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1. Full Text High‐Efficiency Deep‐Blue‐Emitting Organic Light‐Emitting Diodes Based on Iridium(III) Carbene Complexes
by Pal, Amlan K and Krotkus, Simonas and Fontani, Mattia and Mackenzie, Campbell F. R and Cordes, David B and Slawin, Alexandra M. Z and Samuel, Ifor D. W and Zysman‐Colman, Eli
Advanced Materials, ISSN 0935-9648, 12/2018, Volume 30, Issue 50, pp. e1804231 - n/a
High‐efficiency pure blue phosphorescent organic light‐emitting diodes (OLEDs) remain one of the grand challenges, principally because the emissive complexes... 
deep‐blue emission | iridium emitters | organic light‐emitting diodes | NHC ligands | deep-blue emission | organic light-emitting diodes | IR(III) COMPLEXES | PHYSICS, CONDENSED MATTER | PHYSICS, APPLIED | CONSTANTS | TRANSITION-METAL-COMPLEXES | STABILITY | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | HOST | NANOSCIENCE & NANOTECHNOLOGY | CHEMISTRY, MULTIDISCIPLINARY | DEPENDENCE | FLUORESCENCE | MOLECULAR-ORIENTATION | EMISSION | PHOSPHORESCENT EMITTER | Circuit components | Light-emitting diodes | Iridium compounds | Quantum efficiency | Efficiency | Photoluminescence | Organic light emitting diodes | Phosphorescence | Iridium | Emitters | Diodes
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2. Full Text Fluorine containing cyclopropanes: synthesis of aryl substituted all-cis 1,2,3-trifluorocyclopropanes, a facially polar motif
by Fang, ZG and Cordes, DB and Slawin, AMZ and O'Hagan, D
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 09/2019, Volume 55, Issue 71, pp. 10539 - 10542
The syntheses of substituted all-cis-1,2,3-trifluorocyclopropanes are described for the first time. The three fluorines located on each of the cyclopropyl... 
HEXAFLUOROCYCLOHEXANE | INHIBITION | DIPOLE-MOMENT | MECHANISM | RING | OZONOLYSIS | GENERATION | 1,2,3,4,5,6-HEXAFLUOROCYCLOHEXANE | CHEMISTRY, MULTIDISCIPLINARY | PHENYLCYCLOPROPYLAMINES | LIPOPHILICITY
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3. Full Text A luminescent [Pd4Ru8]24+ supramolecular cage
by Rota Martir, Diego and Cordes, David B and Slawin, Alexandra M. Z and Escudero, Daniel and Jacquemin, Denis and Warriner, Stuart L and Zysman-Colman, Eli
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 47, pp. 6016 - 6019
A phosphorescent cage of the form [Pd4Ru8]24+ is reported. The cage was formed using the metalloligand [Ru(dtbubpy)2(qpy)]2+, where qpy =... 
X-ray diffraction | Phosphorescence | Cages | Nuclear magnetic resonance--NMR | Emission analysis
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4. Full Text Synthesis, Characterization, and Catalytic Properties of Iridium Pincer Complexes Containing NH Linkers
by Leveson-Gower, Reuben B and Webb, Paul B and Cordes, David B and Slawin, Alexandra M. Z and Smith, David M and Tooze, Robert P and Liu, Jianke
Organometallics, ISSN 0276-7333, 01/2018, Volume 37, Issue 1, pp. 30 - 39
A series of tert-butyl-substituted pincer ligands based on 1,3-diaminobenzene and 3-aminophenol scaffolds, tBu4PXCYP (1e, X = Y = NH; 1f, X = NH; Y = O) and... 
HYDROGENATION | MECHANISM | ALKANE TRANSFER-DEHYDROGENATION | REACTIVITY | CHEMISTRY, ORGANIC | C-H ACTIVATION | CHEMISTRY, INORGANIC & NUCLEAR
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5. Full Text Hydrocarbon-soluble, hexaanionic fulleride complexes of magnesium
by Lawrence, Samuel R and Ohlin, C. André and Cordes, David B and Slawin, Alexandra M. Z and Stasch, Andreas
Chemical Science, ISSN 2041-6520, 11/2019, Volume 10, Issue 46, pp. 10755 - 10764
The reaction of the magnesium(i) complexes [{(Arnacnac)Mg}2], (Arnacnac = HC(MeCNAr)2, Ar = Dip (2,6-iPr2C6H3), Dep (2,6-Et2C6H3), Mes (2,4,6-Me3C6H2), Xyl... 
