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Current Opinion in Chemical Biology, ISSN 1367-5931, 04/2017, Volume 37, pp. 63 - 70
The ability of cobalamin to coordinate different upper axial ligands gives rise to a diversity of reactivity. Traditionally, adenosylcobalamin is associated... 
Journal Article
Natural Product Reports, ISSN 0265-0568, 7/2018, Volume 35, Issue 7, pp. 612 - 614
The Natural Product Reports themed issue on 'Metalloenzymes in natural product biosynthetic pathways' is introduced by the Guest Editors, Katherine Ryan and... 
CHEMISTRY, ORGANIC | ANTIBIOTICS | CHEMISTRY, MEDICINAL | ENZYME | MECHANISM | BIOCHEMISTRY & MOLECULAR BIOLOGY | Enzymes - chemistry | Biological Products - metabolism | Biosynthetic Pathways | Enzymes - metabolism | Natural products
Journal Article
NATURE COMMUNICATIONS, ISSN 2041-1723, 03/2019, Volume 10, Issue 1, pp. 1101 - 10
Bacterial diheme peroxidases represent a diverse enzyme family with functions that range from hydrogen peroxide (H2O2) reduction to post-translational... 
REPLACEMENT | HEME | MAUG | CRYSTAL-STRUCTURE | STABILIZATION | MULTIDISCIPLINARY SCIENCES | TRYPTOPHAN TRYPTOPHYLQUINONE | METHYLAMINE DEHYDROGENASE | IRON | CYTOCHROME-C PEROXIDASE | LIGAND | Enzymes | Hydrogen peroxide | Magnetic resonance | Post-translation | Electrochemistry | Peroxidase | Iron | Burkholderia | Crystal structure
Journal Article
Current Opinion in Chemical Biology, ISSN 1367-5931, 04/2017, Volume 37, p. 63
Journal Article
Annual Review of Biochemistry, ISSN 0066-4154, 01/2018, Volume 87, p. 555
S-adenosylmethionine (AdoMet) has been referred to as both “a poor man's adenosylcobalamin (AdoCbl)” and “a rich man's AdoCbl,” but today, with the... 
Studies | Enzymes | Adenosylmethionine | Adenosylcobalamin | Vitamin B | Comparative analysis | Housing | Vitamin B12 | S-Adenosylmethionine | Cofactors | Crystal structure
Journal Article
Annual Review of Biochemistry, ISSN 0066-4154, 01/2017, Volume 86, p. 485
Living organisms sense and respond to light, a crucial environmental factor, using photoreceptors, which rely on bound chromophores such as retinal, flavins,... 
Photoreception | Gene regulation | Retina | Chromophores | Gene expression | Vitamin B12 | Mode of action | Signal transduction | Light | Vitamin B | Tetrapyrroles | Bacteria | Photoreceptors | Transduction
Journal Article
Nature, ISSN 0028-0836, 04/2017, Volume 544, Issue 7650, p. 322
Oxetanocin A (OXT-A) is a potent antitumour, antiviral and antibacterial compound. Biosynthesis of OXT-A has been linked to a plasmid-borne Bacillus megaterium... 
Proteins | Enzymes | Chemistry | Nuclear magnetic resonance--NMR | Genes | Biosynthesis | Kinases | Experiments
Journal Article
ACS Chemical Biology, ISSN 1554-8929, 02/2019, Volume 14, Issue 2, pp. 266 - 275
Leishmaniases affect the poorest people on earth and have no effective drug therapy. Here, we present the crystal structure of the mitochondrial isoform of... 
ENZYME | BIOCHEMISTRY & MOLECULAR BIOLOGY | SEQUENCE | REVEALS
Journal Article
ELIFE, ISSN 2050-084X, 02/2016, Volume 5, p. e13977
The metallocofactor involved in fixing nitrogen is not a rigid scaffold, as was previously thought. 
NITROGENASE | PROTEIN | LIGAND | FEMO-COFACTOR | BIOLOGY | Bacterial Proteins - metabolism | Iron | Nitrogen Fixation | Physiological aspects | Protein research | Coenzymes | Fixation | Research | Nitrogen | Proteins | Enzymes | Chemistry | X rays | Nitrates | Selenium | Catalysis | Carbon monoxide | Sulfur | Molybdenum | Cofactors
Journal Article
Proceedings of the National Academy of Sciences, USA, ISSN 0027-8424, 08/2016, Volume 113, Issue 35, pp. 9804 - 9804
Fumarate hydratases (FHs) are essential metabolic enzymes grouped into two classes. Here, we present the crystal structure of a class I FH, the cytosolic FH... 
Journal Article
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 04/2018, Volume 115, Issue 15, p. 3846
Pyruvate:ferredoxin oxidoreductase (PFOR) is a microbial enzyme that uses thiamine pyrophosphate (TPP), three [4Fe-4S] clusters, and coenzyme A (CoA) in the... 
Wood | Oxidoreductase | Carbon dioxide | Pyruvic acid | Metabolism | Greenhouse gases | Crystallography | Intermediates | Proteins | Carbon dioxide fixation | Microorganisms | Redox reactions | Vitamin B | Decarboxylation | Coenzyme A | Oxidation | Catalysis | Ferredoxin | Binding sites | Thiamine
Journal Article
Biochemistry, 07/2018, Volume 57, Issue 28, p. 4155
Calprotectin (CP, S100A8/S100A9 oligomer, MRP-8/MRP-14 oligomer) is a host-defense protein that sequesters nutrient transition metals from microbes. Each... 
Journal Article
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 11/2016, Volume 113, Issue 48, p. 13750
  HD domain phosphohydrolase enzymes are characterized by a conserved set of histidine and aspartate residues that coordinate an active site metallocenter.... 
Signal transduction | Phosphorylation | Gram-positive bacteria | Biochemistry | Biosynthesis | Enzyme kinetics | Crystal structure
Journal Article
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 11/2016, Volume 113, Issue 44, p. 12432
  Epothilones are thiazole-containing natural products with anticancer activity that are biosynthesized by polyketide synthase (PKS)-nonribosomal peptide... 
Proteins | Peptides | Simulation | Mutagenesis | Condensation | Crystal structure
Journal Article
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 08/2016, Volume 113, Issue 35, p. 9804
  Fumarate hydratases (FHs) are essential metabolic enzymes grouped into two classes. Here, we present the crystal structure of a class I FH, the cytosolic FH... 
Enzymes | Protozoa | Protein folding | Substrates | Crystal structure
Journal Article
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