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1. Full Text Homogeneous Iron Catalysts in the Reaction of Epoxides with Carbon Dioxide
by Della Monica, Francesco and Buonerba, Antonio and Capacchione, Carmine
Advanced Synthesis & Catalysis, ISSN 1615-4150, 01/2019, Volume 361, Issue 2, pp. 265 - 282
Among the attempts to consolidate the so‐called circular economy, the conversion of carbon dioxide (CO2) into added‐value products has gained more and more... 
iron | epoxides | homogeneous catalysis | carbonates | carbon dioxide fixation | CYCLOHEXENE OXIDE | DOUBLE METAL CYANIDES | CHEMISTRY, ORGANIC | ORGANIC CARBONATES | BIMETALLIC IRON(III) COMPLEXES | MEDIATED FORMATION | HIGHLY EFFICIENT | ALTERNATING COPOLYMERIZATION | COUPLING REACTION | POLY(PROPYLENE CARBONATE) | CYCLIC CARBONATES | CHEMISTRY, APPLIED | Catalysts | Toxicity | Aluminum | Polycarbonates | Carbon dioxide | Chromium | Iron | Magnesium | Catalysis | Carbonates | Aliphatic compounds
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2. Full Text Highly efficient and selective reduction of nitroarenes into anilines catalyzed by gold nanoparticles incarcerated in a nanoporous polymer matrix: Role of the polymeric support and insight into the reaction mechanism
by Noschese, Annarita and Buonerba, Antonio and Canton, Patrizia and Milione, Stefano and Capacchione, Carmine and Grassi, Alfonso
Journal of Catalysis, ISSN 0021-9517, 08/2016, Volume 340, pp. 30 - 40
Gold nanoparticles supported onto a nanoporous semicrystalline polymorphic polymer matrix consisting of syndiotactic polystyrene- -1,4-polybutadiene multiblock... 
Porous polymers | Azocompounds | Heterogeneous catalysis | Nitroarene reduction | Gold nanoparticles | Mechanism | NITROAROMATIC COMPOUNDS | ROOM-TEMPERATURE | ALCOHOL OXIDATION | AROMATIC AZO-COMPOUNDS | MODEL REACTION | CHEMISTRY, PHYSICAL | LIQUID-PHASE | NANOCLUSTERS | ENGINEERING, CHEMICAL | NITRO-COMPOUNDS | SYNDIOTACTIC POLYSTYRENE | AEROBIC OXIDATION | Polymers | Polymer industry | Prisoners | Nanoparticles | Nitrobenzenes | Chemical tests and reagents | Aniline | Elastomers | Azo compounds
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3. Full Text Regioselective Ring‐Opening of Glycidol to Monoalkyl Glyceryl Ethers Promoted by an [OSSO]‐FeIII Triflate Complex
by Monica, Francesco Della and Ricciardi, Maria and Proto, Antonio and Cucciniello, Raffaele and Capacchione, Carmine
ChemSusChem, ISSN 1864-5631, 08/2019, Volume 12, Issue 15, pp. 3448 - 3452
A FeIII‐triflate complex, bearing a bis‐thioether‐di‐phenolate [OSSO]‐type ligand, was discovered to promote the ring‐opening of glycidol with alcohols under... 
ring-opening | iron | glyceryl ethers | homogeneous catalysis | glycidol | Glycerin | Glycerol | Catalysis | Regioselectivity | Earth crust | Catalysts | Selectivity | Ethers | Alcohols
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4. Full Text Binary copolymerization of 4‐methyl‐1,3‐pentadiene with styrene, butadiene and isoprene catalysed by a titanium [OSSO]‐type catalyst
by Loria, Marianna and Proto, Antonio and Capacchione, Carmine
Polymer International, ISSN 0959-8103, 01/2017, Volume 66, Issue 1, pp. 144 - 150
Binary copolymerization of 4‐methyl‐1,3‐pentadiene (4MPD) with styrene, butadiene and isoprene promoted by the titanium complex... 
