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chemistry, organic (35) 35
sulfides (16) 16
asymmetric-synthesis (11) 11
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leaving groups (10) 10
resolution (10) 10
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chemistry, physical (9) 9
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3-oxo ester reduction (2) 2
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Acta Crystallographica Section C, ISSN 2053-2296, 02/2019, Volume 75, Issue 2, pp. 189 - 195
Aminobenzylnaphthols are a class of compounds containing a large aromatic molecular surface which makes them suitable candidates to study the role of C—H…π... 
small molecule | CrystalExplorer | C—H…π interactions | crystal structure | aminobenzylnaphthol | Hirshfeld | packing | C—H⋅⋅⋅π interactions | Hydrogen bonds | Aromatic compounds | Chemical bonds | Naphthol | Bonding | Hydrogen bonding | Hydrogen ion concentration | Crystal structure
Journal Article
CrystEngComm, ISSN 1466-8033, 12/2019, Volume 21, Issue 47, pp. 7224 - 7232
Along the lines of a systematic investigation of conformational constraints promoted by weak interactions, the aryl-stacked structures of some chiral cyclic... 
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 12/2017, Volume 2017, Issue 44, pp. 6486 - 6490
NH‐sulfoximines are emerging as useful and important targets in drug discovery and synthetic organic chemistry. We report herein the development of an... 
Nitrogen | Sulfur | Flow chemistry | Continuous flow | Microreactors | SULFIDES | SUSTAINABLE SYNTHESIS | BUILDING-BLOCKS | ARENES | CHEMISTRY, ORGANIC | ALDOL REACTIONS | MEDICINAL CHEMISTRY | SULFOXIDES | LIGANDS | KINETIC RESOLUTION | Sulfides
Journal Article
Tetrahedron: Asymmetry, ISSN 0957-4166, 12/2017, Volume 28, Issue 12, pp. 1792 - 1796
The multi-component Betti reaction of 2-naphthol, benzaldehyde and ( )-amines, that usually provides highly valuable aminobenzylnaphthol bearing two... 
MANNICH REACTION | AMINOALKYLATION | ACID | ARYL ALDEHYDES | HYDROGEN-BOND | DIETHYLZINC | RESOLUTION | CHEMISTRY, PHYSICAL | CHIRAL AMINONAPHTHOLS | ENANTIOSELECTIVE ADDITION | DERIVATIVES
Journal Article
Tetrahedron: Asymmetry, ISSN 0957-4166, 2010, Volume 21, Issue 5, pp. 507 - 517
The multicomponent reaction between 2-naphthol, aryl aldehydes and ammonia or amines yields aminobenzylnaphthols in a process known as the Betti reaction,... 
ASYMMETRIC CATALYSIS | ARYL ALDEHYDES | TERTIARY AMINONAPHTHOL | CHEMISTRY, ORGANIC | CHEMISTRY, PHYSICAL | CHIRAL AMINONAPHTHOLS | ENANTIOSELECTIVE ADDITION | AROMATIC-ALDEHYDES | CHEMISTRY, INORGANIC & NUCLEAR | DIETHYLZINC | KINETIC RESOLUTION | RING-CHAIN TAUTOMERISM | STEREOSELECTIVE-SYNTHESIS
Journal Article
Natural Hazards and Earth System Sciences, ISSN 1561-8633, 12/2016, Volume 16, Issue 12, pp. 2623 - 2639
A multiscale sampling experiment was carried out in the Gulf of Taranto (eastern Mediterranean) providing the first synoptic evidence of the large-scale... 
GEOSCIENCES, MULTIDISCIPLINARY | DYNAMICS | WATER RESOURCES | METEOROLOGY & ATMOSPHERIC SCIENCES | CIRCULATION MODEL | SEA | REGION | Dynamic meteorology | Environmental impact analysis
Journal Article
Tetrahedron, ISSN 0040-4020, 04/2019, Volume 75, Issue 16, pp. 2406 - 2412
A fruitful switch from -butyl to cumene hydroperoxide was able to overcome a difficulty arose in the enantioselective oxidation of fluorinated aryl benzyl... 
