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1. Spin states in biochemistry and inorganic chemistry
: influence on structure and reactivity
by Swart, Marcel, 1971- editor and Costas Salgueiro, Miquel, editor
2016, ISBN 1118898311, xix, 448 pages, 16 unnumbered pages of plates
It has long been recognized that metal spin states play a central role in the reactivity of important biomolecules, in industrial catalysis and in spin... 
Chemistry, Inorganic | Biochemistry | Nuclear spin | Free radicals (Chemistry)
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2. Full Text Nucleophilic Aryl Fluorination and Aryl Halide Exchange Mediated by a CuI/CuIII Catalytic Cycle
by Casitas, Alicia and Canta, Mercè and Solà, Miquel and Costas, Miquel and Ribas, Xavi
Journal of the American Chemical Society, ISSN 0002-7863, 12/2011, Volume 133, Issue 48, pp. 19386 - 19392
Copper-catalyzed halide exchange reactions under very mild reaction conditions are described for the first time using a family of model aryl halide substrates.... 
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3. Full Text Computational Insight into the Mechanism of Alkane Hydroxylation by Non-heme Fe(PyTACN) Iron Complexes. Effects of the Substrate and Solvent
by Postils, Verònica and Company, Anna and Solà, Miquel and Costas, Miquel and Luis, Josep M
Inorganic Chemistry, ISSN 0020-1669, 09/2015, Volume 54, Issue 17, pp. 8223 - 8236
The reaction mechanisms for alkane hydroxylation catalyzed by non-heme FeVO complexes presented in the literature vary from rebound stepwise to concerted... 
H BOND ACTIVATION | OXIDATION | RANGE ELECTRON-TRANSFER | ENERGY | CYTOCHROME-P450 ENZYMES | ACTIVE-SITES | REACTIVITY | IRON(IV)-OXO | C-H | WATER | CHEMISTRY, INORGANIC & NUCLEAR | Alkanes | Iron compounds | Chemical properties | Hydroxylation | Analysis | Solvent effect | Solvents | Computation | Acetonitrile | Iron | Optimization | Alquens | Oxidació | Alkenes | Compostos | Catàlisi | Ferro | Oxidation | Catalysis
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4. Full Text Selective C–H oxidation catalyzed by metalloporphyrins
by Costas, Miquel
Coordination Chemistry Reviews, ISSN 0010-8545, 2011, Volume 255, Issue 23, pp. 2912 - 2932
► Selective alkyl C–H bond oxidation reactions catalyzed by metalloporphyrin. ► Chemo, regio and stereoselective C–H oxidations mediated by iron, manganese and... 
C–H Oxidation | Metalloporphyrin | Selectivity | Metal–oxo species | Reaction mechanisms | High-valent | Metal-oxo species | C-H Oxidation | PI-CATION RADICALS | WATER-SOLUBLE METALLOPORPHYRINS | CYTOCHROME P450-CATALYZED HYDROXYLATION | HIGHLY EFFICIENT EPOXIDATION | IRON-PORPHYRIN COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | HYPERSENSITIVE MECHANISTIC PROBE | CHIRAL RUTHENIUM PORPHYRIN | FLASH-PHOTOLYSIS GENERATION | HETEROAROMATIC N-OXIDES | HIGH-VALENT IRON
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5. Full Text Mechanism of the Selective Fe-Catalyzed Arene Carbon–Hydrogen Bond Functionalization
by Postils, Verònica and Rodríguez, Mònica and Sabenya, Gerard and Conde, Ana and Díaz-Requejo, M. Mar and Pérez, Pedro J and Costas, Miquel and Solà, Miquel and Luis, Josep M
ACS Catalysis, ISSN 2155-5435, 05/2018, Volume 8, Issue 5, pp. 4313 - 4322
The complete chemoselective functionalization of aromatic C­(sp2)–H bonds of benzene and alkyl benzenes by carbene insertion from ethyl diazoacetate was... 
H functionalization | C-H activation | iron catalysis | C(sp | carbene transfer | DFT calculations | INSERTION | GOLD CATALYSIS | CHEMISTRY, PHYSICAL | DIAZO-COMPOUNDS | MOLECULAR COMPLEXITY | O-H BONDS | ARYL-ALPHA-DIAZOACETATES | ETHYL DIAZOACETATE | IRON PORPHYRIN CARBENES | C(sp)-H functionalization | AROMATIC C(SP)-H | PHENOLS
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6. Full Text Biologically Inspired C−H and C=C Oxidations with Hydrogen Peroxide Catalyzed by Iron Coordination Complexes
by Olivo, Giorgio and Cussó, Olaf and Costas, Miquel
Chemistry – An Asian Journal, ISSN 1861-4728, 11/2016, Volume 11, Issue 22, pp. 3148 - 3158
The development of catalysts for the selective oxidation of readily available hydrocarbons or organic precursors into oxygenated products is a long‐standing... 
