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Tetrahedron Letters, ISSN 0040-4039, 01/2014, Volume 55, Issue 1, pp. 23 - 26
A simple and convenient method for the chemoselective reduction of nitriles into aldehydes using a 1,1,3,3-tetramethyldisiloxane... 
1,1,3,3-Tetramethyldisiloxane (TMDS) | Nitriles | Reduction | Aldehydes | Vanadium | Organic chemistry | Chemical Sciences
Journal Article
Green Chemistry, ISSN 1463-9262, 12/2010, Volume 12, Issue 12, pp. 2189 - 2195
1- O -alkyl glycerol and diglycerol ethers are obtained in high yields and high selectivity by catalytic reductive alkylation of glycerol and diglycerol with... 
GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | CONVERSION | CHEMISTRY, MULTIDISCIPLINARY | CONVENIENT CATALYTIC METHOD | FUEL | Organic chemistry | Chemical Sciences
Journal Article
Green Chemistry, ISSN 1463-9262, 2013, Volume 15, Issue 3, pp. 786 - 797
From available and bio-sourced methyl esters, monoglycerides or oleic sunflower refined oil, the corresponding 1-O-alkyl (di)glycerol ethers were obtained in... 
SOLID CATALYSTS | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | ACID | GLYCEROL | OLEATE | TELOMERIZATION | SELECTIVE SYNTHESIS | ETHERIFICATION | MODEL | NOX STORAGE | CHEMISTRY, MULTIDISCIPLINARY | MONOGLYCERIDE SYNTHESIS | Pathways | Catalysts | Reductive alkylation | Esters | Transesterification | Catalysis | Ethers | Monoglycerides | Organic chemistry | Chemical Sciences
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2010, Volume 51, Issue 15, pp. 1939 - 1941
An efficient reduction of the nitro group with a catalytic amount of Fe(acac) 3 and TMDS in THF at 60 °C affording the corresponding amine is described. 
1,1,3,3-Tetramethyldisiloxane | Reduction | Nitro | Iron catalyst | Amines | AMINATION | HYDROSILYLATION | COMPLEXES | CHEMISTRY, ORGANIC | Nitro compounds | Organic chemistry | Chemical Sciences
Journal Article
ISSN 1463-9262, 3/2013, Volume 15, Issue 3, pp. 786 - 797
From available and bio-sourced methyl esters, monoglycerides or oleic sunflower refined oil, the corresponding 1- O -alkyl (di)glycerol ethers were obtained in... 
Journal Article
SCIENCE CHINA Chemistry, ISSN 1674-7291, 09/2010, Volume 53, Issue 9, p. 1937
When [alpha]-alkoxy-[beta]-ketophosphonates, prepared by the Rh(II) mediated insertion reaction of [alpha]-diazo-[beta]-ketophosphonates into the OH bond of... 
Intercontinental ballistic missiles | Chemical properties
Journal Article
Tetrahedron, ISSN 0040-4020, 2011, Volume 67, Issue 10, pp. 1971 - 1976
The system 1,1,3,3-tetramethyldisiloxane (TMDS)/Fe(acac) 3 is reported here as a new method to obtain amines from aromatic nitro compounds. Amines are... 
NITROARENES | NITROCOMPOUNDS | CHEMOSELECTIVE HYDROGENATION | HYDROSILYLATION | PLATINUM | CHEMISTRY, ORGANIC | SELECTIVE REDUCTION | Nitriles | Methods | Amines | Reduction | Cyano groups | Aromatic compounds | Tetrahedrons | Nitro compounds | Esters | Carboxylic acids | Organic chemistry | Chemical Sciences
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 08/2011, Volume 52, Issue 32, pp. 4072 - 4075
A simple and useful method for the reduction of primary amides into the corresponding amines using a polymethylhydrosiloxane (PMHS)–Ti(OiPr)4 reducing system... 
Titanium | Reduction | Amines | Polymethylhydrosiloxane (PMHS) | Primary amides | Organic chemistry | Chemical Sciences
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2011, Volume 52, Issue 12, pp. 1281 - 1283
A simple and practical procedure for the reduction of acetals to ethers is described. It is based on the use of a 1,1,3,3-tetramethyldisiloxane (TMDS)–Pd/C... 
1,1,3,3-Tetramethyldisiloxane (TMDS) | Acetal | Reduction | Pd/C | 4,6-O-BENZYLIDENE ACETALS | CHEMISTRY, ORGANIC | SELECTIVE REDUCTION | EFFICIENT | Tetrahedrons | Ethers | Acetals
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 2009, Volume 50, Issue 50, pp. 7005 - 7007
A simple and useful method for the reduction of nitriles into the corresponding amines using a tetramethyldisiloxane/titanium(IV) isopropoxide reducing system... 
Titanium | Nitriles | Reduction | Amines | Tetramethyldisiloxane | CONJUGATE REDUCTION | ALLYLIC TRANSPOSITION | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | SIGMATROPIC REARRANGEMENT | POLYMETHYLHYDROSILOXANE PMHS | KETONES | PRIMARY AMINES | CATALYZED REDUCTION | PHOSPHINE OXIDES | ALPHA,BETA-UNSATURATED NITRILES | Methods
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 01/2014, Volume 55, Issue 1, p. 23
Journal Article
The Journal of Physical Chemistry B, ISSN 1520-6106, 08/2013, Volume 117, Issue 31, pp. 9262 - 9272
Three pentyl and three aryl 1-O-monoglyceryl ethers prepared via a green catalytic route were investigated as hydrotropic solvents. Their amphiphilicities were... 
INTERFACIAL-TENSIONS | TERNARY-SYSTEMS | ETHERS | SOLVENTS | PHASE-BEHAVIOR | COSMO-RS APPROACH | SOLVO-SURFACTANTS | CHEMISTRY, PHYSICAL | CATALYTIC REDUCTIVE ALKYLATION | SELECTIVE SYNTHESIS | WATER | Glycerin | Glycerol | Chemical properties | Solvents | Aromatic compounds | Hydrotropes | Atomic properties | Derivatives | Hydrophobicity | Ethers | Carbon | Organic chemistry | Chemical Sciences
Journal Article
Green Chemistry, ISSN 1463-9262, 01/2011, Volume 13, Issue 10, pp. 2737 - 2742
A protocol is described for the reductive cleavage of the C-O bond of aromatic and aliphatic acetals to ethers catalyzed by Cu(OTf)2 or Bi(OTf)3 at room... 
Economics | Nitriles | Esters | Cleavage | Ethers | Bonding | Acetals | Aliphatic compounds
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 04/2012, Volume 2012, Issue 10, pp. 1960 - 1966
1,1,3,3‐Tetramethyldisiloxane (TMDS) has been developed as an excellent dual‐purpose reductant for the highly regioselective ring cleavage of various... 
Carbohydrates | Reduction | Surfactants | Copper | Aluminum | OPENINGS | SYSTEM | KETALS | CHEMISTRY, ORGANIC | CARBOHYDRATE | SELECTIVE REDUCTION | CATALYST | FATTY-ACID ESTER | BENZYLIDENE ACETALS | BOND | DERIVATIVES
Journal Article
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