X
Search Filters
Format Format
Subjects Subjects
Subjects Subjects
X
Sort by Item Count (A-Z)
Filter by Count
chemistry, multidisciplinary (32) 32
chemistry, inorganic & nuclear (30) 30
chemistry (25) 25
catalysts (21) 21
catalysis (20) 20
ligands (18) 18
activation (17) 17
frustrated lewis pairs (17) 17
chemical or physical processes, e.g. catalysis or colloidchemistry (14) 14
complexes (14) 14
performing operations (14) 14
physical or chemical processes or apparatus in general (14) 14
reactivity (14) 14
their relevant apparatus (14) 14
transporting (14) 14
chemistry, organic (13) 13
methanol (13) 13
chemical properties (12) 12
crystallography (12) 12
derivatives (12) 12
gaz carbonique (11) 11
reduction (11) 11
catalyse (10) 10
hydrogenation (10) 10
organic chemistry (10) 10
paire d'électrons de lewis (10) 10
zirconium (10) 10
acyclic, carbocyclic or heterocyclic compounds containingelements other than carbon, hydrogen, halogen, oxygen, nitrogen,sulfur, selenium or tellurium (9) 9
carbon dioxide (9) 9
co2 (9) 9
hydroboration (9) 9
metallurgy (9) 9
acides de lewis (8) 8
borane (8) 8
boron (8) 8
carbon-dioxide (8) 8
hydrosilylation (8) 8
materials science, multidisciplinary (8) 8
bond activation (7) 7
boranes (7) 7
coordination (7) 7
homogeneous hydrogenation (7) 7
hydrogen (7) 7
molecular-orbital methods (7) 7
molécules ambiphiles (7) 7
n-heterocyclic carbene (7) 7
phosphine (7) 7
réduction (7) 7
adsorption (6) 6
chemical synthesis (6) 6
conversion (6) 6
hydrogène (6) 6
matériaux mésoporeux (6) 6
research (6) 6
silicon dioxide (6) 6
structural-characterization (6) 6
alkenes (5) 5
apparatus therefor (5) 5
borabenzene derivatives (5) 5
c-h activation (5) 5
catalytic-reduction (5) 5
chemistry, physical (5) 5
general methods of organic chemistry (5) 5
index medicus (5) 5
lewis acids (5) 5
mesoporous materials (5) 5
mesoporous silica (5) 5
molecular-structure (5) 5
nanoscience & nanotechnology (5) 5
polymerization (5) 5
separation (5) 5
silica (5) 5
silice (5) 5
zirconium complexes (5) 5
alcènes (4) 4
amines (4) 4
analysis (4) 4
arenes (4) 4
boranes -- dérivés (4) 4
borylation (4) 4
c-h borylation (4) 4
carbone (4) 4
chemical bonds (4) 4
composés organorhodiés (4) 4
coordination chemistry (4) 4
cross-coupling reactions (4) 4
diborane (4) 4
highly efficient (4) 4
ketones (4) 4
lewis acid (4) 4
ligand (4) 4
metal-complexes (4) 4
methane (4) 4
méthanol (4) 4
olefin polymerization (4) 4
organocatalysis (4) 4
porosity (4) 4
rare earth elements (4) 4
rhodium (4) 4
silanes (4) 4
more...
Language Language
Publication Date Publication Date
Click on a bar to filter by decade
Slide to change publication date range


Science, ISSN 0036-8075, 07/2015, Volume 349, Issue 6247, pp. 513 - 516
Transition metal complexes are efficient catalysts for the C-H bond functionalization of heteroarenes to generate useful products for the pharmaceutical and... 
FREE HYDROGEN ACTIVATION | REDUCTION | SCOPE | MULTIDISCIPLINARY SCIENCES | ARENES | CONSTRUCTION | ARYLATION | DEPROTONATION MECHANISM | FRUSTRATED-LEWIS-PAIR | INSIGHTS | Chemical bonds | Models | Catalysis | Chemical properties | Transition metal compounds | Identification and classification | Hydrogen bonds | Catalysts | Metals | Lewis acid | Transition metals | Pyrroles | Activation | Furans | Selectivity | Bonding
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2014, Volume 20, Issue 11, pp. 2990 - 2996
Metal‐free systems, including frustrated Lewis pairs (FLPs) have been shown to bind CO2. By reducing the Lewis acidity and basicity of the ambiphilic system,... 
organocatalysis | carbon dioxide | reduction | main group elements | frustrated Lewis pairs | FREE HYDROGEN ACTIVATION | N-HETEROCYCLIC CARBENE | METHANOL | CO2 REDUCTION | CONVERSION | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | HOMOGENEOUS HYDROGENATION | PHOSPHINE-BORANE | FIXATION | Greenhouse effect | Carbon dioxide | Catalysts | Methyl alcohol | Deoxygenation | Derivatives | Catalysis | Conversion | Basicity
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2013, Volume 135, Issue 25, pp. 9326 - 9329
In this work, we report that organocatalyst 1-Bcat-2-PPh2–C6H4 ((1); cat = catechol) acts as an ambiphilic metal-free system for the reduction of carbon... 
