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Macromolecules, ISSN 0024-9297, 01/2014, Volume 47, Issue 2, pp. 517 - 524
This contribution describes our recent results regarding the metal-catalyzed ring-opening polymerization of pentadecalactone and its copolymerization with... 
CYCLIC ESTERS | MULTIFUNCTIONAL INITIATOR | BIODEGRADABLE POLYMERS | POLYMER SCIENCE | EPSILON-CAPROLACTONE | COMPLEXES | LACTIDE | OMEGA-PENTADECALACTONE | FATTY-ACIDS | ALT-GLYCOLIC ACID | ZINC
Journal Article
Macromolecules, ISSN 0024-9297, 04/2012, Volume 45, Issue 8, pp. 3356 - 3366
Journal Article
Organometallics, ISSN 0276-7333, 02/2012, Volume 31, Issue 4, pp. 1458 - 1466
The coordination chemistry of bidentate fluorinated alkoxy-imino ligands onto Al(III) centers has been studied. The proligands (CF3)2C(OH)CH2C(R1)N–R2... 
Chemical Sciences | Other
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2011, Volume 17, Issue 6, pp. 1872 - 1883
A series of methoxy‐amino‐bis(phenol)s (ONOO R 1,R 2)H2 possessing on the phenol rings R1 ortho substituents with variable steric and electronic properties... 
electronic effects | ring‐opening polymerization | lactide | stereoselectivity | yttrium | ring-opening polymerization | CYCLIC ESTERS | STEREOCONTROL | CRYSTAL-STRUCTURE | RAC-LACTIDE | CHEMISTRY, MULTIDISCIPLINARY | METALLOCENE POLYOLEFIN CATALYSTS | LIGANDS | F-C CONTACTS | YTTRIUM COMPLEXES | INITIATORS | GROUP-3 METAL-COMPLEXES | Chemical Sciences | Catalysis
Journal Article
Organometallics, ISSN 0276-7333, 01/2010, Volume 29, Issue 2, pp. 491 - 500
Routes toward heteroleptic Al complexes supported by fluorinated β-diketonate ligands have been studied. Reactions of pro-ligands (acacR1,R2)H (R1 = R2 = CF3,... 
RACEMIC LACTIDE | CYCLIC ESTERS | SALEN-ALUMINUM | EPSILON-CAPROLACTONE POLYMERIZATION | NUCLEAR MAGNETIC RESONANCE | MASS-SPECTRA | IMMORTAL POLYMERIZATION | YTTRIUM COMPLEXES | CHEMISTRY, ORGANIC | METAL-COMPLEXES | CATALYSTS | CHEMISTRY, INORGANIC & NUCLEAR | Chemical Sciences | Catalysis
Journal Article
Macromolecules, ISSN 0024-9297, 02/2015, Volume 48, Issue 3, pp. 502 - 510
A highly effective and facile technique for catalytic ring-opening copolymerization (cROP) of lactones viz. ε-caprolactone and ε-decalactone with... 
Materials Chemistry | Inorganic Chemistry | Organic Chemistry | Polymers and Plastics | STATE MAS NMR | POLYMER SCIENCE | MOLECULAR-WEIGHT | EPSILON-CAPROLACTONE | ALKOXIDES | STRATEGY | ENHANCEMENT | RESOLUTION | DYNAMICS | OMEGA-PENTADECALACTONE | RING-OPENING POLYMERIZATION
Journal Article
Macromolecules, ISSN 0024-9297, 02/2009, Volume 42, Issue 4, pp. 987 - 993
The mechanism of the ring-opening polymerization of rac-β-butyrolactone using yttrium complexes supported by dianionic aminoalkoxybis(phenolate) ligands as... 
(R,S)-BETA-BUTYROLACTONE | POLYMER SCIENCE | BLOCK-COPOLYMERS | POLY(BETA-HYDROXYBUTYRATE) | LACTIDE | PROPYLENE | VALEROLACTONE | HYDROXYBUTYRATE | INITIATORS | HOMOPOLYMERS | GROUP-3 METAL-COMPLEXES | Chemical Sciences | Catalysis
Journal Article
Organometallics, ISSN 0276-7333, 11/2008, Volume 27, Issue 22, pp. 5815 - 5825
The coordination chemistry of new fluorinated dialkoxy-diimino ligands onto Al(III) centers has been studied. Diimino-diols (CF3)2C(OH)CR1... 
RACEMIC LACTIDE | METAL ALKOXIDES | EPSILON-CAPROLACTONE POLYMERIZATION | STEREOCONTROL | CHEMISTRY, ORGANIC | POLY(LACTIC ACID) | CRYSTAL | INITIATORS | PRECURSORS | CATALYSTS | ALCOHOLYSIS | CHEMISTRY, INORGANIC & NUCLEAR | Chemical Sciences | Catalysis
Journal Article
Macromolecules, ISSN 0024-9297, 01/2017, Volume 50, Issue 1, pp. 107 - 122
The synthesis and characterization of polyethylene–polyester block and graft copolymers and their potential as compatibilizers in polyethylene-based polymer... 
