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organic chemistry (53) 53
chemistry, organic (49) 49
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life sciences (22) 22
olefins (22) 22
amination (20) 20
rhodium (20) 20
c-h amination (18) 18
chemistry, multidisciplinary (16) 16
amines (15) 15
aziridination (15) 15
acyclic or carbocyclic compounds (14) 14
derivatives (14) 14
nitrene (14) 14
animals (13) 13
neurons and cognition (13) 13
stereoisomerism (12) 12
calcium (10) 10
humans (10) 10
organic-synthesis (10) 10
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calcium-sensing receptor (9) 9
catalysts (9) 9
nitrenes (9) 9
receptors, calcium-sensing (9) 9
acyclic, carbocyclic or heterocyclic compounds containingelements other than carbon, hydrogen, halogen, oxygen, nitrogen,sulfur, selenium or tellurium (8) 8
alkenes (8) 8
amidation (8) 8
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aziridines (8) 8
cellular biology (8) 8
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rats (8) 8
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amino-acids (7) 7
analogs (7) 7
chemical properties (7) 7
copper-catalyzed aziridination (7) 7
functionalization (7) 7
imines - chemistry (7) 7
intermolecular amination (7) 7
models, molecular (7) 7
molecular structure (7) 7
nitrogen-atom-transfer (7) 7
oxidation (7) 7
receptors, calcium-sensing - metabolism (7) 7
amination, n‐alkylation, n‐arylation (6) 6
analysis (6) 6
apparatus therefor (6) 6
aziridine (6) 6
bonds (6) 6
copper (6) 6
enantiomers (6) 6
general methods of organic chemistry (6) 6
homogeneous catalysis (6) 6
hydrocarbons (6) 6
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n bond formation (6) 6
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rat (6) 6
receptors, calcium-sensing - genetics (6) 6
sulfonamides (6) 6
aminierung (5) 5
amino acids (5) 5
aziridines - chemistry (5) 5
bonding (5) 5
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calcium - metabolism (5) 5
cell line (5) 5
chiral aziridines (5) 5
cho cells (5) 5
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highly efficient (5) 5
hypervalent iodine (5) 5
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reagents (5) 5
rhodium-catalyzed aziridination (5) 5
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1. Full Text Nitrene chemistry in organic synthesis: Still in its infancy?
by Dequirez, Geoffroy and Pons, Valérie and Dauban, Philippe
Angewandte Chemie - International Edition, ISSN 1433-7851, 07/2012, Volume 51, Issue 30, pp. 7384 - 7395
The element nitrogen is essential to life. Considerable attention is thus paid to the development of synthetic methods for its introduction into molecules.... 
cascade reactions | homogeneous catalysis | alkenes | heterocycles | nitrenes | TRANSITION-METAL-COMPLEXES | RHODIUM-CATALYZED AZIRIDINATION | RHODIUM(II)-CATALYZED AZIRIDINATION | CHEMISTRY, MULTIDISCIPLINARY | PHOTOCHEMICAL-TRANSFORMATIONS | MECHANISTIC INSIGHTS | SATURATED HYDROCARBONS | SELECTIVE SYNTHESIS | CHIRAL AZIRIDINES | C-H AMINATION | Nitrogen | Animal behavior | Catalysis | Synthesis | Amines | Alkenes | Catalysts | Alkanes | Formations | Inserts | Bonding | Organic chemistry | Chemical Sciences
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2. Full Text Modern Drug Synthesis. Edited by Jie Jack Li and Douglas S. Johnson
by Dauban, Philippe
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2011, Volume 50, Issue 16, pp. 3600 - 3600
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3. Full Text Catalytic C-H amination: The stereoselectivity issue
by Collet, Florence and Lescot, Camille and Dauban, Philippe
Chemical Society Reviews, ISSN 0306-0012, 04/2011, Volume 40, Issue 4, pp. 1926 - 1936
Catalytic C-H amination has recently emerged as a unique tool for the synthesis of amines. This tutorial review highlights the existing protocols catalyzed by... 
