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Organometallics, ISSN 0276-7333, 11/2010, Volume 29, Issue 22, pp. 6057 - 6064
Hydrosilylation of a variety of ketones and aldehydes using the cationic iridium catalyst (POCOP)Ir(H)(acetone)+, 1 (POCOP =... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2012, Volume 134, Issue 1, pp. 640 - 653
The cationic Ir(III) acetone complex (POCOP)Ir(H)2(acetone)+ (POCOP = 2,6-bis(di-tert-butylphosphinito)phenyl) was shown to catalyze the reduction of a variety... 
CONVERSION | SILANE REDUCTION | HYDROSILANES | HYDROSILYLATION | CONVENIENT | CATALYZED REDUCTION | CARBOXAMIDES | SELECTIVITY | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | HYDRODEFLUORINATION | Amides | Amines | Chemical properties | Catalysis | Iridium | Analysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2014, Volume 53, Issue 33, pp. 8709 - 8713
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 08/2018, Volume 51, Issue 8, pp. 1831 - 1839
Conspectus The most ubiquitous polymer, polyethylene (PE), is produced either through a radical-initiated process or, more commonly, through a... 
POLAR MONOMERS | OLEFIN POLYMERIZATION CATALYSTS | NICKEL-CATALYSTS | TEMPERATURE | PALLADIUM COMPLEXES | ISOMERIZATION | CHAIN-GROWTH | CHEMISTRY, MULTIDISCIPLINARY | COORDINATION-INSERTION COPOLYMERIZATION | ALKYL COMPLEXES | POLYETHYLENE
Journal Article
Nature Communications, ISSN 2041-1723, 01/2019, Volume 10, Issue 1, pp. 438 - 6
Here we report that the tri-1-adamantylphosphine- nickel complex [Ad(3)PNiBr(3)](-)[Ad(3)PH](+) upon activation with an alkylaluminoxane catalyzes the... 
PALLADIUM | ETHYLENE | TEMPERATURE | MULTIDISCIPLINARY SCIENCES | COMPLEXES | POLYMERIZATION | LIGAND | OLIGOMERIZATION | COPOLYMERIZATION | NICKEL(II) | Polyethylenes | Polyethylene | Alkenes | Ethylene | Polymerization | Nickel | Copolymerization | Chemical synthesis | Weight
Journal Article
Chemical Communications, ISSN 1359-7345, 03/2011, Volume 47, Issue 12, pp. 3643 - 3645
Cationic silane complex 2, catalyzes the hydrosilylation of epoxides and cyclic ethers to give the silyl-protected alcohols, regioselectively. A mechanistic... 
Substrate Specificity | Silanes - chemistry | Catalysis | Stereoisomerism | Iridium - chemistry | Epoxy Compounds - chemistry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2012, Volume 134, Issue 28, pp. 11304 - 11307
Catalytic reduction of secondary amides to imines and secondary amines has been achieved using readily available iridium catalysts such as [Ir­(COE)2Cl]2 with... 
CHEMOSELECTIVE REDUCTION | COMPLEX | SILANES | HYDROSILANES | SELECTIVE REDUCTIONS | HYDROSILYLATION | TERTIARY AMIDES | SILYL | CHEMISTRY, MULTIDISCIPLINARY | CARBOXYLIC-ACID DERIVATIVES | FACILE TRANSFORMATION | Amides | Oxidation-reduction reaction | Chemical properties | Catalysis | Iridium | Analysis
Journal Article
Proceedings of the National Academy of Sciences, ISSN 0027-8424, 04/2007, Volume 104, Issue 17, pp. 6908 - 6914
The impact of agostic interactions (i.e., 3-center–2-electron M H C bonds) on the structures and reactivity of organotransition metal compounds is reviewed. 
MOLYBDENUM COMPLEXES | C-H BOND | STEREOSPECIFIC POLYMERIZATION | MULTIDISCIPLINARY SCIENCES | ALKYL ETHYLENE COMPLEXES | OLEFIN POLYMERIZATION | IN-PLACE ROTATION | ZIEGLER-NATTA POLYMERIZATION | CHAIN PROPAGATION | RAY CRYSTAL-STRUCTURE | ISOTACTIC POLYPROPYLENE
Journal Article
Nature, ISSN 0028-0836, 06/2010, Volume 465, Issue 7298, pp. 598 - 601
Chemical reactions inside single crystals are likely to be highly selective, but examples of single crystal to single crystal (SC-SC) transformations are... 
