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Journal of Cluster Science, ISSN 1040-7278, 11/2019, Volume 30, Issue 6, pp. 1623 - 1631
This paper focuses on the life and scientific career of Paolo Chini (1928–1980), an Italian chemist with a great experimental ingenuity. In Italy and abroad he... 
Chemistry | Physical Chemistry | Polypropylene | Paolo Chini | Biography | Cluster | Catalysis | Inorganic Chemistry | Nanochemistry | MCC
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 07/2017, Volume 2017, Issue 25, pp. 3135 - 3143
The reduction of [Fe6C(CO)16]2– (1) with NaOH in DMSO or with Na/naphthalene in THF affords the highly reduced [Fe6C(CO)15]4– (2) monocarbide tetraanion. The... 
Iron | Carbonyl ligands | Structure elucidation | Carbides | Cluster compounds | Nuclear magnetic resonance spectroscopy | Naphthalene | Molecular structure | Decomposition reactions | Clusters | Protonation | NMR spectroscopy | Crystallography | Carbonyls
Journal Article
自然科学进展:英文版, ISSN 1002-0071, 2016, Volume 26, Issue 5, pp. 461 - 466
The hetero-metallic [Sb@Rh12(CO)27]3-cluster has been known as for over three decades thanks to Vidal and co-workers, and represents the first example of an... 
Antimony | Synthesis | Carbonyl cluster | Rhodium | Crystal structure
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 07/2017, Volume 2017, Issue 25, pp. 3134 - 3134
Invited for the cover of this issue is the group of Stefano Zacchini from Bologna University, Italy. The cover image shows the effect of aurophilic... 
Gold | Fragments | Clusters | Iron | Assembly | Carbonyls | Fragmentation
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 07/2017, Volume 2017, Issue 25, pp. 3133 - 3133
The cover picture shows the assembly of a hexanuclear iron carbide tetraanionic cluster with two cationic gold–phosphine fragments, which is driven by the... 
Diffraction patterns | Gold | Single crystals | Fragments | Clusters | Iron | Assembly | Carbonyls | Fragmentation
Journal Article
Dalton Transactions, ISSN 1477-9226, 2018, Volume 47, Issue 13, pp. 4467 - 4477
The reactions of [Pt3n(CO)6n]2- (n = 2-5) homoleptic Chini-type clusters with increasing amounts of 1,3,5-triaza-7-phosphaadamantane (PTA) result in the... 
Substitutes | Single crystals | Toxicity | Platinum | Clusters | Cytotoxicity | Oxidation | Chemical synthesis | Cobalt | Carbonyls
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 06/2016, Volume 55, Issue 12, pp. 6068 - 6079
The molecular [Pt33(CO)38]2– nanocluster was obtained from the thermal decomposition of Na2[Pt15(CO)30] in methanol. The reaction of [Pt19(CO)22]4– with acids... 
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 02/2017, Volume 56, Issue 3, pp. 1655 - 1668
The reactions of [Pt3n (CO)6n ]2– (n = 2–4) homoleptic Chini-type clusters with stoichiometric amounts of Ph2PCH2CH2PPh2 (dppe) result in the heteroleptic... 
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 02/2018, Volume 57, Issue 3, pp. 1136 - 1147
The reaction of [NEt4]2[Ni6(CO)12] in thf with 0.5 equiv of PCl3 affords the monophosphide [Ni11P­(CO)18]3– that in turn further reacts with PCl3 resulting in... 
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 11/2017, Volume 849-850, pp. 299 - 305
This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction... 
Carbide | Cluster compound | Electrochemistry | Nickel | Carbonyl ligand
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 06/2017, Volume 56, Issue 11, pp. 6343 - 6351
The reaction of [Rh (CO) ] with BiCl under N and at room temperature results in the formation of the new heterometallic [Bi@Rh (CO) ] cluster in high yields.... 
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 01/2018, Volume 355, pp. 27 - 38
[Display omitted] In this review, the authors describe the role of gold in the chemistry of transition metal carbonyl clusters, a field that has been very... 
Clusters | Gold | Crystal structures | Metal carbonyls | HIGH-NUCLEARITY CLUSTERS | STRUCTURAL-CHARACTERIZATION | HETERONUCLEAR CLUSTERS | CHEMISTRY, INORGANIC & NUCLEAR | MOLECULAR-STRUCTURES | ELECTROCHEMICAL-BEHAVIOR | SOLID-STATE STRUCTURE | DYNAMIC-BEHAVIOR | GROUP-1B METALS | X-RAY CRYSTAL | CARBIDE CLUSTERS | Transition metal compounds | Structure | Analysis | Crystals
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 07/2018, Volume 57, Issue 13, pp. 7578 - 7590
The reactions of [Pt6(CO)12]2– with CH­(PPh2)2 (dppm), CH2C­(PPh2)2 (P^P), and Fe­(C5H4PPh2)2 (dppf) proceed via nonredox substitution and result in the... 
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 11/2017, Volume 849-850, p. 299
This paper reports a detailed study of the oxidation and reduction reactions of simple nickel mono-carbide and mono-acetlyde carbonyl clusters. The reduction... 
Electrochemistry | Electrochemical reactions | Carbides
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 01/2018, Volume 470, pp. 238 - 249
CO-protected molecular platinum nanoclusters comprising from 14 up to 44 metal atoms have been synthesized from Chini clusters and structurally characterized.... 
Cluster compound | Nanocluster | Molecular structure | Platinum | Carbonyl ligand
Journal Article
Journal of Cluster Science, ISSN 1040-7278, 3/2017, Volume 28, Issue 2, pp. 703 - 723
The reaction of the Collman’s reagent Na2Fe(CO)4 with two equivalents of Au(NHC)Cl (NHC = IMes, IPr, IBu) in thf results in the bimetallic Fe(CO)4(AuNHC)2... 
Gold | Chemistry | Physical Chemistry | N -Heterocyclic carbene | Heterometallic clusters | Iron | Catalysis | Inorganic Chemistry | Nanochemistry | Carbonyl | N-Heterocyclic carbene
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 01/2018, Volume 470, p. 238
To access, purchase, authenticate, or subscribe to the full-text of this article, please visit this link: http://dx.doi.org/10.1016/j.ica.2017.04.045 The... 
Analysis | Precious metal products
Journal Article
Inorganica Chimica Acta, ISSN 0020-1693, 01/2018, Volume 470, p. 238
The thermal decomposition of [Pt3n(CO)6n]2− (n = 2–10) Chini clusters results in the formation of globular molecular platinum carbonyl clusters, whose nature... 
Molecular structure | Thermal decomposition | Crystallization | Chemical compounds | Cobalt | Molecular chains | Single crystals | Anions | Naphthalene | Platinum | Clusters | Oxidation | Chemical synthesis | Carbonyls
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2014, Volume 53, Issue 28, pp. 7233 - 7237
Metal hydrides are of fundamental importance in chemistry, both as solid‐state materials and molecular compounds. The first low‐valent molecular metal cluster... 
aurophilicity | iron | cluster compounds | hydride ligands | carbonyl ligands | CRYSTAL | CHEMISTRY, MULTIDISCIPLINARY | TRANSITION-METAL HYDRIDES | GOLD(I) COMPLEXES | NEUTRON-DIFFRACTION ANALYSIS | RARE-EARTH | X-RAY | LIGAND | 4-COORDINATE HYDROGEN-ATOM | THEORETICAL CHEMISTRY | Nuclear magnetic resonance spectroscopy | Clathrate compounds
Journal Article
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