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1. Full Text Electronic, molecular weight, molecular volume, and financial cost-scaling and comparison of two-photon absorption efficiency in disparate molecules (organometallic complexes for nonlinear optics. 48.) - A response to "comment on 'organometallic complexes for nonlinear optics. 45. Dispersion of the third-order nonlinear optical properties of triphenylamine-cored alkynylruthenium dendrimers.'
by Schwich, Torsten and Cifuentes, Marie P and Gugger, Paul A and Samoc, Marek and Humphrey, Mark G
Advanced Materials, ISSN 0935-9648, 03/2011, Volume 23, Issue 12, pp. 1433 - 1435
nonlinear optics | dendrimers | organometallics
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2. Full Text Mixed-metal cluster chemistry. 39. Syntheses and X-ray structures of Mo.sub.3Ir.sub.3.sub.3 and Mo.sub.3RhIr.sub.3
by Fu, Junhong and Randles, Michael D and Moxey, Graeme J and Stranger, Rob and Cifuentes, Marie P and Humphrey, Mark G
Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2017, Volume 829, p. 66
To access, purchase, authenticate, or subscribe to the full-text of this article, please visit this link: http://dx.doi.org/10.1016/j.jorganchem.2016.10.016... 
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3. Full Text Mixed-metal cluster chemistry. 39. Syntheses and X-ray structures of Mo3Ir3(μ4-η2-CO)(μ3-CO)(CO)10(η5-C5H5)3 and Mo3RhIr3(μ-CO)4(CO)7(η5-C5H5)3(η5-C5Me5)
by Fu, Junhong and Randles, Michael D and Moxey, Graeme J and Stranger, Rob and Cifuentes, Marie P and Humphrey, Mark G
Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2017, Volume 829, pp. 66 - 70
Thermolysis of tetrahedral Mo Ir (μ-CO) (CO) (η -C H ) in refluxing toluene affords small amounts of Mo Ir (μ -η -CO)(μ -CO)(CO) (η -C H ) ( . Reaction of with... 
Cluster | Iridium | Rhodium | Carbonyl | Molybdenum
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4. Full Text Mixed-metal cluster chemistry. 39. Syntheses and X-ray structures of Mo 3 Ir 3 (μ 4 -η 2 -CO)(μ 3 -CO)(CO) 10 (η 5 -C 5 H 5 ) 3 and Mo 3 RhIr 3 (μ-CO) 4 (CO) 7 (η 5 -C 5 H 5 ) 3 (η 5 -C 5 Me 5 )
by Fu, Junhong and Randles, Michael D and Moxey, Graeme J and Stranger, Rob and Cifuentes, Marie P and Humphrey, Mark G
Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2017, Volume 829, pp. 66 - 70
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5. Full Text Mixed-metal cluster chemistry. 39. Syntheses and X-ray structures of Mo.sub.3Ir.sub.3([mu].sub.4-I[middle dot].sup.2-CO).sub.10(I[middle dot].sup.5-C.sub.5H.sub.5).sub.3 and Mo.sub.3RhIr.sub.3.sub.7(I[middle dot].sup.5-C.sub.5H.sub.5).sub.3(I[middle dot].sup.5-C.sub.5Me.sub.5)
by Fu, Junhong and Randles, Michael D and Moxey, Graeme J and Stranger, Rob and Cifuentes, Marie P and Humphrey, Mark G
Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2017, Volume 829, p. 66
Thermolysis of tetrahedral Mo.sub.2Ir.sub.2([mu]-CO).sub.3(CO).sub.7(I*.sup.5-C.sub.5H.sub.5).sub.2 in refluxing toluene affords small amounts of... 
