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Angewandte Chemie International Edition, ISSN 1433-7851, 03/2016, Volume 55, Issue 12, pp. 3904 - 3908
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2016, Volume 55, Issue 12, p. n/a
Red Phosphorus M. Shatruk, D. T. McQuade et al. describe the activation of red phosphorus by nucleophilic attack of KOEt to produce soluble polyphosphide... 
polyanions | phosphorus allotropes | structure elucidation | NMR spectroscopy | flow chemistry | Nuclear magnetic resonance spectroscopy | Phosphorus | Anions | Chemistry | Scaling up | Activation | Potassium | Conversion | Flow
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 09/2019, Volume 58, Issue 18, pp. 11920 - 11926
A synthetic strategy featuring dicyanometalates [M(CN)(2)](-) (M = Ag, Au) as N-coordinating ditopic linkers connecting partially blocked Fe-II centers has... 
TRANSITION | FE(II) COMPLEXES | BEHAVIOR | HELICAL CHAINS | ISOMERISM | COORDINATION | CRYSTAL | ADSORPTION | COUNTERANIONS | CYANIDE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 09/2017, Volume 56, Issue 18, pp. 11096 - 11103
Heteroleptic complexes [Fe­(bpte)­(bim)]­X2 and [Fe­(bpte)­(xbim)]­X2 (bpte = S,S′-bis­(2-pyridylmethyl)-1,2-thioethane, bim = 2,2′-biimidazole, xbim =... 
CRYSTAL | TRANSITIONS | SCHIFF-BASE LIGANDS | DERIVATIVES | CHEMISTRY, INORGANIC & NUCLEAR | Iron compounds | Chemical properties | Research | Coordination compounds | Particle spin | Analysis
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2007, Volume 129, Issue 19, pp. 6104 - 6116
Pentanuclear, cyanide-bridged clusters [M(tmphen)2]3[M‘(CN)6]2 (M/M‘ = Zn/Cr (1), Zn/Fe (2), Fe/Fe (3), Fe/Co (4), and Fe/Cr (5); tmphen =... 
TRANSITION | ROOM-TEMPERATURE | CRYSTAL-STRUCTURE | BIMETALLIC ASSEMBLIES | MAGNETIC-PROPERTIES | TURNBULLS BLUE | IRON(II) | MOSSBAUER | CHARGE-TRANSFER | CHEMISTRY, MULTIDISCIPLINARY | Atomic properties | Spin coupling | Cyanides | Chemical properties | Isomerism | Analysis
Journal Article
Synlett, ISSN 0936-5214, 12/2018, Volume 29, Issue 20, pp. 2673 - 2678
Abstract We recently introduced a family of 6-NHC-Cu(I) catalysts that exhibit highest selectivities (regio- and enantio-) exclusively when aryl ethers are... 
letter | copper catalyst | regioselectivities | enantioselectivities | allylic borylation | N-heterocyclic carbenes | REAGENT | SUBSTITUTION | SITE | ALKYLATION | COMPLEXES | CHEMISTRY, ORGANIC | PHOSPHATES | BEARING | LIGAND
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 06/2016, Volume 55, Issue 12, pp. 5904 - 5913
Reactions of Fe­(II) precursors with the tetradentate ligand S,S′-bis­(2-pyridylmethyl)-1,2-thioethane (bpte) and monodentate NCE– coligands afforded... 
TRANSITION | ROOM-TEMPERATURE | POLYMERS | IRON(II) COMPLEXES | 2-STEP | BEHAVIOR | CRYSTAL | MONONUCLEAR COMPLEXES | MOSSBAUER | TRIAZINE LIGANDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie, ISSN 0044-8249, 03/2016, Volume 128, Issue 12, p. n/a
Roter Phosphor In ihrer Zuschrift auf S. 3972 ff. beschreiben M. Shatruk, D. T. McQuade et al. die Aktivierung von rotem Phosphor durch nukleophilen Angriff... 
