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Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 11, pp. 3552 - 3565
The recent uptake of molecular metathesis catalysts in specialty‐chemicals and pharmaceutical manufacturing is reviewed. The metathesis industry: Olefin... 
olefin metathesis | large-scale synthesis | renewable feedstocks | industrial chemistry | pharmaceutical chemistry | BILN-2061 | SB-462795 | OILS | CONVERGENT | CHEMISTRY, MULTIDISCIPLINARY | DISCOVERY | RING-CLOSING METATHESIS | ETHENOLYSIS | HCV PROTEASE INHIBITOR | Olefins | Reviews | Catalysts | Metathesis | Decomposition reactions | Manufacturing | Chemicals | Pharmaceuticals
Journal Article
Current Organic Chemistry, ISSN 1385-2728, 01/2006, Volume 10, Issue 2, pp. 185 - 202
Recent advances in ruthenium-catalyzed ring closing metathesis are discussed, in context of both substrate and catalyst parameters. As well as thermodynamic... 
Methylidene | Oligomerization | Cycloadditions | ADMET | Non-metathesis reaction | Lactones | 1,4-POLYBUTADIENE SYSTEM | QUANTITATIVE DESCRIPTION | TANDEM CATALYSIS | GRUBBS CARBENE | POLYMERIZATION/DEPOLYMERIZATION EQUILIBRIUM | CHEMISTRY, ORGANIC | OLEFIN-METATHESIS | RECYCLABLE CATALYST | IONIC LIQUID | N-HETEROCYCLIC CARBENES | BY-PRODUCTS
Journal Article
Organometallics, ISSN 0276-7333, 12/2018, Volume 37, Issue 24, pp. 4551 - 4555
The controlled reaction of [RuCl2(p-cymene)]2 with H2IMes generates the previously challenging precatalyst and Ru synthon RuCl2(p-cymene)­(H2IMes) (Ru-2) in... 
HYDROGENATION | RING-CLOSING METATHESIS | CHEMICAL-SHIFTS | LIGANDS SYNTHESIS | RUTHENIUM COMPLEXES | DECOMPOSITION | CHEMISTRY, ORGANIC | ACCEPTOR PROPERTIES | POLYMERIZATION | N-HETEROCYCLIC CARBENES | ACRYLATE METATHESIS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Catalysis science & technology, ISSN 2044-4761, 2018, Volume 8, Issue 6, pp. 1535 - 1544
Phosphine-scavenging Merrifield resins can significantly facilitate the synthesis of highly active Ru metathesis catalysts, including the second-generation... 
RUTHENIUM COMPLEXES BEARING | PHOSPHINE | LIGANDS | HYDROGEN CARBONATES | ISOMERIZATION | HYDROLYSIS | CHEMISTRY, PHYSICAL | N-HETEROCYCLIC CARBENES | EFFICIENT | GRUBBS CATALYSTS | METAL-COMPLEXES | Polystyrene resins | Catalysts | Reproducibility | Metathesis | Decomposition reactions | Ligands | Crosslinking | Catalysis | Chemical synthesis
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 10/2010, Volume 16, Issue 38, pp. 11720 - 11725
Journal Article
ISSN 2044-4753, 3/2018, Volume 8, Issue 6, pp. 1535 - 1544
Phosphine-scavenging resins can significantly facilitate the synthesis of highly active Ru metathesis catalysts, including the second-generation Grubbs,... 
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2018, Volume 140, Issue 22, pp. 6931 - 6944
The correlation between rapid initiation and rapid decomposition in olefin metathesis is probed for a series of fast-initiating, phosphine-free Ru catalysts:... 
HETEROCYCLIC CARBENE LIGAND | ALKYLIDENE COMPLEXES | CROSS-METATHESIS | METALLACYCLOBUTANE DEPROTONATION | RING-CLOSING METATHESIS | CORRELATED MOLECULAR CALCULATIONS | DENSITY-FUNCTIONAL THEORY | ARYL SUBSTITUENT | CHEMISTRY, MULTIDISCIPLINARY | GAUSSIAN-BASIS SETS | GRUBBS CATALYSTS
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2016, Volume 138, Issue 44, pp. 14668 - 14677
.... These include benzylidene derivatives RuCl2(NHC)­(PCy3)­(CHPh) (Ru-2: NHC = H2IMes, a; IMes, b; H2IPr, c; IPr, d; H2ITol, e) and indenylidene complexes RuCl2... 