Pyrolysis
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6. Full Text Mixed-metal cluster chemistry. 35. Syntheses and structural studies of Mo3Ir3(μ3-O)(μ-CO)3(CO)8(η5-C5H5)3, Mo4Ir4(μ-CO)4(CO)9(η5-C5H5)4 and Mo3Ir5(μ-CO)3(Cl)(CO)6(η5-C5H5)3(η5-C5HMe4)
by Fu, Junhong and Moxey, Graeme J and Cifuentes, Marie P and Humphrey, Mark G
Journal of Organometallic Chemistry, ISSN 0022-328X, 09/2015, Volume 792, pp. 46 - 50
The reaction of Ir(CO) ( -C HMe ) with Mo Ir (μ-CO) (CO) ( -C H ) affords a complex mixture from which three structurally-characterized products were obtained... 
Crystal structures | Cluster | Cyclopentadienyl | Iridium | Molybdenum
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7. Full Text Metal alkynyl complexes as switchable NLO systems
by Green, Katy A and Cifuentes, Marie P and Samoc, Marek and Humphrey, Mark G
Coordination Chemistry Reviews, ISSN 0010-8545, 2011, Volume 255, Issue 21, pp. 2530 - 2541
Progress in employing metal alkynyl complexes as nonlinear optical (NLO) switchable systems is reviewed. The origin of NLO effects in molecules is summarized,... 
Hyperpolarizabilities | Molecular switches | Organometallic | Alkynyl complexes | Nonlinear optics | PHOTOCHROMISM | ORGANOMETALLIC COMPLEXES | DONOR-ACCEPTOR MOLECULE | CONFORMATIONAL DYNAMICS | CHEMISTRY, INORGANIC & NUCLEAR | 2ND-HARMONIC GENERATION | LUMINESCENT SENSORS | BACTERIORHODOPSIN | NONLINEAR-OPTICAL-PROPERTIES | 1ST HYPERPOLARIZABILITIES | DINUCLEAR IRON(II)
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8. Full Text Mixed-metal cluster chemistry. 35. Syntheses and structural studies of Mo.sub.3Ir.sub.3.sub.8(I[middle dot].sup.5-C.sub.5H.sub.5).sub.3, Mo.sub.4Ir.sub.4.sub.9(I[middle dot].sup.5-C.sub.5H.sub.5).sub.4 and Mo.sub.3Ir.sub.5.sub.6(I[middle dot].sup.5-C.sub.5H.sub.5).sub.3(I[middle dot].sup.5-C.sub.5HMe.sub.4)
by Fu, Junhong and Moxey, Graeme J and Cifuentes, Marie P and Humphrey, Mark G
Journal of Organometallic Chemistry, ISSN 0022-328X, 09/2015, Volume 792, p. 46
The reaction of Ir(CO).sub.2(I*.sup.5-C.sub.5HMe.sub.4) with Mo.sub.2Ir.sub.2([mu]-CO).sub.3(CO).sub.7(I*.sup.5-C.sub.5H.sub.5).sub.2 affords a complex mixture... 
Molybdenum
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9. Full Text Mixed-metal cluster chemistry. 35. Syntheses and structural studies of Mo 3 Ir 3 (μ 3 -O)(μ-CO) 3 (CO) 8 ( η 5 -C 5 H 5 ) 3 , Mo 4 Ir 4 (μ-CO) 4 (CO) 9 ( η 5 -C 5 H 5 ) 4 and Mo 3 Ir 5 (μ-CO) 3 (Cl)(CO) 6 ( η 5 -C 5 H 5 ) 3 ( η 5 -C 5 HMe 4 )
by Fu, Junhong and Moxey, Graeme J and Cifuentes, Marie P and Humphrey, Mark G
Journal of Organometallic Chemistry, ISSN 0022-328X, 09/2015, Volume 792, pp. 46 - 50
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10. Full Text Optical limiting properties of (reduced) graphene oxide covalently functionalized by coordination complexes
by Dissanayake, D.M. Aradhana S and Cifuentes, Marie P and Humphrey, Mark G
Coordination Chemistry Reviews, ISSN 0010-8545, 11/2018, Volume 375, pp. 489 - 513
The nonlinear optical (NLO) and optical limiting (OL) properties of graphene oxide (GO), reduced graphene oxide (RGO), and particularly GO/RGO coordination... 