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6. Full Text Fluorinated cyclopropanes: Synthesis and chemistry of the aryl α,β,β-trifluorocyclopropane motif
by Thomson, Connor J and Zhang, Qingzhi and Al-Maharik, Nawaf and Bühl, Michael and Cordes, David B and Slawin, Alexandra M. Z and O'Hagan, David
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 60, pp. 8415 - 8418
A general route to aryl α,β,β-trifluorocyclopropanes is reported and aryl oxidation gave the corresponding α,β,β-trifluorocyclopropane carboxylic acid.... 
Organic chemistry | Cyclopropane | Thiophenol | Aromatic compounds | Amides | Oxidation | Fluorination | Chemical synthesis | Lipophilicity | Organic compounds
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7. Full Text P-stereogenic wide bite angle diphosphine ligands
by Czauderna, Christine F and Slawin, Alexandra M.Z and Cordes, David B and van der Vlugt, Jarl Ivar and Kamer, Paul C.J
Tetrahedron, ISSN 0040-4020, 01/2019, Volume 75, Issue 1, pp. 47 - 56
Two modular synthetic approaches for the preparation of novel wide bite angle diphosphine ligands containing stereogenic P-atoms have been developed, leading... 
Wide bite angle ligand | Phosphinite borane | P-stereogenic ligand | Oxazaphospholidine | Ephedrine | PHOSPHORUS | XANTPHOS LIGANDS | ASYMMETRIC-SYNTHESIS | PHOSPHINE | HYDROGENATION | RESOLUTION | COMPLEXES | CHEMISTRY, ORGANIC | BORANE | STEREOSELECTIVE-SYNTHESIS | HYDROFORMYLATION | Resveratrol
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8. Full Text Near-Infrared Fluorescence of Silicon Phthalocyanine Carboxylate Esters
by Pal, Amlan K and Varghese, Shinto and Cordes, David B and Slawin, Alexandra M. Z and Samuel, Ifor D. W and Zysman-Colman, Eli
Scientific Reports, ISSN 2045-2322, 12/2017, Volume 7, Issue 1, pp. 12282 - 14
Seven silicon(IV) phthalocyanine carboxylate esters (SiPcs, 1-7) with non-, partially-and per-fluorinated aliphatic (linear or branched at the alpha-carbon)... 
LIGHT-EMITTING-DIODES | SENSITIZED SOLAR-CELLS | EXCITATION-ENERGIES | CAMBRIDGE STRUCTURAL DATABASE | PHOTODYNAMIC THERAPY | MULTIDISCIPLINARY SCIENCES | METAL PHTHALOCYANINES | AXIAL LIGANDS | CRYSTAL-STRUCTURES | PHOTOPHYSICAL PROPERTIES | DENSITY-FUNCTIONAL THEORY | Chloroform | Esters | I.R. radiation | Photons | Silicon | Oxidation | Dichlorobenzene | Esterification
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9. Full Text Normal and abnormal NHC coordination in cationic hydride iodide complexes of aluminium
by Trose, Michael and Burnett, Stuart and Bonyhady, Simon J and Jones, Cameron and Cordes, David B and Slawin, Alexandra M. Z and Stasch, Andreas
Dalton Transactions, ISSN 1477-9226, 2018, Volume 47, Issue 30, pp. 10281 - 10287
The mixed N-heterocyclic carbene (NHC) complexes NHCAlHxI3-x, where NHC is IDip or IMes ((HCNAr)(2)C:, Ar = 2,6-iPr(2)C(6)H(3) = Dip (IDip); or 2,4,6-Me3C6H2 =... 
RING EXPANSION | ALANE ADDUCTS | LEWIS BASE-ADDUCTS | BOND ACTIVATION | N-HETEROCYCLIC CARBENES | OXIDATIVE ADDITION | REDUCTIVE ELIMINATION | GROUP-13 TRIHYDRIDES | C-H | CHEMISTRY, INORGANIC & NUCLEAR | Aluminum | Benzene | Halogenation
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10. Full Text Unexpected α,α′-difluoroethers from Ag(i)F and N-bromosuccinimide reactions of dibenzo[a,e]cyclooctatetraene
by Fang, Zeguo and Gillatt, Roscoe Z and Slawin, Alexandra M. Z and Cordes, David B and Carpenter-Warren, Cameron L and O'Hagan, David
Chemical Communications, ISSN 1359-7345, 11/2019, Volume 55, Issue 95, pp. 14295 - 14298
An unexpected and highly efficient reaction of dibenzo[a,e]cyclooctatetraene with Ag(i)F and N-bromosuccinamide in dichloromethane results in a sequential ring... 