POLYMER SCIENCE | LINEAR POLYETHYLENE | CHAIN TRANSFER-REACTION | NUCLEAR-MAGNETIC-RESONANCE | FUNCTIONALIZED OLEFINS | RING-OPENING POLYMERIZATION | TRANSFER RADICAL POLYMERIZATION | MEDIATED OLEFIN POLYMERIZATION | ORGANOLANTHANIDE-CATALYZED SYNTHESIS | POLARIZATION TRANSFER | ISOTACTIC POLYPROPYLENE
Journal Article
Organometallics, ISSN 0276-7333, 04/2010, Volume 29, Issue 7, pp. 1865 - 1868
Methyl abstraction from a neutral aluminum complex stabilized by a salen-like fluorinated dialkoxide-diimino ligand yields the corresponding cationic species,... 
RACEMIC LACTIDE | CYCLIC ESTERS | LACTIDE POLYMERIZATION | EPSILON-CAPROLACTONE | INCORPORATING AMINOTROPONIMINATE LIGANDS | RAY CRYSTAL-STRUCTURES | CHEMISTRY, ORGANIC | RING-OPENING POLYMERIZATION | PROPYLENE-OXIDE | ALKYL COMPLEXES | METAL-COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | Chemical Sciences | Catalysis
Journal Article
Polymer Chemistry, ISSN 1759-9954, 2014, Volume 5, Issue 10, pp. 3306 - 3310
A new approach towards polyolefin-¿like copolyesters is introduced based on a single set of reaction conditions. The delicate balance between steric hindrance... 
STATE MAS NMR | POLYMERS | POLYMER SCIENCE | EPSILON-CAPROLACTONE | ALKOXIDES | ENHANCEMENT | RESOLUTION | DYNAMICS | OMEGA-PENTADECALACTONE | RING-OPENING POLYMERIZATION | LIPASE
Journal Article
Polymer Chemistry, ISSN 1759-9954, 04/2014, Volume 5, Issue 10, pp. 3306 - 3310
A new approach towards polyolefin-like copolyesters is introduced based on a single set of reaction conditions. The delicate balance between steric hindrance... 
Polymer chemistry | Copolymers | Branched | Steric hindrance | Topology | Monomers | Block copolymers | Lactones
Journal Article
ISSN 1759-9954, 4/2014, Volume 5, Issue 1, pp. 336 - 331
A new approach towards polyolefin-like copolyesters is introduced based on a single set of reaction conditions. The delicate balance between steric hindrance... 
Journal Article
Chemistry: A European Journal, ISSN 0947-6539, 02/2011, Volume 17, Issue 6, pp. 1872 - 1883
A series of methoxy-amino-bis(phenol)s (ONOO)H2 possessing on the phenol rings R1ortho substituents with variable steric and electronic properties (R1=CMe2Ph,... 
Syndiotacticity | Enrichment | Phenol | Polymerization | Electronics | Mathematical models | Yttrium | Methylene
Journal Article
New Journal of Chemistry, ISSN 1144-0546, 2008, Volume 32, Issue 12, pp. 2279 - 2291
The coordination chemistry of a series of potentially tetra-, tri- and bi-dentate aminophenol proligands ([L-1]H-[L-5]H) with magnesium and zinc derivatives... 
ARM TRIAZACYCLONONANE LIGANDS | RADICAL STABILITY | LACTIDE POLYMERIZATION | EPSILON-CAPROLACTONE | N-DONOR | CRYSTAL-STRUCTURE DETERMINATION | STRUCTURAL-CHARACTERIZATION | RING-OPENING POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | ENOLIZABLE KETONES | METAL-COMPLEXES | Chemical Sciences | Catalysis
Journal Article
Tetrahedron, ISSN 0040-4020, 01/2008, Volume 64, Issue 1, p. 75
A series of novel [beta]-hydroxy-[beta]-bis(trifluoromethyl)-imines (2a-j) and di([beta]-hydroxy-[beta]-bis(trifluoromethyl))-diimines (3a-f) were prepared in... 
Schiff bases | Amines | Ketones | Microbiological synthesis
Journal Article
Tetrahedron, ISSN 0040-4020, 2008, Volume 64, Issue 1, pp. 75 - 83
A series of novel β-hydroxy-β-bis(trifluoromethyl)-imines ( 2a– j) and di(β-hydroxy-β-bis(trifluoromethyl))-diimines ( 3a– f) were prepared in moderate to good... 
Aldolization | Imines | Lewis acid catalysis | β-Ketols | Fluorinated alcohols | fluorinated alcohols | TRANSITION-METAL-COMPLEXES | OLEFIN POLYMERIZATION | CHEMISTRY, ORGANIC | imines | LEWIS-ACID CATALYSIS | ENAMINES | beta-Ketols | TRIFLUOROACETALDEHYDE | BETA-TRIFLUOROMETHYL KETONES | GENERATION | BOND | PRECURSORS | aldolization | Chemical Sciences | Catalysis
Journal Article
ACS CATALYSIS, ISSN 2155-5435, 09/2019, Volume 9, Issue 9, pp. 7779 - 7790
Well-defined randomly functionalized polyolefins produced by catalysis form an interesting class of polymers with great potential for various applications. One... 
POLYOLEFINS | DESIGN | TERPOLYMERIZATION | titanium | ALPHA-OLEFIN | OLEFIN POLYMERIZATION | CHEMISTRY, PHYSICAL | CYCLOPENTADIENYL | ZIEGLER-NATTA POLYMERIZATION | ETHYLENE POLYMERIZATION | polyethylene | BHT | functionalized polyolefin | low valent | COPOLYMERIZATION
Journal Article
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