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CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 09/2019, Volume 55, Issue 71, pp. 10539 - 10542
The syntheses of substituted all-cis-1,2,3-trifluorocyclopropanes are described for the first time. The three fluorines located on each of the cyclopropyl... 
HEXAFLUOROCYCLOHEXANE | INHIBITION | DIPOLE-MOMENT | MECHANISM | RING | OZONOLYSIS | GENERATION | 1,2,3,4,5,6-HEXAFLUOROCYCLOHEXANE | CHEMISTRY, MULTIDISCIPLINARY | PHENYLCYCLOPROPYLAMINES | LIPOPHILICITY
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 47, pp. 6016 - 6019
A phosphorescent cage of the form [Pd4Ru8]24+ is reported. The cage was formed using the metalloligand [Ru(dtbubpy)2(qpy)]2+, where qpy =... 
X-ray diffraction | Phosphorescence | Cages | Nuclear magnetic resonance--NMR | Emission analysis
Journal Article
Organometallics, ISSN 0276-7333, 01/2018, Volume 37, Issue 1, pp. 30 - 39
A series of tert-butyl-substituted pincer ligands based on 1,3-diaminobenzene and 3-aminophenol scaffolds, tBu4PXCYP (1e, X = Y = NH; 1f, X = NH; Y = O) and... 
HYDROGENATION | MECHANISM | ALKANE TRANSFER-DEHYDROGENATION | REACTIVITY | CHEMISTRY, ORGANIC | C-H ACTIVATION | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Chemical Science, ISSN 2041-6520, 11/2019, Volume 10, Issue 46, pp. 10755 - 10764
The reaction of the magnesium(i) complexes [{(Arnacnac)Mg}2], (Arnacnac = HC(MeCNAr)2, Ar = Dip (2,6-iPr2C6H3), Dep (2,6-Et2C6H3), Mes (2,4,6-Me3C6H2), Xyl... 
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 60, pp. 8415 - 8418
A general route to aryl α,β,β-trifluorocyclopropanes is reported and aryl oxidation gave the corresponding α,β,β-trifluorocyclopropane carboxylic acid.... 
Organic chemistry | Cyclopropane | Thiophenol | Aromatic compounds | Amides | Oxidation | Fluorination | Chemical synthesis | Lipophilicity | Organic compounds
Journal Article
Tetrahedron, ISSN 0040-4020, 01/2019, Volume 75, Issue 1, pp. 47 - 56
Two modular synthetic approaches for the preparation of novel wide bite angle diphosphine ligands containing stereogenic P-atoms have been developed, leading... 
Wide bite angle ligand | Phosphinite borane | P-stereogenic ligand | Oxazaphospholidine | Ephedrine | PHOSPHORUS | XANTPHOS LIGANDS | ASYMMETRIC-SYNTHESIS | PHOSPHINE | HYDROGENATION | RESOLUTION | COMPLEXES | CHEMISTRY, ORGANIC | BORANE | STEREOSELECTIVE-SYNTHESIS | HYDROFORMYLATION | Resveratrol
Journal Article
Scientific Reports, ISSN 2045-2322, 12/2017, Volume 7, Issue 1, pp. 12282 - 14
Seven silicon(IV) phthalocyanine carboxylate esters (SiPcs, 1-7) with non-, partially-and per-fluorinated aliphatic (linear or branched at the alpha-carbon)... 
LIGHT-EMITTING-DIODES | SENSITIZED SOLAR-CELLS | EXCITATION-ENERGIES | CAMBRIDGE STRUCTURAL DATABASE | PHOTODYNAMIC THERAPY | MULTIDISCIPLINARY SCIENCES | METAL PHTHALOCYANINES | AXIAL LIGANDS | CRYSTAL-STRUCTURES | PHOTOPHYSICAL PROPERTIES | DENSITY-FUNCTIONAL THEORY | Chloroform | Esters | I.R. radiation | Photons | Silicon | Oxidation | Dichlorobenzene | Esterification
Journal Article
Dalton Transactions, ISSN 1477-9226, 2018, Volume 47, Issue 30, pp. 10281 - 10287
The mixed N-heterocyclic carbene (NHC) complexes NHCAlHxI3-x, where NHC is IDip or IMes ((HCNAr)(2)C:, Ar = 2,6-iPr(2)C(6)H(3) = Dip (IDip); or 2,4,6-Me3C6H2 =... 
RING EXPANSION | ALANE ADDUCTS | LEWIS BASE-ADDUCTS | BOND ACTIVATION | N-HETEROCYCLIC CARBENES | OXIDATIVE ADDITION | REDUCTIVE ELIMINATION | GROUP-13 TRIHYDRIDES | C-H | CHEMISTRY, INORGANIC & NUCLEAR | Aluminum | Benzene | Halogenation
Journal Article
Chemical Communications, ISSN 1359-7345, 11/2019, Volume 55, Issue 95, pp. 14295 - 14298
An unexpected and highly efficient reaction of dibenzo[a,e]cyclooctatetraene with Ag(i)F and N-bromosuccinamide in dichloromethane results in a sequential ring... 
