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European Journal of Organic Chemistry, ISSN 1434-193X, 12/2018, Volume 2018, Issue 48, pp. 6901 - 6912
The fully O‐sulfated, O‐methylated, heparin‐related anticoagulant pentasaccharide idraparinux was prepared by a new synthetic pathway in 38 steps using... 
Oxidation | Glycosylation | Hydroboration | Heparin | Diastereoselectivity | (2-NAPHTHYL)METHYLENE ACETALS | ANALOGS | CHEMISTRY, ORGANIC | ALPHA | ANTITHROMBIN-BINDING DOMAIN | L-IDURONIC ACID | PENTASACCHARIDE | FRAGMENTS | COUPLING REACTION | HYDROGENOLYTIC TRANSFORMATION
Journal Article
Tetrahedron, ISSN 0040-4020, 04/2013, Volume 69, Issue 15, pp. 3149 - 3158
Idraparinux, the fully -sulfated, -methylated, heparin-related pentasaccharide possessing selective factor Xa inhibitory activity, was prepared by two novel... 
Blood coagulation | Heparinoid pentasaccharide | Glycosylation | d-Glucuronic acid | l-Iduronic acid | ANALOGS | CHEMISTRY, ORGANIC | ACETALS | HEPARIN | CLEAVAGE | REGIOSELECTIVITY | III BINDING DOMAIN | D-Glucuronic acid | FRAGMENT | ANTITHROMBIN-III | L-Iduronic acid | NAP | DERIVATIVES | Glucose metabolism | Glycosaminoglycans | Anticoagulants (Medicine) | Glucose | Sulfates | Dextrose | Organic acids
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 07/2018, Volume 2018, Issue 25, pp. 3312 - 3316
A new methodology for the synthesis of the most challenging heparin building block has been developed. Orthogonally protected l‐idosyl glycosyl donors were... 
Glycosylation | Heparin | l‐Idose | Diastereoselectivity | Thioglycosides | l-Idose
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 09/2015, Volume 2015, Issue 26, pp. 5730 - 5741
The reductive cleavage of 4,6‐O‐arylmethylene acetals of hexopyranosides is an effective method for the regioselective formation of a benzyl‐type ether at... 
Carbohydrates | Reduction | Chemoselectivity | Acetals | Protecting groups | Ring opening
Journal Article
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 08/2016, Volume 2016, Issue 22, pp. 3884 - 3893
The applicability of the Horner–Wadsworth–Emmons olefination to the introduction of the sulfonatomethyl moiety at the 2‐ and 3‐positions of orthogonally... 
Glycosides | Configuration determination | Carbohydrates | Allylic compounds | Olefination | Conformational analysis | STABILIZED PHOSPHORUS YLIDE | SUBSTITUTION | ANGIOGENESIS | CHEMISTRY, ORGANIC | GROUP MIGRATION | HEPARIN | SIALYL-LEWIS | ANTITHROMBIN-BINDING DOMAIN | REPLACEMENT | PENTASACCHARIDE | SULFONIC-ACID ANALOGS
Journal Article
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2010, Volume 51, Issue 51, pp. 6711 - 6714
Three sulfonic acid trisaccharides related to the antithrombin-binding DEFGH domain of heparin were synthesised. Trisaccharides carrying the sulfonatomethyl... 
PENTASACCHARIDE | M6P | MANNOSE 6-PHOSPHATE ANALOGS | SEQUENCE | BIOLOGICAL EVALUATION | CHEMISTRY, ORGANIC | RECEPTOR | URONIC-ACIDS | DERIVATIVES | Couplings | Binding | Synthesis (chemistry) | Effectiveness | Tetrahedrons | Joining | Sulfonic acid | Heparins
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2018, Volume 24, Issue 18, pp. 4532 - 4536
The photoinitiated thiol‐ene coupling reactions of 2‐substituted glycals were studied as a generally applicable strategy for stereoselective... 
radical reactions | temperature-controlled | thioglycosides | stereoselective | glycals | photoinitiation | Galactosides | Stereoselectivity | Cooling | Effectiveness | Alkenes | Temperature effects | Chemical reactions | Coupling
Journal Article
Organic & biomolecular chemistry, ISSN 1477-0520, 11/2017, Volume 15, Issue 43, pp. 9226 - 9233
Sugar-modified nucleosides are prime synthetic targets in anticancer and antiviral drug development. Radical mediated thiol-ene coupling was applied for the... 
Alkenes - chemistry | Nucleosides - chemistry | Sugars - chemistry | Temperature | Chemistry Techniques, Synthetic | Nucleosides - chemical synthesis | Click Chemistry | Sulfhydryl Compounds - chemistry | Photochemical Processes
Journal Article
Chemistry (Weinheim an der Bergstrasse, Germany), ISSN 0947-6539, 08/2019
A comprehensive optimization and mechanistic study on the photoinduced hydrothiolation of different D- and L-hexo- and pentoglycals with various thiols was... 
Journal Article
Journal Article