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chemistry, multidisciplinary (12) 12
ligands (8) 8
platinum (8) 8
cations (7) 7
mass-spectrometry (7) 7
bond activation (6) 6
c-h activation (6) 6
chemistry, inorganic & nuclear (6) 6
activation (5) 5
c-h bond (5) 5
chemistry, organic (5) 5
ch activation (5) 5
intramolecular-coordination compounds (5) 5
mass spectrometry (5) 5
platinum complexes (5) 5
density functional calculations (4) 4
electrospray-ionization (4) 4
gas-phase (4) 4
ligand (4) 4
methane (4) 4
spectroscopy (4) 4
bonding (3) 3
chemical bonds (3) 3
complexes (3) 3
crystallography (3) 3
cyclometalation (3) 3
dichtefunktionaltheorie (3) 3
dissociation behavior (3) 3
hydrogen (3) 3
organometallic chemistry (3) 3
palladium complexes (3) 3
physics, atomic, molecular & chemical (3) 3
reactivity (3) 3
2,2′-bipyridine (2) 2
5-membered ring compounds (2) 2
ab-initio pseudopotentials (2) 2
anions (2) 2
bipyridine (2) 2
bonding strength (2) 2
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cation (2) 2
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desorption mass-spectrometry (2) 2
deuterium-exchange reaction (2) 2
different sites (2) 2
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dinuclear platinum derivatives (2) 2
electrospray ionization (2) 2
electrospray mass-spectrometry (2) 2
ethers (2) 2
fast-atom-bombardment (2) 2
index medicus (2) 2
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ions (2) 2
iridium (2) 2
mathematical analysis (2) 2
metal bonding (2) 2
metals (2) 2
monodentate 2,2'-bipyridine complex (2) 2
n-heterocyclic molecules (2) 2
nuclear magnetic resonance--nmr (2) 2
olefins (2) 2
open reading frames (2) 2
orbitals (2) 2
oxidation (2) 2
ph-wert (2) 2
pincer ligands (2) 2
platinum derivatives (2) 2
ray crystal-structure (2) 2
reaction mechanism (2) 2
rollover (2) 2
salts (2) 2
solvent (2) 2
sulfur (2) 2
tell us (2) 2
transition-metal complexes (2) 2
transition-metal-complexes (2) 2
2,2 '-bipyridine (1) 1
2,2'-bipyridine (1) 1
6-substituted 2,2'-bipyridines (1) 1
acetate (1) 1
acid-strength (1) 1
acidity (1) 1
acids (1) 1
active ligands (1) 1
adiabatic connection (1) 1
alcohols (1) 1
alkalimetalle zu halbmetallen (1) 1
alkene hydroboration (1) 1
alkylamin (1) 1
alkylamine (1) 1
aluminum (1) 1
ameisensäure (1) 1
amination (1) 1
amines (1) 1
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aromatization-dearomatization (1) 1
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Chemical Science, ISSN 2041-6520, 1/2012, Volume 3, Issue 2, pp. 38 - 326
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2018, Volume 57, Issue 16, pp. 4386 - 4411
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2019, Volume 58, Issue 40, pp. 14162 - 14166
The reaction of the Ga+ source [Ga(PhF)2]+[Al(ORF)4]− with the neutral σ‐donor ligand dmap (4‐Me2N‐C6H4N) produces the unexpectedly large and fivefold... 
weakly coordinating anions | cationic clusters | gallium cations | main-group chemistry | density functional theory | Orbitals | Salts | Metal bonding | Metals | Chemical bonds | Bonding strength | Ligands | Cations | Open reading frames | Bonding
Journal Article
Angewandte Chemie, ISSN 0044-8249, 10/2019, Volume 131, Issue 40, pp. 14300 - 14304
The reaction of the Ga+ source [Ga(PhF)2]+[Al(ORF)4]− with the neutral σ‐donor ligand dmap (4‐Me2N‐C6H4N) produces the unexpectedly large and fivefold... 
