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Chemical Communications, ISSN 1359-7345, 12/2010, Volume 47, Issue 3, pp. 859 - 871
The ability of Lewis acids to coordinate to transition metals as σ-acceptor ligands was recognized as early as in the 1970's, but so-called Z-type ligands... 
Journal Article
NATURE CHEMISTRY, ISSN 1755-4330, 03/2019, Volume 11, Issue 3, pp. 199 - 200
Gold — long presumed to be an inert metal — has been increasingly shaking this image over the past couple of decades, mostly through electrophilic behaviour.... 
CHEMISTRY, MULTIDISCIPLINARY | COMPLEXES | Shaking | Carbon dioxide
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2015, Volume 54, Issue 50, pp. 15022 - 15045
For a while, the reactivity of gold complexes was largely dominated by their Lewis acid behavior. In contrast to the other transition metals, the elementary... 
gold | transmetallation | migratory insertion | reductive elimination | oxidative addition | CYCLOMETALATED GOLD(III) COMPLEXES | ORGANOGOLD COMPLEXES | BOND FORMATION | TERMINAL ALKYNES | C-H ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | BORONIC ACIDS | CROSS-COUPLING REACTIONS | CATALYZED INTERMOLECULAR HYDROAMINATION | Gold
Journal Article
Chemical Society reviews, ISSN 0306-0012, 02/2016, Volume 45, Issue 4, pp. 1065 - 1079
Since the mid 2000's, the incorporation of Lewis acid moieties in ligands for transition metals has been studied extensively. So-called ambiphilic ligands were... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2018, Volume 57, Issue 2, pp. 386 - 388
Square way to heaven: As a result of their square‐planar geometry, the reactive site of gold(III) complexes is much closer to the ancillary ligands. This... 
BINOL | gold | asymmetric catalysis | N-heterocyclic carbenes (NHCs) | cyclometalated complexes | 1,5-ENYNES | LIGANDS | REACTIVITY | ENANTIOSELECTIVE GOLD CATALYSIS | OXIDATIVE ADDITION | BOND | CHEMISTRY, MULTIDISCIPLINARY | Catalysis | Gold
Journal Article
ISSN 0306-0012, 2/2016, Volume 45, Issue 4, pp. 165 - 179
Since the mid 2000's, the incorporation of Lewis acid moieties in ligands for transition metals has been studied extensively. So-called ambiphilic ligands were... 
Journal Article
Nature Communications, ISSN 2041-1723, 12/2017, Volume 8, Issue 1, pp. 565 - 8
Journal Article
Dalton Transactions, ISSN 1477-9226, 8/2018, Volume 47, Issue 31, pp. 1388 - 1393
π Hydrocarbons are widespread ligands and substrates in transition metal chemistry. Although gold( iii ) has been known for some time to efficiently activate... 
Gold | Organic chemistry | Alkenes | Aromatic compounds | Hydrocarbons | Coordination compounds | Substrates | Alkynes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2015, Volume 54, Issue 17, pp. 5236 - 5240
The oxidative addition of strained CC bonds (biphenylene, benzocyclobutenone) to DPCb (diphosphino‐carborane) gold(I) complexes is reported. The resulting... 
selectivity | CC bond activation | gold chemistry | reductive elimination | oxidative addition | C-C bond activation | CATALYSIS | ACTIVATION | INSERTION | RHODIUM | COMPLEXES | ISOMERIZATION | CLEAVAGE | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | C-C BOND | Carbon-carbon composites | Thermodynamics | Gold | Adjustment | Cationic | Mathematical analysis | Transformations | Inserts | Chemical Sciences
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2015, Volume 54, Issue 4, pp. 1266 - 1269
Migratory insertion of alkenes into gold–carbon bonds, a fundamental yet unprecedented organometallic transformation, has been investigated from a discrete... 
gold | Lewis acids | insertion reactions | olefins | organometallic chemistry | Gold | Insertion reactions | Organometallic chemistry | Olefins | SYN-INSERTION | REACTIVITY | POLYMERIZATION | HYDROAMINATION | ORGANOGOLD COMPOUNDS | OXIDATIVE ADDITION | ALLENES | CHEMISTRY, MULTIDISCIPLINARY | BONDS | LIGAND | Carbocyclic compounds | Pyridine | Trapping | Dimethyl | Pyridines | Alkenes | Cationic | Chlorides | Metalorganic compounds | Insertion | Transformations
Journal Article
Dalton transactions (Cambridge, England : 2003), ISSN 1477-9226, 08/2018, Volume 47, Issue 31, pp. 10388 - 10393
π Hydrocarbons are widespread ligands and substrates in transition metal chemistry. Although gold(iii) has been known for some time to efficiently activate... 
Journal Article