oxidation | dihydroxylation | iron | epoxidation | C−H activation | NONHEME IRON | SELECTIVE OXIDATION | ALKANE HYDROXYLATION | MANGANESE COMPLEXES | RIESKE DIOXYGENASES | HYDROCARBON OXIDATIONS | HIGHLY ENANTIOSELECTIVE EPOXIDATION | FE-III-OOH | ASYMMETRIC EPOXIDATION | CHEMISTRY, MULTIDISCIPLINARY | OLEFIN CIS-DIHYDROXYLATION | Olefins | Hydrogen peroxide
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7. Full Text Mechanistically Driven Development of an Iron Catalyst for SelectiveSyn-Dihydroxylation of Alkenes with Aqueous Hydrogen Peroxide
by Borrell, Margarida and Costas, Miquel
Journal of the American Chemical Society, ISSN 0002-7863, 09/2017, Volume 139, Issue 36, pp. 12821 - 12829
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8. Full Text Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C-H and C=C oxidation reactions
by Prat, Irene and Mathieson, Jennifer S and Güell, Mireia and Ribas, Xavi and Luis, Josep M and Cronin, Leroy and Costas, Miquel
Nature Chemistry, ISSN 1755-4330, 10/2011, Volume 3, Issue 10, pp. 788 - 793
Oxo-transfer chemistry mediated by iron underpins many biological processes and today is emerging as synthetically very important for the catalytic oxidation... 
COMPLEX | ACTIVATION | 2 FACES | O-O BOND | ALKANE HYDROXYLATION | CHEMISTRY | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | EPOXIDATION | OLEFIN CIS-DIHYDROXYLATION | NONHEME IRON CATALYSTS | Hydrogen Peroxide - chemistry | Alkenes - chemistry | Thermodynamics | Temperature | Oxidation-Reduction | Iron - chemistry | Mass Spectrometry | Oxides - chemistry | Isotope Labeling | Catalysis | Hydrogen - chemistry | Carbon - chemistry
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9. Full Text Evidence for an oxygen evolving iron-oxo-cerium intermediate in iron-catalysed water oxidation
by Codolà, Zoel and Gómez, Laura and Kleespies, Scott T and Que, Lawrence and Costas, Miquel and Lloret-Fillol, Julio
Nature Communications, ISSN 2041-1723, 01/2015, Volume 6, Issue 1, p. 5865
The non-haem iron complex alpha-[Fe-II(CF3SO3)(2)(mcp)] (mcp = (N,N'-dimethyl-N,N'-bis (2-pyridylmethyl)-1,2-cis-diaminocyclohexane) reacts with Ce-IV to... 
METHANE MONOOXYGENASE | CORES | MECHANISM | SYNTHETIC MODEL | MULTIDISCIPLINARY SCIENCES | COMPLEXES | PHOTOSYSTEM-II | CIS-DIHYDROXYLATION | O BOND FORMATION | LIGAND | PEROXODIIRON(III) | Bacteria - metabolism | Cerium - chemistry | Iron - chemistry | Spectrum Analysis, Raman - methods | Spectrophotometry, Ultraviolet | Spectrometry, Mass, Electrospray Ionization | Photosystem II Protein Complex - chemistry | Oxygen - chemistry | Water - chemistry | Catalysis | Kinetics | Mass Spectrometry - methods | Hydrogen-Ion Concentration
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10. Biologically inspired non-heme iron-catalysts for asymmetric epoxidation; design principles and perspectives
by Cusso, Olaf and Ribas, Xavi and Costas, Miquel
Chemical Communications: Chem Comm, ISSN 1359-7345, 09/2015, Volume 51, Issue 76, pp. 14285 - 14298
Iron coordination complexes with nitrogen and oxygen donor ligands have long since been known to react with peroxides producing powerful oxidizing species.... 
State of the art | Asymmetry | Epoxidation | Ligands | Activation | Peroxides | Oxidation | Iron
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11. Full Text Characterized cis-FeV(O)(OH) intermediate mimics enzymatic oxidations in the gas phase
by Borrell, Margarida and Anis, E and Navrátil, Rafael and Roithova, J and Costas, Miquel
Nature Communications, ISSN 2041-1723, 2019, Volume 10, Issue 1, pp. 1 - 9
FeV(O)(OH) species have long been proposed to play a key role in a wide range of biomimetic and enzymatic oxidations, including as intermediates in arene... 
Organic chemistry | Spectroscopy | Alkenes | Biomimetics | Aromatic compounds | Vapor phases | Heme | Iron | Catalysis | Enzymology | Intermediates
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12. Full Text Readily Accessible Bulky Iron Catalysts exhibiting Site Selectivity in the Oxidation of Steroidal Substrates
by Font, David and Canta, Mercè and Milan, Michela and Cussó, Olaf and Ribas, Xavi and Klein Gebbink, Robertus J M and Costas, Miquel
Angewandte Chemie-International Edition, ISSN 1433-7851, 04/2016, Volume 55, Issue 19, pp. 5776 - 5779
Bulky iron complexes are described that catalyze the site-selective oxidation of alkyl C-H bonds with hydrogen peroxide under mild conditions. Steric bulk at... 
bioinspired catalysis | iron | asymmetric catalysis | C−H activation | selective oxidation | C-H activation | STRAIN RELEASE | COPPER-COMPLEXES | ACTIVATION | HYDROGEN-ATOM TRANSFER | HYDROXYLATION | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | STEREOSELECTIVITY | METHYLENIC SITES | MOLECULAR-OXYGEN | Exhibitions | Oxidation-reduction reaction | Hydrogen peroxide | Pyridine | Chemical properties | Catalysis | Oxidation
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13. Full Text Metallosupramolecular receptors for fullerene binding and release
by García-Simón, Cristina and Costas, Miquel and Ribas, Xavi
Chemical Society Reviews, ISSN 0306-0012, 12/2015, Volume 45, Issue 1, pp. 4 - 62
Fullerene extracts are easily available from fullerene soot, but finding an efficient strategy to obtain them in pure form remains elusive, especially for... 
