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Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 43, pp. 13602 - 13605
A dual catalytic iron/lipase system has been developed and applied in the dynamic kinetic resolution of benzylic and aliphatic secondary alcohols. A detailed... 
kinetic resolution | chiral alcohols | reduction | hydrogenases | lipases | Catalysis | Lipase | Hydrogen | Acetates | Catalysts | Triacylglycerol lipase | Alcohol | Iron | Coordination compounds | Aliphatic compounds | Alcohols | Carbonyls
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2018, Volume 57, Issue 41, pp. 13439 - 13443
The first base‐metal‐catalysed hydrogenation of CO2‐derived carbonates to alcohols is presented. The reaction proceeds under mild conditions in the presence of... 
methanol | carbon dioxide | reduction | carbonates | manganese | CARBOXYLIC-ACID ESTERS | DIOXIDE | IRON CATALYST | RUTHENIUM | HOMOGENEOUS COBALT CATALYST | CHEMISTRY, MULTIDISCIPLINARY | CO2 CAPTURE | ALCOHOLS | PINCER COMPLEXES | CYCLIC CARBONATES | EFFICIENT | Glycols | Catalysis | Hydrogenation | Polycarbonates | Methanol | Metals | Carbon dioxide | Catalytic converters | Alcohols | Computer applications | Ligands | Carbonates | Diols | Manganese
Journal Article
ChemSusChem, ISSN 1864-564X, 2018, Volume 12, Issue 13, pp. 3099 - 3102
A new Mn‐catalyzed alkylation of secondary alcohols with non‐activated alcohols is presented. The use of a stable and well‐defined manganese pincer complex,... 
manganese catalysis | alkylation | alcohols | base metals | hydrogen autotransfer | GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY | COMPLEXES | BOND FORMATION | RUTHENIUM | IRON | CHEMISTRY, MULTIDISCIPLINARY | KETONES | BETA-ALKYLATION | ALPHA-ALKYLATION | LIGAND | COOPERATIVE METAL | EFFICIENT | Catalysis | Metal catalysts | Hydrogen | Alcohols | Halides | Ligands | Alcohol | Noble metals | Catalytic converters | Alkylation | Manganese
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2014, Volume 53, Issue 30, pp. 7923 - 7927
We describe herein a catalytic, enantioselective process for the synthesis of 4H‐chromenes which are important structural elements of many natural products and... 
benzhydrylic alcohols | asymmetric synthesis | chromenes | xanthenones | chiral phosphoric acids | ASYMMETRIC CATALYSIS | ONE-POT SYNTHESIS | ANNULATION | FUNCTIONALIZED 4H-CHROMENES | BOND-FORMING REACTIONS | SALICYL N-TOSYLIMINES | CHEMISTRY, MULTIDISCIPLINARY | FACILE CONSTRUCTION | SELECTIVE SYNTHESIS | EFFICIENT
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 01/2019, Volume 58, Issue 3, pp. 775 - 779
A metal‐catalyzed methylation process has been developed. By employing an air‐ and moisture‐stable manganese catalyst together with isotopically labeled... 
alkylation | transition-metal catalysis | trideuteromethylation | manganese | methylation | CD3 antigen | Catalysis | Methylation | Alkylation | Methanol | Manganese
Journal Article
Organic Letters, ISSN 1523-7060, 02/2018, Volume 20, Issue 3, pp. 696 - 699
A new iron-catalyzed chemoselective intramolecular hydroamination and hydroalkoxylation of the readily available α-allenic amines and alcohols to valuable... 
ALCOHOLS | ORGANIC-SYNTHESIS | HYDROGENATION | ALPHA-AMINOALLENES | COMPLEXES | 3-PYRROLINES | REACTIVITY | CHEMISTRY, ORGANIC | CYCLOISOMERIZATION | EFFICIENT | 2,3-DIHYDROFURANS
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 06/2015, Volume 357, Issue 9, pp. 2098 - 2104
A chiral dinuclear zinc complex can effectively catalyse the direct aldol reactions of pyruvic acid ester with various chiral sugar aldehydes, thus... 
aldol reaction | ulosonic acids | asymmetric synthesis | zinc catalysts | pyruvate esters | ACID | ENANTIOSELECTIVE SYNTHESIS | CHEMISTRY, ORGANIC | DAH | LIGANDS | ETHYL PYRUVATE | CHEMISTRY, APPLIED | WATER | Synthesis | Biomimetics | Diastereomers | Esters | Chemical properties | Aldehydes | Enolates | Organic compounds | Pyruvates | Dimethyl acetals | Formations | Zinc | Sugars
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2017, Volume 56, Issue 12, pp. 3129 - 3129
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2019, Volume 58, Issue 3, pp. 775 - 779
A metal-catalyzed methylation process has been developed. By employing an air- and moisture-stable manganese catalyst together with isotopically labeled... 
alkylation | transition-metal catalysis | trideuteromethylation | manganese | methylation | ENANTIOSELECTIVE FORMATION | BORROWING HYDROGEN | IRON | C-H FUNCTIONALIZATION | N-METHYLATION | CHEMISTRY, MULTIDISCIPLINARY | PRIMARY ALCOHOLS | MILD | KETONES | AMINES | ALPHA-ALKYLATION
Journal Article
Organic Letters, ISSN 1523-7060, 12/2018, Volume 20, Issue 24, pp. 7779 - 7783
The first example of manganese-catalyzed C-alkylation of the carboxylic acid derivatives is reported. The bench-stable homogeneous manganese complex enables... 
SECONDARY ALCOHOLS | KETONES | ASYMMETRIC TRANSFER HYDROGENATION | IRON CATALYSIS | STEREOSELECTIVE TRANSFER SEMIHYDROGENATION | C BOND FORMATION | BORROWING HYDROGEN | ALPHA-ALKYLATION | CHEMISTRY, ORGANIC | COOPERATIVE METAL | N-METHYLATION
Journal Article
Organic letters, ISSN 1523-7060, 01/2019, Volume 21, Issue 1, pp. 70 - 74
A general and selective metal-catalyzed conversion of biomass-derived primary diols and amines to the highly valuable 2,5-unsubstituted pyrroles has been... 
SECONDARY ALCOHOLS | KETONES | IRON CATALYSIS | CYCLIC IMIDES | BORROWING HYDROGEN | ALPHA-ALKYLATION | CHEMISTRY, ORGANIC | RUTHENIUM | N-HETEROCYCLIZATION | MULTICOMPONENT SYNTHESIS | COOPERATIVE METAL
Journal Article
Journal of organic chemistry, ISSN 0022-3263, 06/2019, Volume 84, Issue 12, pp. 7927 - 7935
A general and chemoselective catalytic alkylation of nitriles using a homogeneous nonprecious manganese catalyst is presented. This alkylation reaction uses... 
SECONDARY ALCOHOLS | KETONES | STEREOSELECTIVE TRANSFER SEMIHYDROGENATION | ONE-POT SYNTHESIS | CHEMISTRY, ORGANIC | RUTHENIUM | C-ALKYLATION | IRON | ARYLACETONITRILES | COOPERATIVE METAL | ALPHA-ARYL NITRILES
Journal Article