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solubility (12) 12
thermodynamics (10) 10
hydrolysis (8) 8
neptunium (8) 8
speciation (7) 7
chemistry, inorganic & nuclear (6) 6
complexes (5) 5
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Journal Article
Monatshefte für Chemie - Chemical Monthly, ISSN 0026-9247, 2/2018, Volume 149, Issue 2, pp. 237 - 252
The solubility behavior of hexavalent neptunium (Np) was systematically investigated as function of [CaCl2] = 0.25–4.5 mol dm−3 [0.252–5.26 mol (kg H2O)−1] and... 
Hydrolytic behavior | Calcium neptunates | Np L3-edge XANES | Calcium chloride brines | Theoretical and Computational Chemistry | Thermodynamics | Chemistry | Analytical Chemistry | Neptunium(VI) | Chemistry/Food Science, general | Physical Chemistry | Inorganic Chemistry | Organic Chemistry
Journal Article
Journal of Radioanalytical and Nuclear Chemistry, ISSN 0236-5731, 3/2017, Volume 311, Issue 3, pp. 1665 - 1671
Journal Article
Monatshefte fur Chemie / Chemical Monthly, ISSN 0026-9247, 02/2018, Volume 149, Issue 2, p. 237
To access, purchase, authenticate, or subscribe to the full-text of this article, please visit this link: http://dx.doi.org/10.1007/s00706-017-2116-4 The... 
Thermodynamics | Hazardous waste management industry | Calcium chloride
Journal Article
Applied Geochemistry, ISSN 0883-2927, 05/2019, Volume 104, pp. 10 - 18
The complexation of NpO2+ with fluoride is studied in aqueous solution using Vis/NIR absorption spectroscopy. The total ligand concentration (NaF), ionic... 
Thermodynamics | Complexation | Fluoride | Neptunium | Speciation | Nuclear waste | NP(V) COMPLEXES | NPO2 | CM(III) | PLUTONIUM | STABILITY-CONSTANTS | GEOCHEMISTRY & GEOPHYSICS | SULFATE | TRLFS | CHLORIDE | RANGE
Journal Article
Journal of Chemical Thermodynamics, ISSN 0021-9614, 04/2019, pp. 375 - 386
We have developed new chemical, thermodynamic and activity models for the system UO –Na –K –Mg –H –OH –Cl –H O(l) within the Pitzer approach. The new... 
Hydrolysis | KCl | MgCl | Solubility | NaCl | Pitzer | Uranium(VI)
Journal Article
Journal of Radioanalytical and Nuclear Chemistry, ISSN 0236-5731, 03/2017, Volume 311, Issue 3, p. 1665
Journal Article
Pure and Applied Chemistry, ISSN 0033-4545, 05/2015, Volume 87, Issue 5, pp. 487 - 502
The complexation of An /Ln with nitrate was investigated in dilute to concentrated Na–Mg–Ca–Cl–NO solutions at 2.94 ≤ pH ≤ 13.2 and = 22 ± 2 °C. Comprehensive... 
neodymium | curium | ISSP-16 | Pitzer model | quaternary complexes | solubility | nitrate | TRLFS | EXAFS | weak complexation | Nitrate | Neodymium | Quaternary complexes | Solubility | Weak complexation | Curium | Fine structure | Time resolved | Dilution | Fluorescence | Spectroscopic analysis | Nitrates | Mathematical models | Sodium chloride | Neodymium lasers | Solid phases | Magnesium chloride | Calcium chloride | Organic chemistry | X ray absorption | Spectroscopy | Absorption | X-ray diffraction
Journal Article
INORGANIC CHEMISTRY, ISSN 0020-1669, 01/2020, Volume 59, Issue 1, pp. 8 - 22
Neptunium(V) and uranium(VI) are precipitated from an aqueous potassium-sodium-containing carbonate-rich solution, and the solid phases are investigated. U/Np... 
U(VI) | URANYL | MINERALS | CRYSTAL-STRUCTURE | COMPLEXES | SORPTION | SURFACE | ABSORPTION SPECTROSCOPY | NP(V) | SOLUBILITY | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
ISSN 1359-7345, 11/2018, Volume 54, Issue 91, pp. 12824 - 12827
Pu L 3 HR-XANES and FEFF9 computations provide evidence for band-like 6d states in colloidal Pu contrasting to narrow 6d states in molecular Pu( iv ). Pu L 3... 
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 11/2018, Volume 54, Issue 91, pp. 12824 - 12827
Pu L-3 HR-XANES and FEFF9 computations provide evidence for band-like 6d states in colloidal Pu contrasting to narrow 6d states in molecular Pu(iv). Pu L-3... 
X-RAY-ABSORPTION | CHEMISTRY, MULTIDISCIPLINARY | OXIDE
Journal Article
The Journal of Chemical Thermodynamics, ISSN 0021-9614, 01/2018, Volume 116, pp. 309 - 315
[Display omitted] •Complexation of NpO2+ with SO42− is studied as a function of T and Im by UV/Vis/NIR.•log β0(T), ΔrH0m, ΔrS0m is determined at IUPAC... 
Thermodynamics | Spectroscopy | Complexation | Sulfate | Neptunium | FLUORESCENCE SPECTROSCOPY | SOLVENT POLARITY | 200 DEGREES-C | CHEMISTRY, PHYSICAL | NP(V) COMPLEXATION | STABILITY-CONSTANTS | ABSORPTION-SPECTRA | ELEVATED-TEMPERATURES | TRIVALENT ACTINIDES | INORGANIC LIGANDS | EXTRACTION EQUILIBRIA | Sulfates
Journal Article
Radiochimica Acta, ISSN 0033-8230, 06/2016, Volume 104, Issue 6, pp. 355 - 379
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 11/2017, Volume 56, Issue 22, pp. 13982 - 13990
Pu­(III), Pu­(IV), and a higher oxidation state of Pu, likely Pu­(VI), are for the first time characterized simultaneously present in a borosilicate glass... 
URANIUM | NUCLEAR-WASTE | HR-XANES | SPECTROSCOPY | SPECIATION | X-RAY-ABSORPTION | NEUTRON-DIFFRACTION | SYSTEMS | CERAMIC WASTE FORMS | PLUTONIUM SOLUBILITY | CHEMISTRY, INORGANIC & NUCLEAR | Silicon compounds | Plutonium | Chemical properties
Journal Article
The Journal of Chemical Thermodynamics, ISSN 0021-9614, 04/2019, Volume 131, pp. 375 - 386
•New Pitzer activity model for the system UO22+–Na+–K+–Mg2+–H+–OH−–Cl−–H2O(l).•Uranium(VI) solubility studies in dilute to concentrated MgCl2... 
Hydrolysis | MgCl2 | KCl | Solubility | NaCl | Pitzer | Uranium(VI) | HYDROLYSIS CONSTANTS | TRANSFORMATION | COMPLEXES | CHEMISTRY, PHYSICAL | OSMOTIC COEFFICIENTS | ELECTROLYTES | THERMODYNAMICS | EQUILIBRIA | SPECIATION | SCHOEPITE | Energy Sciences | INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Journal Article
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