Optical limiting | Graphene oxide | Nonlinear optics | Phthalocyanines | Porphyrins | LASER-PULSES | 2-PHOTON ABSORPTION | NONLINEAR-SCATTERING | PHTHALOCYANINE HYBRIDS | EXFOLIATED GRAPHITE OXIDE | NANOTUBE DISPERSIONS | CHEMISTRY, INORGANIC & NUCLEAR | HYBRID MATERIAL | COLLOIDAL SUSPENSIONS | REVERSE-SATURABLE ABSORPTION | CARBON-BLACK SUSPENSIONS | Hydroxides | Graphene | Analysis | Phthalocyanins | Graphite | Excited state chemistry
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11. Full Text Facile hydrothermal synthesis and optical limiting properties of TiO 2 -reduced graphene oxide nanocomposites
by Wang, Aijian and Yu, Wang and Fang, Yu and Song, Yinglin and Jia, Ding and Long, Lingliang and Cifuentes, Marie P and Humphrey, Mark G and Zhang, Chi
Carbon, ISSN 0008-6223, 08/2015, Volume 89, pp. 130 - 141
TiO 2 /reduced graphene oxide (RGO) nanocomposites Gx (RGO titania nanocomposite, x grams tetrabutyl titanate per 0.03 g RGO, x = 0.25, 0.50, 1.00) were... 
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12. Full Text Quadratic and cubic hyperpolarizabilities of nitro-phenyl/-naphthalenyl/-anthracenyl alkynyl complexesOrganometallic complexes for nonlinear optics, part 61. For part 60 see T. Schwich, A. Barlow, M. P. Cifuentes, J. Szeremeta, M. Samoc, M. G. Humphrey, Chem. - Eur. J., 2017, 23, 8395-8399.Electronic supplementary information (ESI) available: ESI for this article contains descriptions of syntheses, full NMR and UV-Vis spectra, crystallographic data, cyclic voltammetric and spectroelectrochemical traces, details of the hyper-Rayleigh scattering and Z-scan experiments, and complete computational details and results. CCDC 1452957-1452969. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8dt00155c
by Du, Jun and Kodikara, Mahesh S and Moxey, Graeme J and Morshedi, Mahbod and Barlow, Adam and Quintana, Cristóbal and Wang, Genmiao and Stranger, Robert and Zhang, Chi and Cifuentes, Marie P and Humphrey, Mark G
ISSN 1477-9226, 3/2018, Volume 47, Issue 13, pp. 456 - 4571
1-Nitronaphthalenyl-4-alkynyl and 9-nitroanthracenyl-10-alkynyl complexes [M](C&z.tbd;C-4-C 10 H 6 -1-NO 2 ) ([M] = trans -[RuCl(dppe) 2 ] ( 6b ), trans... 
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13. Full Text Blue-shifted emission and enhanced quantum efficiency: Via π-bridge elongation in carbazole-carborane dyads
by Wang, Zhaojin and Jiang, Peng and Wang, Tianyu and Moxey, Graeme J and Cifuentes, Marie P and Zhang, Chi and Humphrey, Mark G
Physical Chemistry Chemical Physics, ISSN 1463-9076, 2016, Volume 18, Issue 23, pp. 15719 - 15726
Carbazole-carborane linear dyads and di(carbazole)-carborane V-shaped dyads with phenyleneethynylene-based bridges have been synthesized. The V-shaped dyads... 
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14. Full Text Group 8 metal alkynyl complexes for nonlinear optics
by Grelaud, Guillaume and Cifuentes, Marie P and Paul, Frédéric and Humphrey, Mark G
Journal of Organometallic Chemistry, ISSN 0022-328X, 02/2014, Volume 751, pp. 181 - 200
Studies of the nonlinear optical (NLO) properties of Group 8 metal alkynyl complexes are summarized, with particular focus on results since 2003; structure–NLO... 