copolymers | butadiene | NMR | 4‐methyl‐1,3‐pentadiene | isoprene | styrene | 4-methyl-1,3-pentadiene | POLYOLEFINS | POLYMER SCIENCE | METHYL-SUBSTITUTED 1,4-TRANS-POLYBUTADIENES | C-13 NMR-SPECTRA | COMPLEXES | POLYMERIZATION | 3-pentadiene | TETRADENTATE | 4-methyl-1 | FUNCTIONALIZATION | BIS(PHENOLATO) LIGAND | ETHYLENE | POLY-1,2-(4-METHYL-1,3-PENTADIENE) | Chemical industry | Herbicides | Pesticides industry | Nuclear magnetic resonance spectroscopy | Analysis | Butadiene | Stereoselectivity | Copolymers | Catalysts | Styrenes | Titanium | Copolymerization | Isoprene
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5. Full Text Glycidol: an Hydroxyl‐Containing Epoxide Playing the Double Role of Substrate and Catalyst for CO2 Cycloaddition Reactions
by Della Monica, Francesco and Buonerba, Antonio and Grassi, Alfonso and Capacchione, Carmine and Milione, Stefano
ChemSusChem, ISSN 1864-5631, 12/2016, Volume 9, Issue 24, pp. 3457 - 3464
Glycidol is converted into glycerol carbonate (GC) by coupling with CO2 in the presence of tetrabutylammonium bromide (TBAB) under mild reaction conditions... 
carbon dioxide | cycloaddition | epoxide | density functional theory | hydrogen bond | FUNCTIONALIZED IONIC LIQUID | GRAPHENE OXIDE | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | GLYCEROL CARBONATE | ORGANIC CARBONATES | BIMETALLIC IRON(III) COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | MILD CONDITIONS | CHEMICAL FIXATION | CYCLIC CARBONATES | CARBON-DIOXIDE | EFFICIENT | Glycerin | Hydroxides | Specific gravity | Hydrogen | Glycerol | Density functionals | Ethylene oxide | Carbonates
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6. Full Text Synthesis of Monoalkyl Glyceryl Ethers by Ring Opening of Glycidol with Alcohols in the Presence of Lewis Acids
by Cucciniello, Raffaele and Ricciardi, Maria and Vitiello, Rosa and Di Serio, Martino and Proto, Antonio and Capacchione, Carmine
ChemSusChem, ISSN 1864-5631, 12/2016, Volume 9, Issue 23, pp. 3272 - 3275
The present work deals with the production of monoalkyl glyceryl ethers (MAGEs) through a new reaction pathway based on the reaction of glycidol and alcohols... 
Lewis acids | ethers | waste valorization | green chemistry | glycerol | SOLID CATALYSTS | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | DESIGN | CHEMICALS | CATALYZED ETHERIFICATION | SELECTIVE CONVERSION | CHEMISTRY, MULTIDISCIPLINARY | Lewis Acids - chemistry | Alcohols - chemistry | Green Chemistry Technology | Propanols - chemistry | Epoxy Compounds - chemistry | Glyceryl Ethers - chemical synthesis | Catalysis | Glycerin | Glycerol | Green chemistry | Lewis acid | Pathways | Catalysts | Byproducts | Chemical reactions | Ethers | Alcohols
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7. Full Text Binary copolymerization of 4-methyl-1,3-pentadiene with styrene, butadiene and isoprene catalysed by a titanium [OSSO]-type catalyst
: Titanium complex-catalysed copolymerization of 4-methyl-1,3-pentadiene
by Loria, Marianna and Proto, Antonio and Capacchione, Carmine
Polymer International, ISSN 0959-8103, 01/2017, Volume 66, Issue 1, pp. 144 - 150
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8. Full Text Thin‐film nanostructure and polymer architecture in semicrystalline syndiotactic poly(p‐methylstyrene)–(cis‐1,4‐polybutadiene) multiblock copolymers
by Buonerba, Antonio and Monica, Francesco Della and Speranza, Vito and Capacchione, Carmine and Milione, Stefano and Grassi, Alfonso
Polymer International, ISSN 0959-8103, 10/2019, Volume 68, Issue 10, pp. 1681 - 1687
The thin‐film morphology of stereoregular syndiotactic poly(p‐methylstyrene)–(cis‐1,4‐polybutadiene) (sP(pMS–B)) multiblock copolymers has been investigated... 
