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The New England Journal of Medicine, ISSN 0028-4793, 10/2018, Volume 379, Issue 15, pp. 1416 - 1430
Journal Article
Chemical Reviews, ISSN 0009-2665, 07/2017, Volume 117, Issue 13, pp. 8649 - 8709
Computational studies on carboxylate-assisted C–H activation and functionalization at group 8–10 transition metal centers are reviewed. This Review is... 
QUINOLINE N-OXIDES | C(SP)-H ACTIVATION | CATALYZED INTRAMOLECULAR ARYLATION | AMINO-ACID LIGANDS | BOND ACTIVATION | NONCOVALENT INTERACTIONS | DIRECTING-GROUP | CHEMISTRY, MULTIDISCIPLINARY | PROTON-ABSTRACTION MECHANISM | ASTERISK-IR | ACTIVATION/CYCLOADDITION REACTIONS
Journal Article
Nature Communications, ISSN 2041-1723, 04/2017, Volume 8, Issue 1, p. 15022
Organoboranes are some of the most synthetically valuable and widely used intermediates in organic and pharmaceutical chemistry. Their synthesis, however, is... 
FUNCTIONALIZATION | LITHIUM BORYL | ANION | DIANION | MULTIDISCIPLINARY SCIENCES | CENTERED NUCLEOPHILE | COMPLEXES | REACTIVITY | CHEMISTRY | BORYLLITHIUM | B BONDS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2017, Volume 56, Issue 47, pp. 15131 - 15135
The para‐selective C−H alkylation of aniline derivatives furnished with a pyrimidine auxiliary is herein reported. This reaction is proposed to take place via... 
reaction mechanisms | ruthenium | C−H activation | arenes | homogeneous catalysis | ENANTIOSELECTIVE DEAROMATIZATION | ACID | SPIROINDOLENINES | IRIDIUM | STEREOSELECTIVE MIGRATION | CHEMISTRY, MULTIDISCIPLINARY | DESYMMETRIZATION | ASYMMETRIC ALLYLIC SUBSTITUTIONS | C-H activation | DEAROMATIZATION REACTIONS | CARBON-CARBON | INDOLE ALKALOIDS | Aniline | Ruthenium | Catalysis | Derivatives | Catalysts | Alkylation
Journal Article
Dalton Transactions, ISSN 1477-9226, 09/2014, Volume 43, Issue 36, pp. 13545 - 13556
The manifold of reaction pathways for the oxidative addition of phenyl bromide and phenyl chloride substrates to phosphine-modified palladium(0) complexes has... 
CROSS-COUPLING REACTIONS | KNOWLEDGE-BASE | ZEROVALENT PALLADIUM | C-N | ORGANOMETALLIC CHEMISTRY | OLEFIN METATHESIS | CARBON-HETEROATOM | ACTIVE CATALYST | SUZUKI-MIYAURA | ARYL CHLORIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2017, Volume 56, Issue 51, pp. 16363 - 16366
Reactions of a magnesium‐based pinacolatoboryl nucleophile with the electrophilic organoboranes, 9‐BBN and Ph3B, provide facile B−B′ single bond formation.... 
boranes | diborane | magnesium | main-group chemistry | boryl groups | METAL-PROMOTED REACTIONS | NUCLEOPHILIC BORON | HYDRIDE ABSTRACTION | ORGANIC-SYNTHESIS | SINGLE | CARBORANES | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | HYDROBORANE | CHEMISTRY | Chemical tests and reagents | Isomerization | Organoboranes | Diborane | Magnesium | Bonding | Thermal stability | Communications | Communication
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2013, Volume 52, Issue 37, pp. 9776 - 9780
A meeting of borons: The homocoupling of a BB bond in an amine‐borane is reported to give a diborane coordinated to a RhI metal center (see picture; C... 
amine‐borane | X‐ray diffraction | dehydrogenative coupling | boron homocoupling | rhodium | X-ray diffraction | amine-borane | METAL-PROMOTED REACTIONS | ALKENE | ACTIVATION | IRIDIUM | HYDRIDES | COMPLEXES | POLYAMINOBORANES | CARBORANES | AMMONIA-BORANE | CHEMISTRY, MULTIDISCIPLINARY | CATALYSTS | Amines | Diborane | Boron | Pathways | Meetings | Mathematical analysis | Density functional theory | Bonding | Free energy
Journal Article
Dalton Transactions, ISSN 1477-9226, 12/2010, Volume 39, Issue 45, pp. 10833 - 10836
We have used dispersion-corrected DFT (DFT-D) together with solvation to examine possible mechanisms for reaction of PhX (X=Cl, Br, I) with Pd((PBu3)-Bu-t)(2)... 
CROSS-COUPLING REACTIONS | AMINATION | MECHANISM | CHLOROARENES | REACTIVITY | PALLADIUM COMPLEX | OXIDATIVE ADDITION | ARYL CHLORIDES | HALIDE-COMPLEXES | CATALYTIC CYCLE | CHEMISTRY, INORGANIC & NUCLEAR | Thermodynamics | Quantum Theory | Models, Chemical | Oxidation-Reduction | Solvents - chemistry | Halogens - chemistry | Kinetics | Palladium - chemistry
Journal Article
Journal Article
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