Acetylide complexes | Hyperpolarizabilities | Cubic nonlinearities | Alkynyl complexes | Nonlinear optics | Quadratic nonlinearities | THIN-FILMS | CONJUGATED WIRES | DIPOLAR ALKYNYLRUTHENIUM COMPLEXES | ARYLALKYNYL COMPLEXES | ORGANOMETALLIC COMPLEXES | CHEMISTRY, ORGANIC | MOLECULAR QUADRATIC HYPERPOLARIZABILITIES | CUBIC HYPERPOLARIZABILITIES | RAY CRYSTAL-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR | NLO PROPERTIES | Organic chemistry | Chemical Sciences
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15. Full Text Exceptional Two-Photon Absorption in Alkynylruthenium-Gold Nanoparticle Hybrids
by Quintana, Cristóbal and Morshedi, Mahbod and Wang, Huan and Du, Jun and Cifuentes, Marie P and Humphrey, Mark G
Nano Letters, ISSN 1530-6984, 2019, Volume 19, Issue 2, pp. 756 - 760
Ruthenium alkynyl "star" complexes with tri(2-thienyl)-, tris(1,2,3-triazolyl)-, or triphenyl-benzene cores stabilize gold nanoparticles (AuNPs). Cyclic... 
nonlinear optics | inorganic materials | metal alkynyl complexes | organometallics | Gold nanoparticles | PHYSICS, CONDENSED MATTER | CROSS-SECTIONS | COMPLEX | PHYSICS, APPLIED | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY | DENDRIMERS | CHEMISTRY, MULTIDISCIPLINARY | CLUSTERS | NONLINEAR-OPTICAL PROPERTIES
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16. Full Text Increased optical nonlinearities of graphene nanohybrids covalently functionalized by axially-coordinated porphyrins
by Wang, Aijian and Long, Lingliang and Zhao, Wei and Song, Yinglin and Humphrey, Mark G and Cifuentes, Marie P and Wu, Xingzhi and Fu, Yongsheng and Zhang, Dongdong and Li, Xiufen and Zhang, Chi
Carbon, ISSN 0008-6223, 03/2013, Volume 53, pp. 327 - 338
Two graphene oxide (GO)-based nanohybrid materials possessing covalent linkages to axially-coordinated tetraphenylporphyrin (TPP), GO-TPP, were prepared and... 
PHTHALOCYANINE MOIETIES | REVERSE SATURABLE ABSORPTION | ELECTRON-TRANSFER | EXCITED-STATE | HETEROTHIOMETALLIC CLUSTERS | HYBRID MATERIAL | LIMITING PROPERTIES | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | PHOSPHORUS(V) PORPHYRINS | GRAPHITE OXIDE | WALLED CARBON NANOTUBES | Atomic force microscopy | Graphene | Optical properties | Analysis | Graphite | Fluorescence | Chemical properties | Universities and colleges | X-ray spectroscopy | Raman spectroscopy | Porphyrins | X-rays | Nonlinearity | Nanostructure | Constraining
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17. Full Text Switching the Cubic Nonlinear Optical Properties of an Electro‐, Halo‐, and Photochromic Ruthenium Alkynyl Complex Across Six States
by Green, Katy A and Cifuentes, Marie P and Corkery, T. Christopher and Samoc, Marek and Humphrey, Mark G
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2009, Volume 48, Issue 42, pp. 7867 - 7870
More than on and off: The title complex (see picture) comprises addressable modules that respond independently to protic (alkynyl ligand⇄vinylidene ligand),... 