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11. Full Text Mechanistic insights of anionic ligand exchange and fullerene reduction with magnesium(i) compounds
by Lawrence, Samuel R and Cordes, David B and Slawin, Alexandra M. Z and Stasch, Andreas
Dalton Transactions, ISSN 1477-9226, 11/2019, Volume 48, Issue 45, pp. 16936 - 16942
Ligand exchange reactions between combinations of the complexes [{(Arnacnac)Mg}2], where Ar = 2,6-iPr2C6H3 (Dip), 2,6-Et2C6H3 (Dep), 2,4,6-Me4C6H2 (Mes), and... 
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12. Full Text Synthesis of Fused Indoline‐Cyclobutanone Derivatives via an Intramolecular [2+2] Cycloaddition
by Neyyappadath, Rifahath M and Greenhalgh, Mark D and Cordes, David B and Slawin, Alexandra M. Z and Smith, Andrew D
European Journal of Organic Chemistry, ISSN 1434-193X, 09/2019, Volume 2019, Issue 31-32, pp. 5169 - 5174
A serendipitously‐discovered process for the synthesis of heterocyclic products containing a novel fused indoline‐cyclobutanone ring system is reported. This... 
[2+2]‐Cycloaddition | Lewis base catalysis | Ketenes | Indolines | N‐Heterocycles | N-Heterocycles | ASYMMETRIC-SYNTHESIS | CYCLO-ADDITION REACTIONS | ENANTIOSELECTIVE SYNTHESIS | NITROGEN-HETEROCYCLES | CHEMISTRY, ORGANIC | TRICYCLIC-BETA-LACTONES | DYOTROPIC REARRANGEMENTS | KETO ACIDS | [2+2]-Cycloaddition | CATALYZED ALDOL-LACTONIZATION | RING-CLOSURE
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13. Full Text Solubilised bright blue-emitting iridium complexes for solution processed OLEDs
by Henwood, Adam F and Bansal, Ashu K and Cordes, David B and Slawin, Alexandra M. Z and Samuel, Ifor D. W and Zysman-Colman, Eli
Journal of Materials Chemistry C, ISSN 2050-7534, 2016, Volume 4, Issue 17, pp. 3726 - 3737
Combining a sterically bulky, electron-deficient 2-(2,4-difluorophenyl)-4-(2,4,6-trimethylphenyl) pyridine (dFMesppy) cyclometalating C boolean AND N ligand... 
ANCILLARY LIGANDS | PHYSICS, APPLIED | MATERIALS SCIENCE, MULTIDISCIPLINARY | DEVICES | ELECTROCHEMICAL-CELLS | PHOTOPHYSICAL PROPERTIES | DIODES | EMITTERS | GREEN | EFFICIENCY | ELECTROLUMINESCENCE | Iridium compounds | Electronic devices | Cationic | Emission | Organic light emitting diodes | Ligands | Bearing
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14. Full Text Chiral AuI‐ and AuIII‐Isothiourea Complexes: Synthesis, Characterization and Application
by Gasperini, Danila and Greenhalgh, Mark D and Imad, Rehan and Siddiqui, Shezaib and Malik, Anum and Arshad, Fizza and Choudhary, Muhammad Iqbal and Al‐Majid, Abdullah M and Cordes, David B and Slawin, Alexandra M. Z and Nolan, Steven P and Smith, Andrew D
Chemistry – A European Journal, ISSN 0947-6539, 01/2019, Volume 25, Issue 4, pp. 1064 - 1075
During an investigation into the potential union of Lewis basic isothiourea organocatalysis and gold catalysis, the formation of gold‐isothiourea complexes was... 
gold | N ligands | homogeneous catalysis | coordination chemistry | bioinorganic chemistry | Gold | Synthesis | Cell lines | Ligands | Catalytic activity | Catalysis | Iridium | Coordination compounds | Carbonyls
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15. Full Text High‐Efficiency Deep‐Blue‐Emitting Organic Light‐Emitting Diodes Based on Iridium(III) Carbene Complexes
by Pal, Amlan K and Krotkus, Simonas and Fontani, Mattia and Mackenzie, Campbell F. R and Cordes, David B and Slawin, Alexandra M. Z and Samuel, Ifor D. W and Zysman‐Colman, Eli
Advanced Materials, ISSN 0935-9648, 12/2018, Volume 30, Issue 51, pp. e1807138 - n/a
High-efficiency pure blue phosphorescent organic light-emitting diodes (OLEDs) remain one of the grand challenges, principally because the emissive complexes... 
iridium emitters | PHYSICS, CONDENSED MATTER | PHYSICS, APPLIED | NHC ligands | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | deep-blue emission | NANOSCIENCE & NANOTECHNOLOGY | CHEMISTRY, MULTIDISCIPLINARY | organic light-emitting diodes | Circuit components | Light-emitting diodes | Organic light emitting diodes | Iridium
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16. Full Text Fluorine containing cyclopropanes: synthesis of aryl substituted all-cis 1,2,3-trifluorocyclopropanes, a facially polar motifElectronic supplementary information (ESI) available. CCDC 1942268-1942271 and 1942891. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9cc05749h
by Fang, Zeguo and Cordes, David B and Slawin, Alexandra M. Z and O'Hagan, David
ISSN 1359-7345, 8/2019, Volume 55, Issue 71, pp. 1539 - 1542
The syntheses of substituted all- cis -1,2,3-trifluorocyclopropanes are described for the first time. The three fluorines located on each of the cyclopropyl... 