II-PYRIDINE INTERACTION | CYCLIC DIMER | CAPSULE | MOLECULAR CAGE | INCLUSION | HEMICARCEPLEX FORMATION | C-60 BINDING | PORPHYRIN | C-70 | CHEMISTRY, MULTIDISCIPLINARY | SELECTIVE COMPLEXATION | Receptors | Purification | Fullerenes | Strategy | Ligands | Evolution | General overviews | Gain
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14. Full Text New perspectives on screening and early detection of endometrial cancer
by Costas, Laura and Frias‐Gomez, Jon and Guardiola, Magdalena and Benavente, Yolanda and Pineda, Marta and Pavón, Miquel Á and Martínez, José M and Climent, Maite and Barahona, Marc and Canet, Júlia and Paytubi, Sonia and Salinas, Mónica and Palomero, Luis and Bianchi, Ilaria and Reventós, Jaume and Capellà, Gabriel and Diaz, Mireia and Vidal, August and Piulats, Josep M and Aytés, Álvaro and Ponce, Jordi and Brunet, Joan and Bosch, Francesc X and Matias‐Guiu, Xavier and Alemany, Laia and Sanjosé, Silvia and Screenwide Team and on behalf of the Screenwide Team
International Journal of Cancer, ISSN 0020-7136, 12/2019, Volume 145, Issue 12, pp. 3194 - 3206
Due to the anatomical continuity of the uterine cavity with the cervix, genomic exploitation of material from routine Pap smears and other noninvasive sampling... 
endometrial cancer | genomics | screening | early detection | biomarkers | pap smears | Diagnosis | Research | Endometrial cancer | Oncology, Experimental | Genomics | Cancer | Genital tract | Invasiveness | Cervix | Biological materials | Exploitation | Screening | Uterus | Biomarkers | Sampling methods | Uterine cancer | Health risk assessment | Sampling | Public health | Endometrium
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15. Full Text Efficient water oxidation catalysts based on readily available iron coordination complexes
by Fillol, Julio Lloret and Codolà, Zoel and Garcia-Bosch, Isaac and Gàmez, Laura and Pla, Juan José and Costas, Miquel
Nature Chemistry, ISSN 1755-4330, 10/2011, Volume 3, Issue 10, pp. 807 - 813
Water oxidation catalysis constitutes the bottleneck for the development of energy-conversion schemes based on sunlight. To date, state-of-the-art homogeneous... 
NONHEME IRON | ELECTRON-TRANSFER | LIGANDS | MODELS | CHEMISTRY, MULTIDISCIPLINARY | EPOXIDATION | PEROXO | Nitrates - chemistry | Oxidation-Reduction | Cerium - chemistry | Iron - chemistry | Oxides - chemistry | Water - chemistry | Catalysis | Kinetics | Coordination Complexes - chemistry | Spectrophotometry, Ultraviolet | Hydrogen-Ion Concentration | Periodic Acid - chemistry
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16. Full Text Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations
by Olivo, Giorgio and Cussó, Olaf and Borrell, Margarida and Costas, Miquel
JBIC Journal of Biological Inorganic Chemistry, ISSN 0949-8257, 4/2017, Volume 22, Issue 2, pp. 425 - 452
The selective oxidation of hydrocarbons is a challenging reaction for synthetic chemists, but common in nature. Iron oxygenases activate the O–O bond of... 
Life Sciences | Biochemistry, general | Oxygenases | Hydrogen peroxide | Microbiology | Bioinspired catalysis | Nonheme iron | IRON(IV)-OXO COMPLEXES | OXOIRON(IV) COMPLEXES | BIOCHEMISTRY & MOLECULAR BIOLOGY | FUNCTIONAL-MODEL | KETOGLUTARATE DIOXYGENASE | C-H BONDS | CHEMISTRY, INORGANIC & NUCLEAR | SATURATED-HYDROCARBONS | HIGHLY ENANTIOSELECTIVE EPOXIDATION | FE-III-OOH | ASYMMETRIC EPOXIDATION | OLEFIN CIS-DIHYDROXYLATION | Hydrogen Peroxide - chemistry | Alkenes - chemistry | Biomimetics - methods | Oxidation-Reduction | Free Radicals - chemistry | Stereoisomerism | Iron - chemistry | Catalysis | Alkanes - chemistry | Oxidases | Chemotherapy | Catalysts | Olefins | Oxidation-reduction reaction | Cancer
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