alkynyl complexes | nonlinear optics | molecular devices | organometallics | nonlinear absorption | Organometallics | Nonlinear absorption | Alkynyl complexes | Nonlinear optics | Molecular devices | ACETYLIDES | ORGANOMETALLIC COMPLEXES | ABSORPTION | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | HYPERPOLARIZABILITIES
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18. Full Text Phosphine, isocyanide, and alkyne reactivity at pentanuclear molybdenum/tungsten-iridium clustersElectronic supplementary information (ESI) available: Synthesis and spectroscopic characterization details for 3b, 4b, 4c, 4d, 5b, 8b, 8c, 9b, and 10b, X-ray crystallographic data in CIF format for 3a, 4a-4c, 5b, 6, 7a, 8a, 8b, and 9a, crystal data for 3a, 4a-4c, 5b, 6, 7a, 8a, 8b, and 9a, ORTEP plots of 4b, 4c, 8a, and 8b, and one of the two crystallographically distinct molecules of each of 6 and 7a, and UV-vis spectral data during reduction of 8b. CCDC 1018833 (3a), 1018834 (4a), 1018835 (4b), 1018836 (4c), 1018837 (5b), 1018838 (6), 1018839 (7a), 1018840 (8a), 1018841 (8b), and 1018842 (9a). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5dt00525f
by Simpson, Peter V and Randles, Michael D and Gupta, Vivek and Fu, Junhong and Moxey, Graeme J and Schwich, Torsten and Morshedi, Mahbod and Cifuentes, Marie P and Humphrey, Mark G
ISSN 1477-9226, 4/2015, Volume 44, Issue 16, pp. 7292 - 734
The trigonal bipyramidal clusters M 2 Ir 3 (μ-CO) 3 (CO) 6 (η 5 -C 5 H 5 ) 2 (η 5 -C 5 Me 4 R) (M = Mo, R = Me 1a , R = H; M = W, R = Me, H) reacted with... 
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19. Full Text Covalent functionalization of reduced graphene oxide with porphyrin by means of diazonium chemistry for nonlinear optical performance
by Wang, Aijian and Yu, Wang and Huang, Zhipeng and Zhou, Feng and Song, Jingbao and Song, Yinglin and Long, Lingliang and Cifuentes, Marie P and Humphrey, Mark G and Zhang, Long and Shao, Jianda and Zhang, Chi
Scientific Reports, ISSN 2045-2322, 03/2016, Volume 6, Issue 1, p. 23325
Reduced graphene oxide (RGO)-porphyrin (TPP) nanohybrids (RGO-TPP 1 and RGO-TPP 2) were prepared by two synthetic routes that involve functionalization of the... 
NONCOVALENT FUNCTIONALIZATION | LIMITING PROPERTIES | CHEMICAL-REDUCTION | MULTIDISCIPLINARY SCIENCES | NANOSHEETS | GRAPHITE OXIDE | POLYMERIZATION | ABSORPTION | CARBON NANOTUBES | Infrared spectroscopy | Salts | Fourier transforms | Transmission electron microscopy | Optical properties | Solubility | Chemical bonds | Electron microscopy | Raman spectroscopy | Photoelectron spectroscopy | Porphyrins
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20. Full Text Record Multiphoton Absorption Cross‐Sections by Dendrimer Organometalation
by Simpson, Peter V and Watson, Laurance A and Barlow, Adam and Wang, Genmiao and Cifuentes, Marie P and Humphrey, Mark G
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2016, Volume 55, Issue 7, pp. 2387 - 2391
Large increases in molecular two‐photon absorption, the onset of measurable molecular three‐photon absorption, and record molecular four‐photon absorption in... 
optically active materials | nonlinear optics | ruthenium | dendrimers | photonics | DESIGN | 2-PHOTON ABSORPTION | DISPERSION | CHEMISTRY, MULTIDISCIPLINARY | NONLINEAR-OPTICAL PROPERTIES | ALKYNYLRUTHENIUM DENDRIMERS | 3-PHOTON ABSORPTION | METAL-COMPLEXES | Dendrimers | Optical properties | Linkages | Transparency | Ruthenium | Metals | Solubility | I.R. radiation | Telecommunications | Photon absorption | Biological activity | Near infrared radiation | Absorption | Multiphoton absorption | Cross sections
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