multiblock copolymer | nanostructure | thin film | microstructure | atomic force microscopy | BUTADIENE BLOCK-COPOLYMERS | ISOPRENE | POLYMER SCIENCE | STRATEGY | STYRENE | INSIGHT | POLYSTYRENE | SULFONATION | SEQUENCE | EFFICIENT | CATALYSTS | Syndiotacticity | Atomic force microscopy | Chemical industry | Architecture | Lamellae | Segments | Inclusions | Polymeric films | Thin films | Domains | Organic chemistry | Copolymers | Morphology | Polybutadiene | Polymers
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9. Full Text [OSSO]‐Type Fe(III) Metallate as Single‐Component Catalyst for the CO2 Cycloaddition to Epoxides
by Della Monica, Francesco and Buonerba, Antonio and Paradiso, Veronica and Milione, Stefano and Grassi, Alfonso and Capacchione, Carmine
Advanced Synthesis & Catalysis, ISSN 1615-4150, 01/2019, Volume 361, Issue 2, pp. 283 - 288
A new [OSSO]‐Fe(III) metallate complex was prepared and characterized. We demonstrated that such metallate is the real catalytic active species for the... 
iron | cycloaddition | homogeneous catalysis | carbon dioxide fixation | CYCLIC CARBONATE SYNTHESIS | MECHANISM | DIOXIDE | CHEMISTRY, ORGANIC | PRESSURE | SOLVENTS | CHEMISTRY, APPLIED | CAPTURE | EFFICIENT | IRON(III) COMPLEXES | Cycloaddition | Catalysis | Carbonates | Catalysts | Tetrabutylammonium bromide | Carbon dioxide
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10. Full Text Aerobic Oxidation and Oxidative Esterification of 5‐Hydroxymethylfurfural by Gold Nanoparticles Supported on Nanoporous Polymer Host Matrix
by Buonerba, Antonio and Impemba, Salvatore and Litta, Antonella Dentoni and Capacchione, Carmine and Milione, Stefano and Grassi, Alfonso
ChemSusChem, ISSN 1864-5631, 09/2018, Volume 11, Issue 18, pp. 3139 - 3149
The aerobic oxidation and oxidative esterification of 5‐hydroxymethylfurfural (HMF) catalyzed by gold nanoparticles (AuNPs) supported on a semicrystalline... 
gold | oxidation | nanoparticles | polymers | supported catalysts | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | SELECTIVE OXIDATION | CATALYZED OXIDATION | ONE-POT | 2,5-FURANDICARBOXYLIC ACID | PD ALLOY NANOPARTICLES | CHEMISTRY, MULTIDISCIPLINARY | BIOMASS | 2,5-DIFORMYLFURAN | SYNDIOTACTIC POLYSTYRENE | EFFICIENT | Nanoparticles | Oxidation-reduction reaction | Furans | Polymer industry | Conveying machinery | Butadiene | Syndiotacticity | Gold | Polystyrene resins | Concentrators | Hydroxymethylfurfural | Conveyors | Oxidation | Catalysis | Esterification
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11. Full Text Glycidol, a Valuable Substrate for the Synthesis of Monoalkyl Glyceryl Ethers: A Simplified Life Cycle Approach
by Ricciardi, Maria and Passarini, Fabrizio and Vassura, Ivano and Proto, Antonio and Capacchione, Carmine and Cucciniello, Raffaele and Cespi, Daniele
ChemSusChem, ISSN 1864-5631, 05/2017, Volume 10, Issue 10, pp. 2291 - 2300
The disposal of any waste by recovering it within the production plant represents the ultimate goal of every biorefinery. In this scenario, the selective... 
lewis acids | green chemistry | life cycle assessment | biobased industry | glycidol | CATALYSIS | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | DESIGN | PUBLISHED ALGORITHMS | ETHERIFICATION | CHEMISTRY, MULTIDISCIPLINARY | CHEMICAL-REACTIONS | SUSTAINABILITY ASSESSMENT | BIOMASS | LEWIS-ACIDS | SYNTHESIS PLANS | Propanols - chemistry | Catalysis | Epoxy Compounds - chemistry | Glyceryl Ethers - chemical synthesis | Catalysts | Glycerol
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12. Improvement of tensile properties, self-healing and recycle of thermoset styrene/2-vinylfuran copolymers via thermal triggered rearrangement of covalent crosslink
by Antonio Buonerba and Vito Speranza and Carmine Capacchione and Stefano Milione and Alfonso Grassi
European Polymer Journal, ISSN 0014-3057, 02/2018, Volume 99, p. 368
Random copolymers of 2-vinylfuran with styrene (S-co-2VFs) have been thermoreversibly cross-linked via Diels-Alder (DA) reaction with... 