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17. Full Text A zwitterionic carbanion frustrated by boranes - Dihydrogen cleavage with weak lewis acids via an "inverse" frustrated lewis pair approach
by Li, Hui and Aquino, Adelia J. A and Cordes, David B and Hung-Low, Fernando and Hase, William L and Krempner, Clemens
Journal of the American Chemical Society, ISSN 0002-7863, 10/2013, Volume 135, Issue 43, pp. 16066 - 16069
The synthesis, structural characterization, and acid base chemistry of [C(SiMe2OCH2CH2OMe)(3)] Na (2), a sterically encumbered zwitterionic organosodium... 
CARBENE | ACTIVATION | PHOSPHINES | COMPLEXES | FREE CATALYTIC-HYDROGENATION | REACTIVITY | BASICITY | CHEMISTRY, MULTIDISCIPLINARY | Lewis structures | Research | Chemical properties | Acids | Organometallic compounds
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18. Full Text A simple access to transition metal cyclopropenylidene complexes
by Bidal, Yannick D and Lesieur, Mathieu and Melaimi, Mohand and Cordes, David B and Slawin, Alexandra M. Z and Bertrand, Guy and Cazin, Catherine S. J
Chemical Communications, ISSN 1359-7345, 03/2015, Volume 51, Issue 23, pp. 4778 - 4781
We report the first example of BAC-Cu complex (BAC = bis-(diisopropylamino)cyclopropenylidene) and its use as a carbene-transfer reagent, allowing access to... 
ROOM-TEMPERATURE | N-HETEROCYCLIC CARBENE | LIGANDS | TRANSMETALATION | DIAMINOCYCLOPROPENYLIDENE | TERMINAL ALKYNES | SYSTEMS | COUPLING CATALYSIS | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | 3+2 CYCLOADDITION | Synthesis (chemistry) | Transition metals | Catalysts | Reagents | Palladium | Catalysis | Coordination compounds
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19. Full Text Copper(I) Complexes Bearing Carbenes beyond Classical N-Heterocyclic Carbenes: Synthesis and Catalytic Activity in "click Chemistry"
by Bidal, Yannick D and Lesieur, Mathieu and Melaimi, Mohand and Nahra, Fady and Cordes, David B and Athukorala Arachchige, Kasun S and Slawin, Alexandra M. Z and Bertrand, Guy and Cazin, Catherine S. J
Advanced Synthesis and Catalysis, ISSN 1615-4150, 10/2015, Volume 357, Issue 14-15, pp. 3155 - 3161
The synthesis and characterization of abnormal N-heterocyclic carbene, cyclic (alkyl)(amino)carbene, and mesoionic carbene copper(I) complexes are reported.... 
click chemistry | copper | remote carbenes | abnormal carbenes | [3+2] cycloaddition | N-heterocyclic carbenes | AZIDES | CHEMISTRY, ORGANIC | 3+2 CYCLOADDITION | NHC LIGANDS | REMOTE | CHEMISTRY, APPLIED | EFFICIENT | BINDING | Heterocyclic compounds | Chemical properties | Metalorganic compounds | BEARINGS | Catalytic activity | Carbenes | COPPER OXIDE | Bearing | Synthesis (chemistry) | Synthesis | FABRICATION | Catalysis | ACTIVITY | COPPER COMPOUNDS | Alkynes
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20. Full Text Unexpected α,α′-difluoroethers from Ag(i)F and N-bromosuccinimide reactions of dibenzo[a,e]cyclooctatetraeneElectronic supplementary information (ESI) available. CCDC 1947537-1947542. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9cc06426e
by Fang, Zeguo and Gillatt, Roscoe Z and Slawin, Alexandra M. Z and Cordes, David B and Carpenter-Warren, Cameron L and O'Hagan, David
ISSN 1359-7345, 11/2019, Volume 55, Issue 95, pp. 14295 - 14298
An unexpected and highly efficient reaction of dibenzo[ a , e ]cyclooctatetraene with Ag( i )F and N -bromosuccinamide in dichloromethane results in a... 
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