Strukturaufklärung | Phosphorallotrope | Polyanionen | NMR-Spektroskopie | Flusschemie
Journal Article
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, ISSN 0002-7863, 11/2019, Volume 141, Issue 45, pp. 17989 - 17994
The nitroxyl radical 1-methyl-2-azaadamantane N-oxyl (Me-AZADO) exhibits magnetic bistability arising from a radical/dimer interconversion. The transition from... 
BISDITHIAZOLYL RADICALS | TEMPERATURE | DIMER | PHASE-TRANSITION | SPIN-CROSSOVER COMPLEXES | LIGHT-INDUCED INTERCONVERSION | ADAMANTANE | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie, ISSN 0044-8249, 03/2016, Volume 128, Issue 12, pp. 3972 - 3976
Soluble polyphosphide anions were successfully generated in a number of organic solvents by the reaction between shelf‐stable red phosphorus and potassium... 
Strukturaufklärung | Phosphorallotrope | Polyanionen | NMR-Spektroskopie | Flusschemie | Nuclear magnetic resonance spectroscopy | Solvents | Solid state | Spectroscopy | Anions | X-rays | Phosphorus | Potassium | Conversion
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 85, pp. 12045 - 12048
Oxidation of distorted square-planar perfluoropinacolate Co compound [Co-II(pin(F))(2)](2-), 1, to [Co-III(pin(F))(2)](1-), 2, is reported. Rigidly... 
FUNCTIONALIZATION | ELECTRONIC-PROPERTIES | SPIN | COMPLEXES | SUSCEPTIBILITY | RECENT PROGRESS | LIGAND | CHEMISTRY, MULTIDISCIPLINARY | CATALYSTS | CHALLENGES | 4-COORDINATE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2005, Volume 127, Issue 18, pp. 6766 - 6779
A series of bimetallic, trigonal bipyramidal clusters of type {[Co(N−N)2]3[Fe(CN)6]2} are reported. The reaction of {Co(tmphen)2}2+ with [Fe(CN)6]3- in MeCN... 
PRUSSIAN BLUE ANALOGS | ALKALI CATION | ROOM-TEMPERATURE | SINGLE-MOLECULE-MAGNET | GROUND-STATE | POLE INVERSION | MAGNETIZATION | COBALT-IRON CYANIDE | CHEMISTRY, MULTIDISCIPLINARY | C-I | PHOTOINDUCED FERRIMAGNETIC SYSTEMS | Iron compounds | Chemical properties | Research | Charge transfer
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2004, Volume 126, Issue 20, pp. 6222 - 6223
A charge-transfer-induced spin transition (CTIST) is observed in the discrete cyanide-bridged complex, {[Co(tmphen)2]3[Fe(CN)6]2}. Single-crystal X-ray... 
MAGNET | CLUSTER | CHEMISTRY, MULTIDISCIPLINARY | ORDERING TEMPERATURE | ISOMERISM | MOLECULES | Molecular structure | Transition metal complexes | Analysis | Atomic properties | Cyanides | Research | Charge transfer
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 10/2018, Volume 2018, Issue 38, p. 4298
Journal Article
ISSN 1359-7345, 10/2018, Volume 54, Issue 85, pp. 1245 - 1248
Oxidation of distorted square-planar perfluoropinacolate Co compound [Co II (pin F ) 2 ] 2− , 1 , to [Co III (pin F ) 2 ] 1− , 2 , is reported. Rigidly... 
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2018, Volume 54, Issue 85, pp. 12045 - 12048
Oxidation of distorted square-planar perfluoropinacolate Co compound [CoII(pinF)2]2−, 1, to [CoIII(pinF)2]1−, 2, is reported. Rigidly square-planar 2 has an... 
Oxidation | Crystallography
Journal Article
Inorganic chemistry, 09/2017, Volume 56, Issue 18, p. 11096
Heteroleptic complexes [Fe(bpte)(bim)]X and [Fe(bpte)(xbim)]X (bpte = S,S'-bis(2-pyridylmethyl)-1,2-thioethane, bim = 2,2'-biimidazole, xbim =... 
Journal Article
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