INTRAMOLECULAR AMIDATION | CHLORAMINE-T | HYDROCARBONS | NITROGEN-ATOM-TRANSFER | MANGANESE PORPHYRINS | CHIRAL DIRHODIUM(II) CARBOXYLATES | SILYL ENOL ETHERS | BOND OXIDATION | SULFAMATE ESTERS | CHEMISTRY, MULTIDISCIPLINARY | ENANTIOSELECTIVE AMINATION | Ruthenium | Catalysts | Rhodium | Insertion | Tools | Activation | Catalysis | Manganese | Organic chemistry | Chemical Sciences
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4. Full Text Tandem Catalytic C(sp3)H Amination/Sila‐Sonogashira–Hagihara Coupling Reactions with Iodine Reagents
by Buendia, Julien and Darses, Benjamin and Dauban, Philippe
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2015, Volume 54, Issue 19, pp. 5697 - 5701
A new tandem CN and CC bond‐forming reaction has been achieved through Rh II /Pd 0 catalysis. The sequence first involves an iodine(III) oxidant, then the in... 
homogeneous catalysis | cross‐coupling | hypervalent compounds | synthetic methods | CH Activation | cross-coupling | C-H Activation | PALLADIUM | CASCADE REACTIONS | ALKYNYLSILANES | MEDIATED AZIRIDINATION | DIARYLIODONIUM SALTS | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | CHEMISTRY | ARYL IODIDES | STEREOSELECTIVE-SYNTHESIS | C-H AMINATION | Iodine | Oxidants | Oxidizing agents | Byproducts | Joining | Oxidation | Catalysis | Bonding | Bonding agents | Chemical Sciences
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5. Full Text A Masked 1,3-dipole revealed from aziridines
by Dauban, Philippe and Malik, Guillaume
Angewandte Chemie - International Edition, ISSN 1433-7851, 11/2009, Volume 48, Issue 48, pp. 9026 - 9029
Lewis acids | Heterocycles | Cycloaddition | Aziridines | aziridines | CYCLOADDITION REACTIONS | IMIDAZOLINES | AZOMETHINE YLIDES | CHEMISTRY, MULTIDISCIPLINARY | DIPOLE | ALKENES | cycloaddition | heterocycles | FORMAL 3+2 | NITRILES | PHENYLAZIRIDINE | CYCLIZATION | Alkenes - chemistry | Molecular Structure | Cyclization | Aziridines - chemistry | Index Medicus | Life Sciences | Cellular Biology
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6. Full Text Rhodium‐Catalyzed Alkene Difunctionalization with Nitrenes
by Ciesielski, Jennifer and Dequirez, Geoffroy and Retailleau, Pascal and Gandon, Vincent and Dauban, Philippe
Chemistry – A European Journal, ISSN 0947-6539, 06/2016, Volume 22, Issue 27, pp. 9338 - 9347
The Rh II ‐catalyzed oxyamination and diamination of alkenes generate 1,2‐amino alcohols and 1,2‐diamines, respectively, in good to excellent yields and with... 
reaction mechanisms | amination | oxyamination | synthetic methods | rhodium | ELECTRON-RICH AMINES | INTERMOLECULAR AMINOACETOXYLATION | CU(I)-CATALYZED REGIOSELECTIVE DIAMINATION | CONJUGATED DIENES | METAL-FREE DIAMINATION | CHEMISTRY, MULTIDISCIPLINARY | UNACTIVATED ALKENES | PROMOTED INTRAMOLECULAR DIAMINATION | FUNCTIONALIZED HYDROXYLAMINES | N BOND FORMATION | C-H AMINATION | Rhodium | Nitrogen | Olefins | Alkenes | Mathematical analysis | Bonding | Ring opening | Alcohols | Organic compounds
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7. Full Text Catalytic Enantioselective Intermolecular Benzylic C(sp3)−H Amination
by Nasrallah, Ali and Boquet, Vincent and Hecker, Alexandra and Retailleau, Pascal and Darses, Benjamin and Dauban, Philippe
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2019, Volume 58, Issue 24, pp. 8192 - 8196
A practical general method for asymmetric intermolecular benzylic C(sp 3 )−H amination has been developed by combining the pentafluorobenzyl sulfamate PfbsNH 2... 
