxazol‐5‐ones are five‐membered heterocycles known to decarboxylate under thermal or photochemical conditions, thus yielding N‐acyl nitrenes. Described... 
ruthenium | homogeneous catalysis | photochemistry | synthetic methods | nitrenes | SULFIDES | RU(SALEN)-CATALYZED ASYMMETRIC SULFIMIDATION | ALKOXYCARBONYL AZIDE | CHEMISTRY, MULTIDISCIPLINARY | METAL-FREE SYNTHESIS | TETROXIDE OXIDATION | SULFOXIDES | HYPERVALENT IODINE | IMINATION | SYNTHETIC APPLICATIONS | SULFILIMINES | Sulfides | Ruthenium | Chemical properties | Organosulfur compounds | Ambient temperature | Photochemical | Decarboxylation | Oxidation | Catalysis | Sulfur
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8. Transition metals for organic synthesis
: building blocks and fine chemicals
by Beller, Matthias and Bolm, Carsten
2004, 2nd rev. and enl. ed., ISBN 3527306137, 2 v. (xxvii, 662; xxiv, 652 p.)
Transition metal compounds | Synthesis | Organic compounds
Book
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9. Full Text Mechanochemical Iridium(III)‐Catalyzed C−H Bond Amidation of Benzamides with Sulfonyl Azides under Solvent‐Free Conditions in a Ball Mill
by Hermann, Gary N and Becker, Peter and Bolm, Carsten
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2016, Volume 55, Issue 11, pp. 3781 - 3784
Mechanochemical conditions have been applied to an iridium(III)‐catalyzed C−H bond amidation process for the first time. In the absence of solvent, the... 
iridium catalysis | mechanochemistry | ball mill | C−H amidations | solvent-free reactions | C-H amidations | ACTIVATION | FUNCTIONALIZATIONS | MECHANOSYNTHESIS | ARENES | ARYLATION | SYNTHETIC ROUTE | CHEMISTRY, MULTIDISCIPLINARY | DIRECTING GROUPS | ALKENES | AMINATION | COUPLING REACTIONS | Catalysis | Solvents | Azides (organic) | Iridium | Hydrogen bonds | Organic solvents | Benign
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10. Full Text Copper-Catalyzed Oxidative α-Ketoacylations of Sulfoximines with Aryl Methyl Ketones and Dioxygen as Terminal Oxidant
by Cheng, Hanchao and Bolm, Carsten
Synlett, ISSN 0936-5214, 03/2016, Volume 27, Issue 5, pp. 769 - 772
Abstract An efficient copper-catalyzed C−H/N−H bond functionalization for the synthesis of α-keto- N -acyl sulfoximines from aryl methyl ketones and N... 
letter | ketone | sulfoximine | α-ketoacylation | oxidative coupling | dioxygen
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11. Full Text Sulfoximidations of Benzylic C−H bonds by Photocatalysis
by Wang, Han and Zhang, Duo and Bolm, Carsten
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2018, Volume 57, Issue 20, pp. 5863 - 5866
An efficient photocatalytic functionalization of compounds with benzylic C−H bonds by sulfoximidation in visible light is described. The mild reaction... 
hypervalent iodine | sulfoximines | radicals | photocatalysis | sulfoximidation | ORGANIC-SYNTHESIS | NITROGEN-CENTERED RADICALS | CHEMISTRY, MULTIDISCIPLINARY | VISIBLE-LIGHT | AMINATION | HETEROARENES | ELECTRON-TRANSFER | HYPERVALENT IODINE(III) REAGENTS | LIGHT PHOTOREDOX CATALYSIS | SYNTHETIC APPLICATIONS | Methane | Catalysis | Chemical bonds | Aromatic compounds | Photocatalysis | Substrates
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12. Full Text Mechanochemistry of Gaseous Reactants
by Bolm, Carsten and Hernández, José G
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2019, Volume 58, Issue 11, pp. 3285 - 3299
In recent years, the application of mechanical energy to chemical systems has repeatedly proven beneficial to facilitate chemical transformations in various... 