BOND ACTIVATION REACTIONS | RING-CLOSING METATHESIS | HETEROCYCLIC CARBENE LIGANDS | NHC LIGANDS | RUTHENIUM | OLEFIN METATHESIS | CATHEPSIN K-INHIBITOR | CHEMISTRY, MULTIDISCIPLINARY | MASS-SPECTROMETRY | GRUBBS CATALYSTS | METAL-COMPLEXES | Lewis structures | Usage | Chemical properties | Catalysts
Journal Article
Catalysis Science and Technology, ISSN 2044-4753, 04/2016, Volume 6, Issue 7, pp. 2077 - 2084
Conversion of essential-oil allylbenzenes (phenylpropenoids) to high-value fine chemicals via isomerization–metathesis is reported. The target reaction... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2007, Volume 47, Issue 2, pp. 303 - 306
Getting the air out: A bottleneck in transition‐metal chemistry is the laborious process of identifying organometallic molecules. Anaerobic, charge‐transfer... 
reaction mechanisms | mass spectrometry | charge‐transfer ionization | inert atmosphere | analytical methods | Analytical methods | Inert atmosphere | Reaction mechanisms | Mass spectrometry | Charge-transfer ionization | MATRIX | COMPLEXES | charge-transfer ionization | TRANSFER IONIZATION | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
ChemCatChem, ISSN 1867-3880, 08/2016, Volume 8, Issue 15, pp. 2422 - 2422
...‐defined molecular species, and exiting as ruthenium nanoparticles (RuNPs). In their Communication, C. S. Higman, A. E. Lanterna et al... 
nanoparticles | metathesis | isomerization | side reactions | catalyst decomposition
Journal Article
ChemCatChem, ISSN 1867-3880, 08/2016, Volume 8, Issue 15, pp. 2424 - 2424
The front cover artwork for Issue 15/2016 is provided by the Fogg and Scaiano groups at the University of Ottawa (Canada). The image shows a well‐defined,... 
Nanoparticles | Ruthenium | Isomerization | Olefins
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2017, Volume 139, Issue 46, pp. 16446 - 16449
Brønsted bases of widely varying strength are shown to decompose the metathesis-active Ru intermediates formed by the second-generation Hoveyda and Grubbs... 
RUTHENIUM-CARBENES | BOND ACTIVATION REACTIONS | PHOSPHINE | RING-CLOSING METATHESIS | HETEROCYCLIC CARBENE LIGANDS | CRYSTAL-STRUCTURE | STABILITY | COMPLEXES | ACRYLATE METATHESIS | 2ND-GENERATION GRUBBS CATALYST | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
ISSN 2044-4753, 4/2016, Volume 6, Issue 7, pp. 277 - 284
Conversion of essential-oil allylbenzenes (phenylpropenoids) to high-value fine chemicals via isomerization-metathesis is reported. The target reaction... 
Journal Article
Chemical science (Cambridge), ISSN 2041-6520, 2015, Volume 6, Issue 12, pp. 6739 - 6746
The inverse relationship between NHC donicity and catalyst initiation. Strong σ-donation from NHC ligands (NHC = N-heterocyclic carbene) is shown to have... 
TRANSITION-METAL-COMPLEXES | LIGANDS | MECHANISM | MOLECULAR-STRUCTURE | CHEMICAL-SHIFTS | OLEFIN METATHESIS REACTIONS | DECOMPOSITION | PI-ACCEPTOR PROPERTIES | N-HETEROCYCLIC CARBENES | CHEMISTRY, MULTIDISCIPLINARY | ELECTRONIC-STRUCTURE | Catalysts | Bonding strength | Attenuation | Ligands | Derivatives | Catalysis | Carbenes | Phosphines
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2018, Volume 140, Issue 5, pp. 1604 - 1607
Ring-closing metathesis (RCM) offers versatile catalytic routes to macrocycles, with applications ranging from perfumery to production of antiviral drugs.... 
METALLACYCLOBUTANE DEPROTONATION | CONSTANTS | MECHANISM | COMPLEXES | DECOMPOSITION | OLEFIN METATHESIS | INHIBITOR | EFFICIENT | CHEMISTRY, MULTIDISCIPLINARY | CATALYSTS | DISCOVERY | Antiviral agents | Ruthenium | Dichloropropane | Aniline | Chlorides | Analysis | Chemical properties | Hydrogen bonding
Journal Article
Chemical Science, ISSN 2041-6520, 12/2015, Volume 6, Issue 12, pp. 6739 - 6746
The inverse relationship between NHC donicity and catalyst initiation. Strong σ-donation from NHC ligands (NHC = N-heterocyclic carbene) is shown to have... 
Chemistry
Journal Article
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