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Advanced Synthesis & Catalysis, ISSN 1615-4150, 04/2018, Volume 360, Issue 7, pp. 1346 - 1351
Journal Article
Chemical science (Cambridge), ISSN 2041-6539, 2019, Volume 10, Issue 9, pp. 2693 - 2699
An iodine-catalyzed strategy for β C–H amination of alcohols is enabled by a chemo-, regio-, and stereo-selective H-atom transfer mechanism... 
FUNCTIONALIZATION | OXIDATION | ALCOHOLS | HYDROGEN | ABSTRACTION | INTRAMOLECULAR C(SP)-H | HYPERVALENT IODINE | BONDS | AMIDATION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 08/2017, Volume 139, Issue 30, pp. 10204 - 10207
.... A streamlined protocol enables rapid conversion of alcohols to their β-amino analogs (via in situ conversion of alcohols to imidates, directed C... 
CATALYTIC FUNCTIONALIZATION | TRANSLOCATION | INSERTION | VICINAL AMINO-ALCOHOLS | BONDS | REMOTE OXIDATION | 1,5-HYDROGEN ATOM TRANSFER | 1,3-DIOL SYNTHESIS | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | AMIDINE MOIETY | Chemical bonds | Amines | Chemical properties | Research | Molecular chaperones | Analysis
Journal Article
Chemical science (Cambridge), ISSN 2041-6539, 2019, Volume 10, Issue 4, pp. 1207 - 1211
A radical relay strategy has been developed to enable selective δ C–H arylation. The approach employs a chiral copper catalyst, which serves the dual roles... 
FUNCTIONALIZATION | OXIDATION | C(SP)-H BONDS | AMINATION | AMINES | ALKYLATION | OXYGENATION | ARYLATION | ALKYLARENES | CHEMISTRY, MULTIDISCIPLINARY | PHOTOREDOX CATALYSIS
Journal Article
Journal Article
Science (American Association for the Advancement of Science), ISSN 1095-9203, 2015, Volume 349, Issue 6254, pp. 1326 - 1330
.... Here, we present a blueprint for aromatic carbon-hydrogen functionalization via photoredox catalysis and describe the utility of this strategy for arene amination... 
FUNCTIONALIZATION | ORGANIC-SYNTHESIS | HETEROARENES | HETEROCYCLES | MULTIDISCIPLINARY SCIENCES | AMIDATION | N BOND FORMATION | DERIVATIVES | ARYLAMINES | IMIDATION | MOLECULES | Catalysts | Materials science | Chemistry | Cross coupling | Aniline | Aromatic compounds | Lighting | Chemical bonds | Activation | Catalysis | Radicals
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2017, Volume 139, Issue 8, pp. 2880 - 2883
.... Herein, we disclose the construction of aromatic nitriles via direct C–H functionalization using an acridinium photoredox catalyst and trimethylsilyl cyanide under an aerobic atmosphere... 
OXIDATION | ETHERS | DEPROTECTION | CHEMISTRY, MULTIDISCIPLINARY | ARYL HALIDES | TRANSITION-METAL | Acridines - chemistry | Calixarenes - chemistry | Temperature | Oxidation-Reduction | Nitriles - chemistry | Nitriles - chemical synthesis | Molecular Structure | Catalysis | Photochemical Processes | Usage | Oxygen | Nitriles | Chemical properties | Research | Photochemistry
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2008, Volume 130, Issue 11, pp. 3645 - 3651
A convenient one-pot C−H alkenylation/electrocyclization/aromatization sequence has been developed for the synthesis of highly substituted pyridine derivatives from alkynes and α,β... 
CYCLOADDITION | ACETYLENES | ROUTE | HANTZSCH 1,4-DIHYDROPYRIDINES | 1-AZATRIENES | RH(I) | COMPLEXES | OLEFINS | BOND ACTIVATION | CHEMISTRY, MULTIDISCIPLINARY | CATALYSTS
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2016, Volume 55, Issue 9, pp. 3166 - 3170
A visible‐light‐mediated in situ generation of a boron‐centered carboranyl radical (o‐C2B10H11.) has been described. With eosin Y as a photoredox catalyst,... 
radicals | carborane | photocatalysis | heterocycles | arylation | ELECTRON-SPIN-RESONANCE | ORGANIC-MOLECULES | DIAZONIUM SALTS | BORYL RADICALS | COMPLEXES | REACTIVITY | N-HETEROCYCLIC CARBENES | SUBSTITUTION-REACTIONS | CHEMISTRY, MULTIDISCIPLINARY | CHEMISTRY | DERIVATIVES | Substitution reactions | Catalysis | Boron | Catalysts | Aromatic compounds | Photocatalysis | Metals | Carborane | Coupling | Light effects
Journal Article
Chemical science (Cambridge), ISSN 2041-6520, 05/2018, Volume 9, Issue 19, pp. 4500 - 4504
...) of sp C-H bonds has been developed. This first example of β C-H di-halogenation is achieved through sequential C-H abstraction by iterative, hydrogen atom transfer (HAT... 
Journal Article