Journal Article
Dalton Transactions, ISSN 1477-9226, 11/2019, Volume 48, Issue 45, pp. 16936 - 16942
Ligand exchange reactions between combinations of the complexes [{(Arnacnac)Mg}2], where Ar = 2,6-iPr2C6H3 (Dip), 2,6-Et2C6H3 (Dep), 2,4,6-Me4C6H2 (Mes), and... 
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 09/2019, Volume 2019, Issue 31-32, pp. 5169 - 5174
A serendipitously‐discovered process for the synthesis of heterocyclic products containing a novel fused indoline‐cyclobutanone ring system is reported. This... 
[2+2]‐Cycloaddition | Lewis base catalysis | Ketenes | Indolines | N‐Heterocycles | N-Heterocycles | ASYMMETRIC-SYNTHESIS | CYCLO-ADDITION REACTIONS | ENANTIOSELECTIVE SYNTHESIS | NITROGEN-HETEROCYCLES | CHEMISTRY, ORGANIC | TRICYCLIC-BETA-LACTONES | DYOTROPIC REARRANGEMENTS | KETO ACIDS | [2+2]-Cycloaddition | CATALYZED ALDOL-LACTONIZATION | RING-CLOSURE
Journal Article
Journal of Materials Chemistry C, ISSN 2050-7534, 2016, Volume 4, Issue 17, pp. 3726 - 3737
Combining a sterically bulky, electron-deficient 2-(2,4-difluorophenyl)-4-(2,4,6-trimethylphenyl) pyridine (dFMesppy) cyclometalating C boolean AND N ligand... 
ANCILLARY LIGANDS | PHYSICS, APPLIED | MATERIALS SCIENCE, MULTIDISCIPLINARY | DEVICES | ELECTROCHEMICAL-CELLS | PHOTOPHYSICAL PROPERTIES | DIODES | EMITTERS | GREEN | EFFICIENCY | ELECTROLUMINESCENCE | Iridium compounds | Electronic devices | Cationic | Emission | Organic light emitting diodes | Ligands | Bearing
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 01/2019, Volume 25, Issue 4, pp. 1064 - 1075
During an investigation into the potential union of Lewis basic isothiourea organocatalysis and gold catalysis, the formation of gold‐isothiourea complexes was... 
gold | N ligands | homogeneous catalysis | coordination chemistry | bioinorganic chemistry | Gold | Synthesis | Cell lines | Ligands | Catalytic activity | Catalysis | Iridium | Coordination compounds | Carbonyls
Journal Article
Advanced Materials, ISSN 0935-9648, 12/2018, Volume 30, Issue 51, pp. e1807138 - n/a
High-efficiency pure blue phosphorescent organic light-emitting diodes (OLEDs) remain one of the grand challenges, principally because the emissive complexes... 
iridium emitters | PHYSICS, CONDENSED MATTER | PHYSICS, APPLIED | NHC ligands | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | deep-blue emission | NANOSCIENCE & NANOTECHNOLOGY | CHEMISTRY, MULTIDISCIPLINARY | organic light-emitting diodes | Circuit components | Light-emitting diodes | Organic light emitting diodes | Iridium
Journal Article
ISSN 1359-7345, 8/2019, Volume 55, Issue 71, pp. 1539 - 1542
The syntheses of substituted all- cis -1,2,3-trifluorocyclopropanes are described for the first time. The three fluorines located on each of the cyclopropyl... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 10/2013, Volume 135, Issue 43, pp. 16066 - 16069
The synthesis, structural characterization, and acid base chemistry of [C(SiMe2OCH2CH2OMe)(3)] Na (2), a sterically encumbered zwitterionic organosodium... 
CARBENE | ACTIVATION | PHOSPHINES | COMPLEXES | FREE CATALYTIC-HYDROGENATION | REACTIVITY | BASICITY | CHEMISTRY, MULTIDISCIPLINARY | Lewis structures | Research | Chemical properties | Acids | Organometallic compounds
Journal Article
Chemical Communications, ISSN 1359-7345, 03/2015, Volume 51, Issue 23, pp. 4778 - 4781
We report the first example of BAC-Cu complex (BAC = bis-(diisopropylamino)cyclopropenylidene) and its use as a carbene-transfer reagent, allowing access to... 
ROOM-TEMPERATURE | N-HETEROCYCLIC CARBENE | LIGANDS | TRANSMETALATION | DIAMINOCYCLOPROPENYLIDENE | TERMINAL ALKYNES | SYSTEMS | COUPLING CATALYSIS | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | 3+2 CYCLOADDITION | Synthesis (chemistry) | Transition metals | Catalysts | Reagents | Palladium | Catalysis | Coordination compounds
Journal Article
ISSN 1359-7345, 11/2019, Volume 55, Issue 95, pp. 14295 - 14298
An unexpected and highly efficient reaction of dibenzo[ a , e ]cyclooctatetraene with Ag( i )F and N -bromosuccinamide in dichloromethane results in a... 
Journal Article