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Chemistry : a European journal, ISSN 0947-6539, 2016, Volume 22, Issue 48, pp. 17169 - 17172
Room temperature hydrogenation of an SIDep‐stabilized diboryne (SIDep=1,3‐bis(diethylphenyl)‐4,5‐dihydroimidazol‐2‐ylidene) and a cAAC‐supported diboracumulene... 
carbenes | main-group chemistry | reaction mechanism | hydrogenation | diborenes | ACTIVATION | HYDROBORATION | SINGLE | ANALOGS | COMPOUND | REACTIVITY | H-2 | CHEMISTRY, MULTIDISCIPLINARY | NEUTRAL DIBORENE | BORON TRIPLE BOND | Hydrogenation | Synthesis (chemistry) | Boron | Catalysts | Bridging | Mathematical analysis | Chemical bonds | Hydrides
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2015, Volume 54, Issue 35, pp. 10271 - 10275
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2015, Volume 54, Issue 15, pp. 4469 - 4473
The reaction of the bisboracumulene (CAAC)2B2 (CAAC=1‐(2,6‐diisopropylphenyl)‐3,3,5,5‐tetramethylpyrrolidin‐2‐ylidene) with excess tert‐butylisocyanide... 
main‐group elements | multiple bonds | thermolysis | boron | diborenes | main-group elements | CARBENE | COMPLEXES | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | MOLECULES | ISOCYANIDE | RADICALS | STABLE METHYLENEBORANES | PAIR | Telomerase | Ligands | Complexation | Boron | Electrochemical analysis | Heating | Electronics | Voltammetry | Formations | Adducts
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 11/2015, Volume 54, Issue 46, pp. 13801 - 13805
A new compound with the formula L‐B2‐L wherein the stabilizing ligand (L) is 1,3‐bis[diisopropylphenyl]‐4,5‐dihydroimidazol‐2‐ylidene (SIDip) has been... 
carbenes | main‐group chemistry | multiple bonds | boron | thermochemistry | main-group chemistry | Ligands
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2018, Volume 57, Issue 38, pp. 12275 - 12279
The first spontaneous, metal‐free, room‐temperature hydrogen transfer from ammonia borane to an iminoborane is reported. Mechanistic studies of the reaction... 
main-group elements | boron | hydrogen transfer | hydrogenation | amine boranes | STORAGE | CATALYTIC DEHYDROGENATION | REGENERATION | COORDINATION | RELEASE | THERMAL-DECOMPOSITION | CHEMISTRY, MULTIDISCIPLINARY | REDISTRIBUTION | AMINOBORANES | CARBENE COMPLEXES | EFFICIENT | Ammonia | Amines | Hydrogen | Activation energy | Hydrogenation | Hydrogen storage | Dehydrogenation | Metals | Boranes
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 18, pp. 5606 - 5609
The reactions of a diborene with elemental selenium or tellurium are shown to afford a diboraselenirane or diboratellurirane, respectively. These reactions are... 
tellurium | selenium | multiple bonds | heterocycles | boron | MOLYBDENUM | TRIPLE BOND | AZIRIDINES | CHEMISTRY, MULTIDISCIPLINARY | ELEMENTAL SULFUR | ALKENES | ORGANOCATALYTIC ASYMMETRIC EPOXIDATION | EPISULFIDATION | OLEFINS | THIIRANES | TRANSFORMATIONS | Chemical properties | Selenium | Bonds | Olefins | Boron
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2018, Volume 24, Issue 1, pp. 266 - 273
A series of NHC‐supported 1,2‐dithienyldiborenes was synthesized from the corresponding (dihalo)thienylborane NHC precursors. NMR and UV/Vis spectroscopic... 
spectroscopy | boron | diborenes | electron donors | N-heterocyclic carbenes | INSERTION | AB-INITIO | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | POTENTIAL CURVES | BORON MULTIPLE BONDS | CHALCOGENS | LIGANDS | BORYLENE | GENERATION | Coplanarity | Stability | Nuclear magnetic resonance--NMR | Crystallography | Destabilization | Electrons
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 27, pp. 7975 - 7979
Although the metathesis of metal–boron double bonds with elemental chalcogenides is an established process, no similar reactivity has been observed with... 
borylenes | density functional calculations | iminoboranes | boron heterocycles | nitrenes | HYDROBORATION | INSERTION | BORON | REACTIVITY | PLATINUM | TERMINAL BORYLENE COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | CHEMISTRY | BASIS-SETS | ARYLBORYLENE COMPLEX | METAL-COMPLEXES | Nitrogen | Chalcogenides | Boron | Cycloaddition | Metathesis | Decomposition reactions | Chemical bonds
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2017, Volume 23, Issue 33, pp. 8006 - 8013
Electronic and steric factors have been investigated in the thermal ring expansion of boroles with organic azides, a reaction that provides access to highly... 
azides | heterocycles | azaborinines | boron | ring expansion | ANTIAROMATICITY | BENZENE | ANALOGS | CAVITY | 1,2-AZABORININES | T4 LYSOZYME | CHEMISTRY, MULTIDISCIPLINARY | BN ISOSTERES | PI INTERACTIONS | C-C | Azides (organic) | Electronic structure | Diffraction | Nuclear magnetic resonance--NMR | Pathways | Benzene | X-ray diffraction | Electrochemistry | Insertion | Expansion
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2018, Volume 24, Issue 26, pp. 6843 - 6847
A family of doubly isonitrile‐stabilized terphenyl borylenes could be obtained by addition of three equivalents of isonitrile to the corresponding Cr and W... 
borylenes | imine ligands | boron | Lewis bases | transition-metal complexes | BORON BONDS | REACTIVITY | CHEMISTRY, MULTIDISCIPLINARY | MULTIPLE COMPLEXATION | ELEMENTS | INFRARED-SPECTRA | REDUCTION | LIGANDS | CARBENES | AMINOBORYLENE | Substitution reactions | Chromium | Carbon monoxide | Tungsten | Phosphines | Carbonyls
Journal Article