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Angewandte Chemie International Edition, ISSN 1433-7851, 07/2013, Volume 52, Issue 29, pp. 7492 - 7495
It works ether way: Labile adducts of dialkyl ethers with the electrophilic borane B(C6F5)3 are shown to scramble HD to H2 and D2 and catalyze the... 
boranes | organocatalysis | ethers | hydrogenation | frustrated Lewis pairs
Journal Article
Organometallics, ISSN 0276-7333, 01/2012, Volume 31, Issue 1, pp. 27 - 30
The Lewis acid B(C6F5)3 is shown to activate a series of alkyl fluorides. In stoichiometric reactions, treatment of sterically demanding phosphines with... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2012, Volume 51, Issue 19, pp. 4714 - 4717
CO2 snapper: Compounds containing both acidic and basic P,N functionalities have been prepared. Of these, two amidophosphoranes containing highly reactive PN... 
amidophosphoranes | Lewis acids and bases | carbon dioxide | pnictogens | phosphonium | HEXACOORDINATE PHOSPHORUS | ACTIVATION | MOLECULAR-STRUCTURE | COMPLEXES | REACTIVITY | RUTHENIUM | CHEMISTRY, MULTIDISCIPLINARY | PHOSPHINE-AMIDO | CARBON-DIOXIDE | TRANSFER HYDROGENATION CATALYSIS | PAIRS
Journal Article
Angewandte Chemie - International Edition, ISSN 1433-7851, 05/2012, Volume 51, Issue 19, pp. 4714 - 4717
Journal Article
Organometallics, ISSN 0276-7333, 11/2018, Volume 37, Issue 21, pp. 3654 - 3658
We demonstrate that tris­(pentafluorophenyl)­borane, B­(C6F5)3, is shown to be an effective catalyst for the hydroarylation of olefins to yield substituted... 
Journal Article
Tetrahedron, ISSN 0040-4020, 01/2019, Volume 75, Issue 1, pp. 31 - 35
In studying the factors which contribute to the Lewis acidity of organoboron compounds we investigated approaches to the design of robust, novel Lewis acids... 
Lewis acid | Boron | Fluoride ion affinity | Catalysis | Gutmann-Beckett method | COMPLEXES | CHEMISTRY, ORGANIC | Esters | Catechin | Hydrogen-ion concentration
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2013, Volume 52, Issue 3, pp. 960 - 963
Frustrating: A sterically unencumbered aniline base (see picture, left) can be transformed into a bulky Lewis base by converting it into a [2]rotaxane (right).... 
interlocked molecules | rotaxanes | macrocycles | hydrogen activation | frustrated Lewis pairs | CO2 | FREE CATALYTIC-HYDROGENATION | OLEFIN METATHESIS | CHEMISTRY, MULTIDISCIPLINARY | TEMPLATE SYNTHESIS | NITROUS-OXIDE | METAL-ORGANIC FRAMEWORKS | ADDITION-REACTIONS | CARBON-DIOXIDE | PAIRS | Scholarships | Hydrogen | Universities and colleges
Journal Article
Journal of Urology, ISSN 0022-5347, 04/2019, Volume 201, Issue Supplement 4
Journal Article
Dalton Transactions, ISSN 1477-9226, 07/2015, Volume 44, Issue 27, pp. 12256 - 12264
A series of fluorophosphonium salts, [R sub(3)PF][X] (R = alkyl or aryl; X = FB(C sub(6)F sub(5)) sub(3), [B(C sub(6)F sub(5)) sub(4)]), have been prepared by... 
Synthesis | Aromatic compounds | Mathematical analysis | Boranes | Affinity | Cations | Fluorides | Phosphines
Journal Article
Angewandte Chemie, ISSN 1433-7851, 07/2013, Volume 52, Issue 29, p. 7492
  It works ether way: Labile adducts of dialkyl ethers with the electrophilic borane B(C6F5)3 are shown to scramble HD to H2 and D2 and catalyze the... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 01/2013, Volume 42, Issue 7, pp. 2629 - 2635
Oxidative fluorination of the electron-deficient phosphine Ph sub(2)P(C sub(6)F sub(5)) using XeF sub(2), followed by fluoride ion abstraction from the... 
