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Angewandte Chemie International Edition, ISSN 1433-7851, 02/2019, Volume 58, Issue 9, pp. 2769 - 2773
The effects of β‐hydrogen‐containing alkyl Grignard reagents in simple ferric salt cross‐couplings have been elucidated. The reaction of FeCl3 with EtMgBr in... 
cross-coupling | X-ray diffraction | Grignard reagents | iron | homogeneous catalysis | CATALYSIS | ALKENYL HALIDES | REACTIVITY | CHLORIDES | CHEMISTRY, MULTIDISCIPLINARY | Salts | Hydrogen | Ferric chloride | Iron | Ferric salts | Rare species | Couplings | Reagents | Hydrogen atoms | Catalysis | Coordination compounds | Nucleophiles | Hydrogen ion concentration | Speciation | Iron chlorides
Journal Article
Angewandte Chemie, ISSN 0044-8249, 05/2018, Volume 130, Issue 22, pp. 6606 - 6610
The use of N‐methylpyrrolidone (NMP) as a co‐solvent in ferric salt catalyzed cross‐coupling reactions is crucial for achieving the highly selective,... 
N-Methylpyrrolidon | Kreuzkupplungen | Mößbauer-Spektroskopie | Eisen | MCD-Spektroskopie | Iron compounds | Catalysis | Chemical tests and reagents | Analysis | Salts | Iron 57 | Chemical reactions | Iron | Ferric salts | Globular clusters | Molecular chains | Coupling (molecular) | Reagents | Scale formation | Cations | Magnesium | Species
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2014, Volume 136, Issue 25, pp. 9132 - 9143
While iron-bisphosphines have emerged as effective catalysts for C-C cross-coupling, the nature of the in situ formed iron species, elucidation of the active... 
SQUARE-PLANAR | PHOSPHINE | COMPLEXES | ARYL-GRIGNARD-REAGENTS | TMEDA | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | Density functionals | Usage | Catalysis | Electron configuration | Research | Analysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2019, Volume 58, Issue 9, p. 2769
The effects of [beta]-hydrogen-containing alkyl Grignard reagents in simple ferric salt cross-couplings have been elucidated. The reaction of FeCl.sub.3 with... 
Iron compounds | Chemical tests and reagents | Hydrogen | Catalysis
Journal Article
Journal of Physical Chemistry A: Molecules, Spectroscopy, Kinetics, Environment and General Theory, ISSN 1089-5639, 05/2013, Volume 117, Issue 21, pp. 4444 - 4454-4444-4454
Ruthenium L sub(3)-edge X-ray absorption (XA) spectroscopy probes unoccupied 4d orbitals of the metal atom and is increasingly being used to investigate the... 
Solvents | Spectroscopy | Computer simulation | X-rays | Grounds | Spectra | Excitation spectra | Charge transfer
Journal Article
Angewandte Chemie, ISSN 0044-8249, 02/2019, Volume 131, Issue 9, pp. 2795 - 2799
The effects of β‐hydrogen‐containing alkyl Grignard reagents in simple ferric salt cross‐couplings have been elucidated. The reaction of FeCl3 with EtMgBr in... 
Röntgenbeugung | Kreuzkupplungen | Grignard-Reagentien | Homogene Katalyse | Eisen | Salts | Hydrogen | Ferric chloride | Iron | Ferric salts | Rare species | Couplings | Reagents | Hydrogen atoms | Catalysis | Coordination compounds | Nucleophiles | Hydrogen ion concentration | Speciation | Iron chlorides
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2013, Volume 19, Issue 15, pp. 4842 - 4848
The discovery and elucidation of a new Nazarov cyclization/Wagner–Meerwein rearrangement/oxidation sequence is described that constitutes an efficient strategy... 
oxidation | density functional calculations | copper | homogeneous catalysis | cyclization | rearrangement | Oxidation-reduction reaction | Oxidation
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 01/2016, Volume 55, Issue 1, pp. 272 - 282
Chelating phosphines are effective additives and supporting ligands for a wide array of iron-catalyzed cross-coupling reactions. While recent studies have... 
PHOSPHINE | ALKENYL HALIDES | DIIMINE | KUMADA | ARYL-GRIGNARD-REAGENTS | CRYSTAL-STRUCTURES | MAGNETIC CIRCULAR-DICHROISM | DENSITY-FUNCTIONAL THEORY | ALKYL-HALIDES | CHEMISTRY, INORGANIC & NUCLEAR | Iron Compounds - chemistry | Spectroscopy, Mossbauer | Molecular Structure | Catalysis | Circular Dichroism | Carbon - chemistry | Electrons
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2016, Volume 138, Issue 24, pp. 7492 - 7495
Iron-catalyzed cross-couplings with simple ferric salts have been known since the 1970s, pioneered by Kochi for cross-coupling using alkylmagnesium... 
Journal Article
Structural Dynamics, ISSN 2329-7778, 03/2016, Volume 3, Issue 2, pp. 023609 - 023609-16
Using polarization-selective two-dimensional infrared (2D IR) and infrared pump-probe spectroscopies, we study vibrational relaxation of the four cyanide... 
DEPHASING DYNAMICS | ECHO | STRETCH | ULTRAFAST ELECTRON-TRANSFER | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | ENERGY RELAXATION | INTRAMOLECULAR VIBRATIONS | CHARGE-TRANSFER | RESONANCE-RAMAN | MOLECULES
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 11/2017, Volume 56, Issue 22, pp. 13766 - 13776
We report an easily prepared bis­(thioether) amine ligand, S Me N H S Me , along with the synthesis, characterization, and reactivity of the paramagnetic... 
N-2 REDUCTION | LIGATION SYNTHESIS | PINCER COMPLEXES | TRIVALENT IRON | RUTHENIUM COMPLEXES | COORDINATION | ASYMMETRIC HYDROGENATION | MAGNETIC-PROPERTIES | NITRILE HYDRATASE | H-BOND | CHEMISTRY, INORGANIC & NUCLEAR | Usage | Iron compounds | Analysis | Ligands | Amides | Chemical properties | Chemical synthesis
Journal Article
The Journal of Physical Chemistry C, ISSN 1932-7447, 08/2017, Volume 121, Issue 30, pp. 16283 - 16290
Nonprecious metal M–N–C (M = Fe or Co) catalysts that are effective for the oxygen-reduction reaction in polymer-electrolyte fuel cells have been developed,... 
Journal Article
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