C−H functionalization | enantioselective synthesis | nitrene | amination | rhodium | CYTOCHROME-P450 | DIRHODIUM(II) | AMIDATION | NITRENE TRANSFER-REACTIONS | C-H functionalization | CHEMISTRY, MULTIDISCIPLINARY | INSERTIONS | AZIRIDINATIONS | BONDS | C-H AMINATION | Enantiomers | Amines | Rhodium | Amination | Catalysts | Catalysis | Substrates | Organic chemistry | Chemical Sciences
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8. Full Text Catalytic Intermolecular Alkene Oxyamination with Nitrenes
by Dequirez, Geoffroy and Ciesielski, Jennifer and Retailleau, Pascal and Dauban, Philippe
Chemistry – A European Journal, ISSN 0947-6539, 07/2014, Volume 20, Issue 29, pp. 8929 - 8933
The Rh II ‐catalyzed intermolecular addition of nitrenes to aromatic and aliphatic alkenes provides vicinal amino alcohols with yields of up to 95 % and... 
alkenes | aminohydroxylation | synthetic methods | nitrenes | rhodium | INTRAMOLECULAR AMINOHYDROXYLATION | AMINOACETOXYLATION | CHEMISTRY, MULTIDISCIPLINARY | HIGHLY EFFICIENT | SHARPLESS ASYMMETRIC AMINOHYDROXYLATION | VICINAL AMINO-ALCOHOLS | MECHANISTIC INSIGHTS | AZIRIDINATION | OLEFINS | TETHERED AMINOHYDROXYLATION | C-H AMINATION | Alkenes - chemistry | Amination | Hydroxylation | Amino Alcohols - chemical synthesis | Stereoisomerism | Imines - chemistry | Catalysis | Amino Alcohols - chemistry | Aziridines - chemistry | Rhodium - chemistry | Olefins | Index Medicus | Lewis acid | Rhodium | Alkenes | Formations | Ring opening | Aliphatic compounds | Alcohols | Organic chemistry | Chemical Sciences
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9. Full Text Catalytic Intramolecular C(sp3)–H Amination of Carbamimidates
by Grelier, Gwendal and Rey‐Rodriguez, Romain and Darses, Benjamin and Retailleau, Pascal and Dauban, Philippe
European Journal of Organic Chemistry, ISSN 1434-193X, 04/2017, Volume 2017, Issue 14, pp. 1880 - 1883
The Rh II ‐catalyzed intramolecular C(sp 3 )–H amination of carbamimidates allowed new nitrogen heterocycles to be isolated in yields up to 99 %. The reaction... 
Nitrenes | Amination | Rhodium | Nitrogen heterocycles | Homogeneous catalysis | INSERTION | INTERMOLECULAR AMINATION | BOND AMINATION | AMIDATION | CHEMISTRY, ORGANIC | NITRENE TRANSFER-REACTIONS | BENZYLIC METHYLENE GROUPS | FUNCTIONALIZATION | AZIRIDINATIONS | ARYL AZIDES | C-H AMINATION | Hydrogen bonds | Substrates | Catalysis
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10. Full Text The Multiple Facets of Iodine(III) Compounds in an Unprecedented Catalytic Auto‐amination for Chiral Amine Synthesis
by Buendia, Julien and Grelier, Gwendal and Darses, Benjamin and Jarvis, Amanda G and Taran, Frédéric and Dauban, Philippe
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2016, Volume 55, Issue 26, pp. 7530 - 7533
Iodine(III) reagents are used in catalytic one‐pot reactions, first as both oxidants and substrates, then as cross‐coupling partners, to afford chiral... 