oxidation | mechanochemistry | ball milling | hydrogenation | gases | ACTIVATION | HYDROGEN GENERATION | H BOND FUNCTIONALIZATIONS | CALCIUM CARBIDE | CHEMISTRY, MULTIDISCIPLINARY | SOLID-STATE | FUNCTIONALIZED GRAPHENE NANOPLATELETS | SOLVENT-FREE | TEMPERATURE | CATALYSTS | Hydrogenation | Organic chemistry | Reviews | Sustainability | Reagents | Ball milling | Chemical reactions | Transformations | Selectivity | Chemical synthesis
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13. Full Text Cross-Coupling Reactions
by Bolm, Carsten
The Journal of Organic Chemistry, ISSN 0022-3263, 06/2012, Volume 77, Issue 12, pp. 5221 - 5223
CHEMISTRY, ORGANIC | ARENE | ARYL | ACIDS
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14. Full Text Copper-Catalyzed C(sp2)–S Coupling Reactions for the Synthesis of Aryl Dithiocarbamates with Thiuram Disulfide Reagents
by Dong, Zhi-Bing and Liu, Xing and Bolm, Carsten
Organic Letters, ISSN 1523-7060, 11/2017, Volume 19, Issue 21, pp. 5916 - 5919
An efficient protocol for the copper-catalyzed preparation of aryl dithiocarbamates from aryl iodides and inexpensive, environmentally benign tetraalkylthiuram... 
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15. Full Text 1,2-Benzothiazines from Sulfoximines and Allyl Methyl Carbonate by Rhodium-Catalyzed Cross-Coupling and Oxidative Cyclization
by Wen, Jian and Tiwari, Deo Prakash and Bolm, Carsten
Organic Letters, ISSN 1523-7060, 04/2017, Volume 19, Issue 7, pp. 1706 - 1709
4-Unsubstituted 1,2-benzothiazines are prepared from sulfoximines and allyl methyl carbonate by Rh­(III)-catalyzed domino allylation/oxidative cyclization. A... 
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16. Full Text Conversion and degradation pathways of sulfoximines
by Wiezorek, Stefan and Lamers, Philip and Bolm, Carsten
Chemical Society (Great Britain). Chemical Society Reviews, ISSN 0306-0012, 10/2019, Volume 48, Issue 21, pp. 548 - 5423
In recent years, sulfoximines have received significant attention in both academia and industry. This development has been reinforced by the introduction of... 
Degradation | Organic chemistry | Industrial development | Agricultural chemicals | Pathways | Metabolites | Reagents | Decomposition reactions
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17. Full Text Cu(OAc)2-Catalyzed N-Arylations of Sulfoximines with Aryl Boronic Acids
by Moessner, Christian and Bolm, Carsten
Organic Letters, ISSN 1523-7060, 06/2005, Volume 7, Issue 13, pp. 2667 - 2669
A simple and mild copper salt-catalyzed N-arylation of sulfoximines in high yields is reported. Cu(OAc)2 activates aryl boronic acids for the reaction with... 
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18. Full Text Iron(II)‐Catalyzed Direct Synthesis of NH Sulfoximines from Sulfoxides
by Yu, Hao and Li, Zhen and Bolm, Carsten
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2018, Volume 57, Issue 1, pp. 324 - 327
Free NH‐sulfoximines were directly prepared from sulfoxides through iron catalysis by applying a readily available, shelf‐stable hydroxylamine triflic acid... 
iron | sulfoximines | sulfoxides | heterocycles | imidation | SULFIDES | DRUG DISCOVERY | BOCN | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | AMINATION | CATALYZED AZIRIDINATION REACTIONS | IRON(II)-MEDIATED NITRENE TRANSFER | C-H | Hydroxides | Catalysis | Heterocyclic compounds | Organosulfur compounds | Triflic acid | Hydroxylamine | Salts | Sulfoxides | Iron | Chemical synthesis | Substrates
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