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2004, 1. Aufl., ISBN 9783527306176, 627
Edited by the leading experts John Gladysz, Dennis Curran, and Istv?n Horv?th, this handbook is the first to summarize all the essential aspects of this... 
Fluorine | Fluorine compounds
eBook
2002, Tetrahedron symposia-in-print, Volume 58, no. 20., xxii, p. 3823-4131
Book
Advances in cycloaddition, ISSN 1052-2077, 1988
Journal
Nature Chemistry, ISSN 1755-4330, 2014, Volume 6, Issue 9, pp. 765 - 773
The electron is an efficient catalyst for conducting various types of radical cascade reaction that proceed by way of radical and radical ion intermediates.... 
TERT-BUTOXIDE | ORGANIC-SYNTHESIS | METAL-FREE CONDITIONS | C-H-ARYLATION | CHAIN REACTIONS | ARYL HALIDES | ADDITION-REACTIONS | ACYL RADICALS | LIVING RADICAL POLYMERIZATIONS | CHEMISTRY, MULTIDISCIPLINARY | HOMOLYTIC AROMATIC-SUBSTITUTION | Free Radicals | Catalysis | Electrons
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2018, Volume 57, Issue 32, pp. 10251 - 10256
1,3‐Dimethylimidazol‐2‐ylidene difluoroborane (NHC‐BF2H) was prepared in a one‐pot, two‐step reaction from the parent ligated borane (NHC‐BH3). The derived... 
radical reactions | polymerization | photochemistry | boron | laser flash photolysis | HETEROCYCLIC CARBENE-BORANES | HOMOLYTIC REACTIONS | HYDROGEN-ATOM ABSTRACTION | REACTIVITY | AMINE | CHEMISTRY, MULTIDISCIPLINARY | AMINOBORYLENE | NHC-BORANES | INITIATORS | POLARITY-REVERSAL CATALYSIS | Photolysis | Polymerization | Spectroscopy | Boron | Initiators | Flash photolysis | Polymers | Monomers
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2017, Volume 23, Issue 23, pp. np - n/a
Boryl radicals attack alkynes of strained diynes to induce subsequent radical cyclization. The image illustrates a radical chain reaction (the photo of space... 
radical reactions | strained molecules | boron | main group chemistry | alkynes | Chemical bonds | Transformations | Utilization | Radicals | Images | Alkynes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2019, Volume 58, Issue 19, pp. 6357 - 6361
Substituted propargyl acetates are converted into 4‐boryl‐2(5H)‐furanones upon thermolysis in the presence of an N‐heterocyclic carbene borane (NHC‐borane) and... 
boranes | radical reactions | lactones | synthetic methods | alkynes | Methane | Carbonyl groups | Methyl radicals | Peroxide | Chemical bonds | Esters | Cleavage | Acetic acid | Acetates | Carbonyls
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/1998, Volume 37, Issue 9, pp. 1174 - 1196
A dirty word in synthesis: separation! The normally unavoidable separation at the end of each reaction finds no friends among synthetic chemists and is often... 
Combinatorial chemistry | Fluorous synthesis | Synthesis design | Solid‐phase synthesis | Solid-phase synthesis
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 08/2019, Volume 141, Issue 31, pp. 12355 - 12361
Reactions of readily available alkenyl triflates with N-heterocyclic carbene (NHC)-boranes in the presence of diisopropyl ethyl amine provided about three... 
REACTIVITY | INSERTION | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | ACCESS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2019, Volume 141, Issue 8, pp. 3623 - 3629
The first ring-opening reactions of ligated boriranes (boracyclopropanes) are described. Treatment of readily available NHC-boriranes bearing ester... 
Journal Article
Organic Letters, ISSN 1523-7060, 04/2018, Volume 20, Issue 7, pp. 2084 - 2087
Radical decyanation of aliphatic nitriles was achieved in the presence of NaBH4 and a thiol. The reaction proceeds via a radical mechanism involving borane... 
SUBSTITUTION | CARBON-CYANO BONDS | ELECTRON-SPIN-RESONANCE | REDUCTIVE DECYANATION | MECHANISM | HETEROCYCLIC CARBENE BORANES | SOLVATED ELECTRONS | ADDITION REACTIONS | GIESE REACTION | CHEMISTRY, ORGANIC | MALONONITRILES
Journal Article
Chemistry - A European Journal, ISSN 0947-6539, 01/2018, Volume 24, Issue 4, p. 822
Journal Article
The Journal of organic chemistry, ISSN 0022-3263, 02/2019, Volume 84, Issue 4, pp. 2102 - 2111
Radical H atom abstraction from a set of N-heterocyclic carbene (NHC) complexes of alkenylboranes bearing two tert-butyl ester substituents was studied by EPR... 
REDUCTIONS | ROTATION | HALIDES | COMPLEXES | BARRIER | TIN | CHEMISTRY, ORGANIC | N-HETEROCYCLIC CARBENES | INITIATORS
Journal Article
Tetrahedron, ISSN 0040-4020, 12/2018, Volume 74, Issue 49, pp. 6961 - 6965
NHC-boranes react with oxalic acid in acetonitrile slowly at room temperature and rapidly at 80 °C to form NHC-boryl oxalates. For example, heating of... 
Borinic acid derivatives | Ligated boranes | Oxalic acid derivatives | Boron heterocycles | N-heterocyclic carbene boranes | CHEMISTRY, ORGANIC | ALDEHYDES | REDUCTIONS | ALKENES | KETONES | BONDS | BORANE COMPLEXES | INITIATORS | Nitriles | Oxalates | Oxalic acid | Heterocyclic compounds
Journal Article