hypervalent iodine | cross-coupling | C−H amination | homogeneous catalysis | tandem synthesis | C-H amination | CASCADE REACTIONS | REAGENTS | ARYLATION | DIARYLIODONIUM SALTS | CHEMISTRY, MULTIDISCIPLINARY | M-CHLOROPERBENZOIC ACID | BONDS | OXIDATIONS | CHEMISTRY | POLYVALENT IODINE | Palladium | Amines | Catalysis | Chemical tests and reagents | Iodine | Cross coupling | Oxidizing agents | Substrates | Couplings | Oxidants | Amination | Aromatic compounds | Reagents | Chemical synthesis
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11. Full Text Catalytic CH Amination: A Reaction Now Accessible to Engineered Natural Enzymes
by Jean-Pierre Mahy and Jennifer Ciesielski and Philippe Dauban
Angewandte Chemie, ISSN 1433-7851, 07/2014, Volume 53, Issue 27, p. 6862
  Catalytic CH aminations with natural enzymes have not been reported thus far. However, when a cytochrome P450 enzyme is modified by switching from an... 
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12. Full Text Positive and Negative Allosteric Modulators of the Ca2+-sensing Receptor Interact within Overlapping but Not Identical Binding Sites in the Transmembrane Domain
by Christophe Petrel and Albane Kessler and Philippe Dauban and Robert H. Dodd and Didier Rognan and Martial Ruat
Journal of Biological Chemistry, ISSN 0021-9258, 04/2004, Volume 279, Issue 18, pp. 18990 - 18997
A three-dimensional model of the human extracellular Ca 2+ -sensing receptor (CaSR) has been used to identify specific residues implicated in the recognition... 
METABOTROPIC GLUTAMATE-RECEPTOR | CALCIUM-SENSING RECEPTOR | RAT | PARATHYROID-HORMONE SECRETION | BIOCHEMISTRY & MOLECULAR BIOLOGY | PROTEIN-COUPLED RECEPTORS | CALCIMIMETIC COMPOUND | HUMAN CA2+ RECEPTOR | IDENTIFICATION | MOLECULAR DOCKING | OLIGODENDROCYTES | Naphthalenes - chemistry | Protein Structure, Tertiary | Cell Line | Allosteric Regulation | Humans | Cyclohexylamines - chemistry | Models, Molecular | Receptors, Calcium-Sensing - metabolism | Dose-Response Relationship, Drug | Transfection | Membrane Proteins - chemistry | Receptors, Calcium-Sensing - genetics | Membrane Proteins - metabolism | Binding Sites | Receptors, Calcium-Sensing - chemistry | Amino Acid Substitution | Benzamides - chemistry | Index Medicus | Neurons and Cognition | Cyclohexylamines | Receptors, Calcium-Sensing | Naphthalenes | Membrane Proteins | Life Sciences | Benzamides
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13. Full Text Dirhodium(II)‐Mediated Alkene Epoxidation with Iodine(III) Oxidants
by Nasrallah, Ali and Grelier, Gwendal and Lapuh, Maria Ivana and Duran, Fernando J and Darses, Benjamin and Dauban, Philippe
European Journal of Organic Chemistry, ISSN 1434-193X, 11/2018, Volume 2018, Issue 42, pp. 5836 - 5842
Dirhodium(II) complexes and iodine(III) oxidants have found useful applications in synthetic nitrene chemistry. In this study, the combination of the... 
Epoxidation | Lewis acids | Hypervalent Iodine | Rhodium | Alkenes | OXIDATION | ORGANIC-SYNTHESIS | INTERMOLECULAR AMINATION | CHEMISTRY, ORGANIC | OXYGEN-ATOM TRANSFER | DIAZO-COMPOUNDS | CATALYST | TERT-BUTYL HYDROPEROXIDE | DIRHODIUM CAPROLACTAMATE | BONDS | C-H AMINATION | Olefins | Lewis acid | Organic chemistry | Rhodium compounds | Oxidants | Reagents | Oxidizing agents | Oxidation | Iodine
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