Hauptgruppenchemie | Dichtefunktionaltheorie | Schwach koordinierende Anionen | Kationische Cluster | Galliumkationen | Orbitals | Salts | Metal bonding | Metals | Chemical bonds | Bonding strength | Ligands | Cations | Open reading frames | Bonding
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 06/2013, Volume 19, Issue 25, pp. 8068 - 8072
Hydrogen liberation: An attractive approach to reversible hydrogen storage applications is based on the decomposition of formic acid. The efficient and... 
formic acid | iron | homogenous catalysis | pincer ligands | hydrogen generation | STORAGE | IRIDIUM | DECOMPOSITION | FUTURE | CHEMISTRY, MULTIDISCIPLINARY | BASE | EVOLUTION | HYDRIDE ELIMINATION | SYSTEMS | GENERATION | Iron | Hydrogen | Formic acid | Organic acids | Iron and steel industry | Hydrogen storage | Decomposition | Computation
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2012, Volume 18, Issue 44, pp. 14055 - 14062
In the ion/molecule reactions of the cyclometalated platinum complexes [Pt(LH)]+ (L=2,2′‐bipyridine (bipy), 2‐phenylpyridine (phpy), and 7,8‐benzoquinoline... 
density functional calculations | CH activation | mass spectrometry | platinum | dehydrogenation | C-H activation | AB-INITIO PSEUDOPOTENTIALS | CHEMISTRY, MULTIDISCIPLINARY | MASS-SPECTROMETRY | SOLVENT | CATIONS | ROLLOVER CYCLOMETALATION | ORGANOMETALLIC CHEMISTRY | BOND ACTIVATION | METAL-IONS | ELECTROSPRAY-IONIZATION | INSIGHTS | Nitrogen | Dehydrogenation | Hydrogen | Mass spectrometry | Olefins | Platinum | Ligands
Journal Article
International Journal of Mass Spectrometry, ISSN 1387-3806, 09/2011, Volume 306, Issue 2-3, p. 108
In the ion/molecule reactions of cyclometalated [Pt(bipy - H)].sup.+ with the chloromethanes CH.sub.4-n Cl.sub.n .sup.+ (n =1-4) insertion of platinum into the... 
Carbon compounds | Bonds | Hydrogen
Journal Article
Angewandte Chemie, ISSN 0044-8249, 04/2018, Volume 130, Issue 16, pp. 4471 - 4498
Dieser Aufsatz beschreibt eine vereinheitlichte Sichtweise auf Brønsted‐Azidität. Zunächst wird ein Überblick über die Konzepte Azidität, Säurestärke und... 
Reduzität | Brønsted-Azidität | pe-Wert | Chemisches Potential | pH-Wert
Journal Article
Chemical science, ISSN 2041-6520, 12/2019, Volume 10, Issue 46, pp. 10779 - 10788
Condensed phase access to the unprecedented tetrahedral cations [EP ] (E = S, Se, Te) was achieved through the reaction of ECl [WCA] with white phosphorus... 
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2008, Volume 14, Issue 35, pp. 11050 - 11060
In a combined experimental/computational investigation, the gas‐phase behavior of cationic [Pt(bipy)(CH3)((CH3)2S)]+ (1) (bipy=2,2′‐bipyridine) has been... 
bipyridine | bond activation | cyclometalation | platinum | dehydrosulfurization | Bipyridtne | Cyclometalation | Dehydrosulfurization | Platinum | Bond activation | IRIDIUM(III) | DINUCLEAR | LIGAND CHARGE-TRANSFER | CHEMISTRY, MULTIDISCIPLINARY | ELECTROSPRAY MASS-SPECTROMETRY | H BOND ACTIVATION | DISSOCIATION | QUADRUPOLE ION-TRAP | IONIZATION | CATION | C-H
Journal Article
Inorganic chemistry, ISSN 0020-1669, 03/2020
The PPh ligands in the heterodinuclear AuPt complex [(Ph P)AuPt(PPh ) ][BAr ] (BAr = tetrakis[3,5-bis(trifluoromethyl)phenyl]borate) exhibit a high... 
Journal Article
Chem. Sci, ISSN 2041-6520, 2012, Volume 3, Issue 2, pp. 308 - 326
"Rollover" cyclometalation constitutes a special case among the well-known class of cyclometalation reactions. An overview is given that covers the very first... 
Pictures | Spectroscopy | Rollover | Mathematical analysis | Coherence | Condensing | Reaction mechanisms
Journal Article
Chemistry (Weinheim an der Bergstrasse, Germany), 10/2011, Volume 17, Issue 42, p. 11761
Electrospray ionization (ESI) of tetrameric platinum(II) acetate, [Pt(4)(CH(3)COO)(8)], in methanol generates the formal platinum(III) dimeric cation... 
Journal Article