Sulfoxide | Catalysis | Hydrobenzoin | Oxidation mechanism | Circular dichroism | SUBSTITUTION | ASYMMETRIC-SYNTHESIS | PHASE-TRANSFER | SULFENATE ANIONS | ARYLATION | RESOLUTION | CHEMISTRY, ORGANIC | CHIRAL SULFOXIDES | Sulfides | Oxidation-reduction reaction | Enantiomers | Organosulfur compounds
Journal Article
Tetrahedron, ISSN 0040-4020, 04/2018, Volume 74, Issue 16, pp. 2041 - 2047
Pentafluorobenzyl pentafluorophenyl sulfide is oxidised with moderate e.e. value and a low yield by the usually highly successful oxidation protocol based upon... 
Titanium | Sulfoxide | Hydrobenzoin | Oxidation mechanism | DFT computations | CHIRAL TITANIUM COMPLEXES | ESOMEPRAZOLE | THERMOCHEMICAL KINETICS | PHASE-TRANSFER | SULFENATE ANIONS | ARYLATION | RESOLUTION | CHEMISTRY, ORGANIC | ASYMMETRIC OXIDATION | ACTIVE SULFOXIDES | FLUORINE SUBSTITUTION | Sulfides | Oxidation-reduction reaction | Enantiomers | Chromatography
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 09/2015, Volume 2015, Issue 25, pp. 5554 - 5562
Journal Article
Chirality, ISSN 0899-0042, 01/2018, Volume 30, Issue 1, p. 29
Three [beta]-keto sulfoxides (1-3) were synthesized in enantiopure form and investigated by means of circular dichroism (CD) spectroscopy, both in electronic... 
Enantiomers | Analysis | Organosulfur compounds | Solid state | Spectroscopy | Quantum chemistry | Mathematical analysis | Spectrum analysis | Absolute configuration | Dichroism | Sulfoxides | Video CD | Configurations | Circular dichroism
Journal Article
Crystal Growth & Design, ISSN 1528-7483, 11/2014, Volume 14, Issue 11, pp. 5442 - 5451
A series of enantiopure crystalline aryl benzyl sulfoxides, bearing different substituents on both the aryl groups, were synthesized by an enantioselective... 
CONTACTS | ROUTE | HIRSHFELD SURFACE-ANALYSIS | ENANTIOSELECTIVE OXIDATION | HYDROGEN-BOND | SULFIDES | MATERIALS SCIENCE, MULTIDISCIPLINARY | CRYSTALLOGRAPHY | CHEMISTRY, MULTIDISCIPLINARY | LEAVING GROUPS | PI INTERACTIONS | DIALKYL SULFOXIDES | MOLECULAR-CRYSTALS
Journal Article
12/2019, Volume 21, Issue 47, pp. 7224 - 7232
Along the lines of a systematic investigation of conformational constraints promoted by weak interactions, the aryl-stacked structures of some chiral cyclic... 
Journal Article
ISSN 1477-0520, 12/2016, Volume 14, Issue 48, pp. 11438 - 11445
Regio- and stereo-selective reduction of substituted 1,3-aryldiketones, investigated in the presence of different whole cell microorganisms, was found to... 
Journal Article
Tetrahedron, ISSN 0040-4020, 07/2015, Volume 71, Issue 29, pp. 4810 - 4816
After the discovery of a few cases of lower enantioselectivity in the oxidation of aryl benzyl sulfides with hydroperoxides in the presence of a complex... 
Titanium | Sulfoxide | X-ray diffraction | Hydrobenzoin | CD spectra | ROUTE | ASYMMETRIC-SYNTHESIS | ALKYL | RESOLUTION | CHEMISTRY, ORGANIC | LEAVING GROUPS | DIALKYL SULFOXIDES | FLUORINE SUBSTITUTION | BOND | INTRAMOLECULAR PUMMERER REACTION | Sulfides | Oxidation-reduction reaction | Chemical properties | Enantiomers
Journal Article
NEW JOURNAL OF CHEMISTRY, ISSN 1144-0546, 04/2019, Volume 43, Issue 15, pp. 5940 - 5947
Two crystalline benzyl phenyl sulfides, bearing at the same time both a pentafluorophenyl and a nitrophenyl moiety in two different assemblies, were... 
CHARGE-DENSITY | SULFOXIDES | LIGANDS | HYDROGEN-BOND | ENANTIOSELECTIVE OXIDATION | CHEMISTRY, MULTIDISCIPLINARY | CENTER-DOT-F | INTERMOLECULAR INTERACTIONS
Journal Article