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Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 8754 - 8786
This Review summarizes the advancements in Pd-catalyzed C­(sp3)–H activation via various redox manifolds, including Pd(0)/Pd­(II), Pd­(II)/Pd­(IV), and... 
UNACTIVATED C(SP)-H BONDS | CROSS-COUPLING REACTIONS | DIRECT ARYLATION | BETA-C(SP)-H ARYLATION | INTERMOLECULAR AMINATION | O-ALLYL ETHERS | ALIPHATIC CARBON-ATOMS | ALPHA-AMINO-ACIDS | STEREOSELECTIVE-SYNTHESIS | DIRECTING-GROUP | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2011, Volume 133, Issue 20, pp. 7652 - 7655
C–H amination of N-aryl benzamides with O-benzoyl hydroxylamines has been achieved with either Pd(II) or Pd(0) catalysts. Furthermore, we demonstrate that... 
C(SP)-H BONDS | CARBAZOLE | TEMPERATURE | ALKYLATION | AMIDATION | ELECTROPHILIC AMINATION | N BOND FORMATION | INHIBITORS | DIORGANOZINC REAGENTS | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2015, Volume 137, Issue 5, pp. 2042 - 2046
C–H arylation via a Pd­(II)/Pd­(IV) catalytic cycle has been one of the most extensively studied C–H activation reactions since the 1990s. Despite the rapid... 
C(SP)-H BONDS | PALLADIUM | ACTIVATION | ACIDS | FUSED INDOLINES | CHEMISTRY | CHEMISTRY, MULTIDISCIPLINARY | Amines - chemistry | Hydrocarbons, Aromatic - chemistry | Catalysis | Stereoisomerism | Palladium - chemistry
Journal Article
Chemical reviews, ISSN 0009-2665, 7/2017, Volume 117, Issue 13, pp. 8754 - 8786
This Review summarizes the advancements in Pd-catalyzed C(sp 3 )–H activation via various redox manifolds, including Pd(0)/Pd(II), Pd(II)/Pd(IV), and... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 09/2010, Volume 132, Issue 37, pp. 12862 - 12864
Journal Article
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, p. 8754
This Review summarizes the advancements in Pd-catalyzed C(sp3)-H activation via various redox manifolds, including Pd(0)/Pd(II), Pd(II)/Pd(IV), and... 
Carbon-carbon composites | Regioselectivity | Hydrocarbons | Chemical reactions | Alkanes | Activation | Palladium | Selectivity | Carbon | Chemistry | Hydrogen bonds | Chemical bonds | Catalysis | Chemical elements
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2012, Volume 134, Issue 33, pp. 13565 - 13568
A Rh-catalyzed intermolecular coupling of diazomalonates with arene C–H bonds is reported. The reaction is initiated by electrophilic C–H activation, which is... 
PALLADIUM | ACTIVATION | INSERTION | CROSS-COUPLING REACTION | ARYL | ALDEHYDES | STEREOSELECTIVE-SYNTHESIS | N-CHLOROAMINES | TERT-BUTYL HYDROPEROXIDE | CHEMISTRY, MULTIDISCIPLINARY | DIAZOESTERS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2012, Volume 134, Issue 45, pp. 18570 - 18572
Journal Article
ORGANIC LETTERS, ISSN 1523-7060, 02/2019, Volume 21, Issue 4, pp. 984 - 988
An efficient method for the coupling of N-alkylamines with silicon enolates to generate beta-amino carbonyl compounds is disclosed. These reactions proceed by... 
ACTIVATION | OXIDATIVE MANNICH REACTION | HYDROGENATION | PHOTOREDOX | CYCLOHEXA-1,4-DIENES | TERTIARY-AMINES | ALPHA-FUNCTIONALIZATION | NITROGEN | CHEMISTRY, ORGANIC | DUAL CATALYSIS | LEWIS PAIRS
Journal Article
by Gai, LZ and To, CT and Chan, KS
TETRAHEDRON LETTERS, ISSN 0040-4039, 11/2014, Volume 55, Issue 46, pp. 6373 - 6376
Free base phthalocyanine H-2(obopc) in 3 mol % loading catalyzed the direct C-H arylation of benzene with aryl iodides. (C) 2014 Published by Elsevier Ltd. 
HALIDES | Phthalocyanine | REAGENTS | BENZENE | Organocatalyst | BUTOXIDE | CHEMISTRY, ORGANIC | ARYL | C-H arylation | Biaryls
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 05/2016, Volume 57, Issue 19, pp. 2121 - 2124
Copper-catalyzed C-H sulfonylation of 8-aminoquinoline scaffolds in the unusual C5 position was developed. The protocol using inexpensive CuI as the catalyst... 