TRANSFORMATION | NETWORK | COORDINATION POLYMER | IRIDIUM | CONVERSION | MULTIDISCIPLINARY SCIENCES | PINCER COMPLEXES | BONDS | FRAMEWORK | ELIMINATION | TRANSFER DEHYDROGENATION | Molecular dynamics | Molecular crystals | Atomic properties | Ligands | Research | Chemical properties | Observations | Hydrogenation | Spectrum analysis | Standard deviation | Crystals
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2007, Volume 129, Issue 47, pp. 14544 - 14545
C−H bond activation has been extensively studied with (Cp*)M(L) n (M = Ir, Rh), but cobalt, the third member of this triad, has not previously been shown to... 
Amines - chemistry | Molecular Structure | Amines - chemical synthesis | Catalysis | Hydrogen - chemistry | Carbon - chemistry | Cobalt - chemistry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2012, Volume 134, Issue 28, pp. 11404 - 11407
Cationic silane complexes of general structure (POCOP)Ir(H)(HSiR3) {POCOP = 2,6-[OP(tBu)2]2C6H3} catalyze hydrosilylations of CO2. Using bulky silanes results... 
HOMOGENEOUS HYDROGENATION | N-HETEROCYCLIC CARBENE | COMPLEX | MECHANISM | CONVERSION | CO2 | HYDROSILYLATION | OPPORTUNITIES | TRIETHYLSILANE | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | Methane | Silicon compounds | Analysis | Carbon dioxide | Chemical bonds | Chemical properties | Catalysis | Iridium
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2012, Volume 51, Issue 37, pp. 9422 - 9424
Trumping DIBALH: A new method for reduction of esters to aldehydes through silyl acetal intermediates involves a single‐step hydrosilylation catalyzed by a... 
hydrosilylation | iridium catalysis | ester reduction | aldehyde synthesis | homogeneous catalysis | SYSTEM | MECHANISM | COMPLEXES | CARBONYL-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE | ALCOHOLS | BEARING | HYDROSILATION | DERIVATIVES | CARBOXYLIC-ACIDS | Aldehydes | Esters | Catalysis | Reduction | Catalysts | Hydrosilylation | Iridium | Conversion
Journal Article
Organic Letters, ISSN 1523-7060, 02/2013, Volume 15, Issue 3, pp. 496 - 499
B(C6F5)3 efficiently catalyzes hydrosilylation of aliphatic and aromatic carboxylic acids to produce disilyl acetals under mild conditions. Catalyst loadings... 
Journal Article
ISSN 1359-7345, 9/2017, Volume 53, Issue 72, pp. 11 - 113
We report a method for palladium-catalysed chain-running isomerization of terminal and internal alkenes. Using an air-stable... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 04/2010, Volume 132, Issue 13, pp. 4534 - 4535
Hydrogenation of the (PONOP)Ir(I)CH3 complex [PONOP = 2,6-bis(di-tert-butylphosphinito)pyridine] yields the unexpected trans-dihydride species... 
Journal Article
Science, ISSN 0036-8075, 4/2006, Volume 312, Issue 5771, pp. 257 - 261
With petroleum supplies dwindling, there is increasing interest in selective methods for transforming other carbon feedstocks into hydrocarbons suitable for... 
Catalysts | Alkenes | Dehydrogenation | Hydrogen | Metathesis | Alkanes | Reports | Iridium | Petroleum reserves | Hydrogenation | Propane | IMIDO ALKYLIDENE COMPLEXES | XPCP PINCER COMPLEXES | IRIDIUM | MOLYBDENUM | MULTIDISCIPLINARY SCIENCES | Analysis | Research
Journal Article
Nature Chemistry, ISSN 1755-4330, 02/2011, Volume 3, Issue 2, pp. 167 - 171
Journal Article
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