Ambient temperature | Heating | Spectroscopic analysis | Fluorides | Nuclear magnetic resonance | Fluorination | Phosphines
Journal Article
Angewandte Chemie (International Edition), ISSN 1433-7851, 07/2013, Volume 52, Issue 29, pp. 7492 - 7495
It works ether way: Labile adducts of dialkyl ethers with the electrophilic borane B(C sub(6)F sub(5)) sub(3) are shown to scramble HD to H sub(2) and D sub(2)... 
Catalysts | Boranes | Catalysis | Ethers | Hydrogenation | Adducts
Journal Article
Military medicine, ISSN 0026-4075, 07/2019
Over 1,500 bladder cancers were diagnosed among US Veterans in 2010, the majority of which were non-muscle invasive bladder cancer (NMIBC). Little is known... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 12/2013, Volume 135, Issue 49, pp. 18308 - 18310
Organofluorophosphonium salts of the formula [(C6F5)3–x Ph x PF][B(C6F5)4] (x = 0, 1) exhibit Lewis acidity derived from a low-lying σ* orbital at P opposite... 
ACTIVATION | CARBON | MECHANISM | COMPLEXES | SILICON | HYDROSILATION | CHEMISTRY, MULTIDISCIPLINARY | B(C6F5)-CATALYZED HYDROSILYLATION | Organofluorine compounds | Chemical properties | Research | Olefins | Isomerization
Journal Article
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 07/2014, Volume 111, Issue 30, p. 10917
  A major advance in main-group chemistry in recent years has been the emergence of the reactivity of main-group species that mimics that of transition metal... 
Chemistry | Acids | Metals | Catalysis | Hydrogenation | Density
Journal Article
Science, ISSN 0036-8075, 9/2013, Volume 341, Issue 6152, pp. 1374 - 1377
Prototypical Lewis acids, such as boranes, derive their reactivity from electronic unsaturation. Here, we report the Lewis acidity and catalytic application of... 
Salts | Catalysts | REPORTS | Lewis acids | Ions | Boranes | Alkanes | Acidity | Cations | Fluorides | Nuclear magnetic resonance | PHOSPHORUS | ACTIVATION | MULTIDISCIPLINARY SCIENCES | COMPLEXES | CO2 | C-F BONDS | CATIONS | Organofluorine compounds | Research | Acids | Properties | Fluorination | Salt | Fluorine | Silanes | Lewis acid | Donors (electronic) | Electronics | Complement | Lewis base | Bonding
Journal Article
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 7/2014, Volume 111, Issue 30, pp. 10917 - 10921
A major advance in main-group chemistry in recent years has been the emergence of the reactivity of main-group species that mimics that of transition metal... 
Silanes | Transition metals | Amines | Thiols | Alkenes | Catalysts | Phenols | Lewis acids | Catalysis | Carboxylic acids | Fluorophosphonium | Properties | Hydrogenation | Olefins | Methods | Physical Sciences | fluorophosphonium
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2016, Volume 55, Issue 4, pp. 1417 - 1421
The electrophilic organofluorophosphonium catalyst [(C6F5)3PF][B(C6F5)4] is shown to effect benzylation or alkylation by aryl and alkyl CF3 groups with... 
alkylation | benzylation | hydrodefluorination | electrophilic phosphonium cations | trifluoromethyl groups | ROOM-TEMPERATURE | SUBSTITUTION | SUBSTANCES | FLUORINATION | LEWIS ACIDITY | CHEMISTRY, MULTIDISCIPLINARY | F BOND ACTIVATION | FLUORIDES | CATIONS | C(SP)-F BONDS | CHEMISTRY | Fragments | Transformation | Catalysts | Aromatic compounds | Alkylation
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2013, Volume 52, Issue 29, p. 7492
Journal Article
ISSN 1477-9226, 7/2015, Volume 44, Issue 27, pp. 12256 - 12264
A series of fluorophosphonium salts, [R 3 PF][X] (R = alkyl or aryl; X = FB(C 6 F 5 ) 3 , [B(C 6 F 5 ) 4 ]), have been prepared by reactions of... 
Journal Article
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