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Angewandte Chemie International Edition, ISSN 1433-7851, 03/2013, Volume 52, Issue 13, pp. 3574 - 3583
... most prominent are the stability and synthesis of the required BB bonds. The homonuclear σ‐bond enthalpy of boron ( D 0 =293 kJ mol −1 ) approaches that of carbon ( D 0... 
boron‐centered ligands | boron–boron bonds | boron | multiple bonding | transition metals | boron-boron bonds | boron-centered ligands | Construction | Diborane | Boron | Formations | Synthesis | Enthalpy
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2018, Volume 24, Issue 38, pp. 9692 - 9697
A range of double carbene adducts of digallanes(4) are prepared from an existing double digallane adduct, and their halides are subsequently exchanged,... 
carbenes | digallanes | cyclic (alkyl)(amino)carbenes | gallium | halogen exchange | BORON | SILICON | REACTIVITY | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | PLATINUM COMPLEXES | BORYL LIGANDS | AL-AL | HOMOLOGS | SUPERSILYL COMPOUNDS | Exchanging | Organic chemistry | Gallium | Halides | Metals | Feasibility studies | Ligands | Base metal | Species | Adducts
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2019, Volume 58, Issue 13, pp. 4405 - 4409
The lability of B=B, B−P, and B–halide bonds is combined in the syntheses of the first diiododiborenes. In a series of reactivity tests, these diiododiborenes... 
low-valent main-group species | iodine | multiple bonds | 1,2-additions | boron | DISILENES | 1, 2-additions | CARBENES | DENSITY-FUNCTIONAL THEORY | CHEMISTRY, MULTIDISCIPLINARY | DISILYNE RSISIR | Hydrogenation | Phosphine | Lability | Bonding
Journal Article
Nature communications, ISSN 2041-1723, 2018, Volume 9, Issue 1, pp. 1197 - 7
..., Rian D. Dewhurst 1,2, Serhiy Demeshko4, William C. Ewing1, Kai Hammond1,2, Merlin Heß1,2, Eckhard Bill5, Eileen Welz 3, Merle I.S. Röhr 3, Roland Mitrić3, Bernd... 
Chemical bonds | Boron | Twisting | Alkenes | Congeners | Diamagnetism
Journal Article
Chemical Communications, ISSN 1359-7345, 5/2015, Volume 51, Issue 47, pp. 9594 - 967
..., 9594 for organic synthesis Rian D. Dewhurst, Emily C. Neeve, Holger Braunschweig* and Todd B. Marder* Despite the widespread use of organoborane reagents... 
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2019, Volume 58, Issue 11, pp. 3268 - 3278
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2014, Volume 53, Issue 21, pp. 5453 - 5457
Despite the synthesis of a boryl anion by Yamashita et al. in 2006, compounds that show boron‐centered nucleophilicity are still rare and sought‐after... 
radicals | anions | boron | Lewis bases | boroles | REDUCTION | FORM | NUCLEAR-MAGNETIC-RESONANCE | COMPLEXES | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | BORYLLITHIUM | Substitution reactions | Electron transport | Analysis | Boron | Spectroscopy | Anions | Synthesis | Iodides | Halides | X-rays | Crystallography | Radicals
Journal Article
Dalton transactions : an international journal of inorganic chemistry, ISSN 1477-9234, 2011, Volume 40, Issue 3, pp. 549 - 558
...” boron ligands and metal-to-boron dative bonding Holger Braunschweig and Rian D. Dewhurst Received 7th September 2010, Accepted 29th October 2010 DOI: 10.1039... 
SIGMA-BOND | BLOCK METALS | BU-T | REACTIVITY | TRIS(METHIMAZOLYL)BORANE COMPLEXES | METALLABORATRANES | OXIDATIVE ADDITION | BORANE | BORYLENE COMPLEXES | CHEMISTRY, INORGANIC & NUCLEAR | Spectroscopy | Boron | Correlation | Transition metals | Ligands | Electron density | Lewis base | Bonding
Journal Article
Chemical Society reviews, ISSN 1460-4744, 2013, Volume 42, Issue 8, pp. 3197 - 328
...Chem Soc Rev TUTORIAL REVIEW Transition metal borylene complexes Holger Braunschweig,* Rian D. Dewhurst and Viktoria H. Gessner Borylene ligands (:BR... 
SUBSTITUTION | ABSTRACTION | ACTIVATION | BORON | LIGANDS | REACTIVITY | CHEMISTRY | COORDINATION | CHEMISTRY, MULTIDISCIPLINARY | ELECTRON-DENSITY | Transition metals | Synthesis | Bridging | Metalorganic compounds | Ligands | Terminals | Coordination compounds
Journal Article