Bismaleimides | Differential scanning calorimetry | Atomic force microscopy | Design for recycling | Nuclear magnetic resonance--NMR | Isothermal annealing | Mechanical properties | Crosslinking | Self healing materials | Thermosetting resins | Stability analysis | Polymeric films | Thermal stability | Thin films | Copolymers | Styrenes | Styrene | Infrared radiation | Polymers | Tensile properties
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13. Full Text First Attempt of Glycidol‐to‐Monoalkyl Glyceryl Ethers Conversion by Acid Heterogeneous Catalysis: Synthesis and Simplified Sustainability Assessment
by Ricciardi, Maria and Passarini, Fabrizio and Capacchione, Carmine and Proto, Antonio and Barrault, Joel and Cucciniello, Raffaele and Cespi, Daniele
ChemSusChem, ISSN 1864-5631, 06/2018, Volume 11, Issue 11, pp. 1829 - 1837
The selective preparation of monoalkylglyceryl ethers (MAGEs) is a task for researchers owing to their broad range of applications. In this work, green... 
ethers | lewis acids | green chemistry | life cycle assessment | glycidol | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | LIFE-CYCLE ASSESSMENT | ETHERIFICATION | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | HYDROGEN | POLYETHER | SUBSTRATE | VALUE-ADDED PRODUCT | EFFICIENT | ZEOLITE | Glycerin | Heterogeneous catalysis | Analysis | Green technology | Glycerol | Green chemistry | Chemical synthesis | Sustainable development | Externalities | Economic analysis | Catalysts | Green aspects | Catalysis | Economic conditions | Ethers | Conversion | Environmental impact | Impact analysis | Alcohols
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14. Full Text Thioetherphenolate group 4 metal complexes in the ring opening polymerization of rac--Butyrolactone
by Luciano, E and Buonerba, A and Grassi, A and Milione, S and Capacchione, C
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, ISSN 0887-624X, 10/2016, Volume 54, Issue 19, pp. 3132 - 3139
Group 4 complexes 1-3 [1=(t-BuOS)(2)Ti(O-i-Pr)(2); 2=(t-BuOS)(2)Zr(O-t-Bu)(2); 3=(t-BuOS)(2)Hf(O-t-Bu)(2)] supported by two phenolate bidentate ligands... 
copolymers | CYCLIC ESTERS | POLYMER SCIENCE | polyhydroxybutyrate | RACEMIC BETA-BUTYROLACTONE | Biopolymers | group 4 metal complexes | ring-opening polymerization | YTTRIUM | STEREOSELECTIVITY | LACTONES | LIGANDS | LACTIDE | INITIATORS | COPOLYMERIZATION | CATALYSTS | Polymerization | Zirconium | Analysis
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15. Full Text Thioetherphenolate group 4 metal complexes in the ring opening polymerization of rac‐β‐Butyrolactone
by Luciano, Ermanno and Buonerba, Antonio and Grassi, Alfonso and Milione, Stefano and Capacchione, Carmine
Journal of Polymer Science Part A: Polymer Chemistry, ISSN 0887-624X, 10/2016, Volume 54, Issue 19, pp. 3132 - 3139
ABSTRACT Group 4 complexes 1–3 [1 = (t‐BuOS)2Ti(O‐i‐Pr)2; 2 = (t‐BuOS)2Zr(O‐t‐Bu)2; 3 = (t‐BuOS)2Hf(O‐t‐Bu)2] supported by two phenolate bidentate ligands... 
copolymers | polyhydroxybutyrate | Biopolymers | group 4 metal complexes | ring-opening polymerization | Ring opening polymerization | Catalysts | Copolymerization | Catalysis | Coordination compounds | Monomers | Isopropanol | Block copolymers
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