Quinoline | C-H activation | Radical reactions | Regioselectivity | Copper | ACTIVATION | RH(I)-CATALYZED DIRECT ARYLATION | VINYL SULFONES | ALKYLATION | CHEMISTRY, ORGANIC | BOND FORMATION | SELECTIVE ALKENYLATION | PYRIDINES | FUNCTIONALIZATION | QUINOLINE N-OXIDES | C-8 POSITION | Pets | Dichloropropane | Chemical tests and reagents | Chlorides | Nitrogen compounds | Organosulfur compounds
Journal Article
Organic Letters, ISSN 1523-7060, 08/2009, Volume 11, Issue 15, pp. 3174 - 3177
A Pd(OAc)2-catalyzed protocol for decarboxylative arylation of aromatic C−H bond was developed using aryl acylperoxides as inexpensive aryl sources. Substrates... 
FUNCTIONALIZATION | HALIDES | ACTIVATION | INSERTION | CROSS-COUPLING REACTION | COMPLEXES | BIARYL SYNTHESIS | AROMATIC CARBOXYLATES | CHEMISTRY, ORGANIC | BENZOIC-ACIDS | Hydrogen Bonding | Benzoyl Peroxide - chemistry | Organometallic Compounds - chemistry | Catalysis | Hydrogen - chemistry | Palladium - chemistry | Carbon - chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2015, Volume 54, Issue 38, pp. 11143 - 11146
Journal Article
Organic Letters, ISSN 1523-7060, 10/2012, Volume 14, Issue 20, pp. 5306 - 5309
A C–H arylation with aryl chloride is made viable through a transition-metal-free approach. In the presence of a simple diol associating with KOt-Bu, various... 
HALIDES | CROSS-COUPLING REACTIONS | ACTIVATION | BENZENE | HETEROCYCLES | MEDIATED SYNTHESIS | POTASSIUM TERT-BUTOXIDE | CHEMISTRY, ORGANIC | UNACTIVATED ARENES | DERIVATIVES | CYCLIZATION | Molecular Structure | Chlorides - chemistry | Hydrogen Bonding | Phenanthridines - chemistry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2015, Volume 137, Issue 5, p. 2042
Journal Article
Organic Letters, ISSN 1523-7060, 02/2011, Volume 13, Issue 3, pp. 522 - 525
An efficient and conceptually new method for oxidative amination of azoles with tertiary amines via copper-catalyzed C−H and C−N bond activation has been... 
DIOXYGEN ACTIVATION | PALLADIUM | HETEROARENES | DIRECT ARYLATION | INTERMOLECULAR AMINATION | SODIUM-CYANIDE | EFFICIENT SYNTHESIS | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | CARBON-HYDROGEN BONDS | DIRECT ALKYNYLATION
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2017, Volume 56, Issue 23, pp. 6544 - 6547
A new protocol for amide‐directed ortho and lateral C−H sodiation is enabled by sodium hydride (NaH) in the presence of either sodium iodide (NaI) or lithium... 
sodium hydride | amides | C−H activation | arenes | metalation | DEPROTONATION | ORGANOSODIUM | ORGANOPOTASSIUM COMPOUNDS | 2-INDANONES | CHEMISTRY, MULTIDISCIPLINARY | METHODOLOGY | C-H activation | IODIDE COMPOSITE | FRIES REARRANGEMENT | LITHIATION | ORTHO-METALATION | POLYSUBSTITUTED AROMATICS | Amides | Chemical tests and reagents | Aromatic compounds | Lithium compounds | Iodides | Sodium | Lithium | Sodium iodide | Intermediates
Journal Article
Organic Letters, ISSN 1523-7060, 09/2010, Volume 12, Issue 17, pp. 3926 - 3929
A Pd-catalyzed protocol for direct C−H bond acylation by cross coupling of aryl ketone oximes and aldehydes using tert-butyl hydroperoxide (TBHP) as oxidant... 
Oximes - chemistry | Combinatorial Chemistry Techniques | Oxidants - chemistry | Ketones - chemical synthesis | Stereoisomerism | Ketones - chemistry | Molecular Structure | Catalysis | Palladium - chemistry | tert-Butylhydroperoxide - chemistry | Acylation | Aldehydes - chemistry
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 07/2012, Volume 53, Issue 30, pp. 3911 - 3914
A general procedure for free porphyrin catalyzed direct C–H arylation of benzene was demonstrated. This air tolerant, transition-metal-free process provides a... 
Free porphyrin | Biaryls | Organocatalyst | C–H arylation | C-H arylation | ACTIVATION | CROSS-COUPLING REACTION | CHEMISTRY, ORGANIC | UNACTIVATED ARENES | REGIOSELECTIVE ARYLATION | CARBON BOND FORMATION | BUTOXIDE | ORGANIC HALIDES | PROMOTE | Benzene | Porphyrins
Journal Article
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