HOMOGENEOUS HYDROGENATION | CONVERSION | HYDROSILYLATION | FRUSTRATED LEWIS PAIRS | CATALYST | CARBON-DIOXIDE | CHEMISTRY, MULTIDISCIPLINARY | FIXATION | Carbon Dioxide - chemistry | Phosphines - chemistry | Oxidation-Reduction | Boranes - chemistry | Molecular Structure | Catalysis | Methanol - chemistry | Methanol - chemical synthesis
Journal Article
Accounts of Chemical Research, ISSN 0001-4842, 02/2018, Volume 51, Issue 2, pp. 454 - 464
Conspectus Ambiphilic molecules were first used as functional ligands for transition elements, which could enable intriguing organometallic transformations. In... 
ACTIVATION | METHANOL | C-H BOND | HYDROGENATION | CO2 REDUCTION | AMPHOTERIC LIGANDS | B-B | CARBON-DIOXIDE | CHEMISTRY, MULTIDISCIPLINARY | BORYLATION | FRUSTRATED-LEWIS-PAIR
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 07/2014, Volume 136, Issue 30, pp. 10708 - 10717
The full mechanism of the hydroboration of CO2 by the highly active ambiphilic organocatalyst 1-Bcat-2-PPh2–C6H4 (Bcat = catecholboryl) was determined using... 
HOMOGENEOUS HYDROGENATION | FORMIC-ACID | N-HETEROCYCLIC CARBENE | CARBON-DIOXIDE FIXATION | CATALYTIC-REDUCTION | MOLECULAR-ORBITAL METHODS | CONVERSION | COMPLEXES | HYDROSILYLATION | CHEMISTRY, MULTIDISCIPLINARY | BASE
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2017, Volume 23, Issue 15, pp. 3567 - 3571
The cleavage of a Csp3−H bond by an N/B frustrated Lewis pair (FLP) is reported. Upon mild heating, the ambiphilic molecule (2‐NMe2‐C6H4)2BH activates the C−H... 
Csp3−H activation | amineboranes | N–B heterocycles | quantum mechanical calculations | frustrated Lewis pairs | Csp | H activation | Nitrogen
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2016, Volume 55, Issue 41, pp. 12722 - 12726
Journal Article
Coordination chemistry reviews, ISSN 0010-8545, 2017, Volume 334, pp. 124 - 135
•Phosphine-aluminum frustrated Lewis pairs (FLPs) can activate CO2 but show significant stability issues.•The Lewis acidity and basicity need to be fine-tuned... 
Boron | C-H activation | Ambiphilic molecules | Aluminum | Frustrated Lewis pairs | Carbon dioxide | METHANOL | DIRECT ARYLATION | CO2 REDUCTION | SMALL MOLECULES | IRON CATALYSTS | BORANE | CHEMISTRY, INORGANIC & NUCLEAR | CARBENE CATALYSTS | METAL-FREE HYDROGENATION | BOND ACTIVATION | C-H BORYLATION | Transition metal compounds | Catalysis | Catalysts
Journal Article
ChemCatChem, ISSN 1867-3880, 06/2017, Volume 9, Issue 11, pp. 1886 - 1890
The physical phenomenon of gas oversolubility in nanoconfined liquids was successfully applied for the catalytic cycloaddition of carbon dioxide to epoxides to... 
carbon dioxide | cycloaddition | supported catalysts | mesoporous materials | oversolubility | GAS SOLUBILITY | PROPYLENE CARBONATE | CO2 | COMPLEXES | CHEMISTRY, PHYSICAL | ORGANIC CARBONATES | EPOXIDES | HOMOGENEOUS CATALYST | IONIC LIQUIDS | EFFICIENT | Silica | Carbonates | Atmospheric carbon dioxide
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2016, Volume 52, Issue 31, pp. 5387 - 5390
Air and moisture-stable fluoroborate derivatives of (tetramethylpiperidino)benzene are stable and convenient precatalysts for the dehydrogenative borylation of... 
BORONIC ACID | HYDROGENATION | REAGENTS | REDUCTION | CO2 | CONVENIENT | BOND ACTIVATION | CATALYZED BORYLATION | CHEMISTRY, MULTIDISCIPLINARY | ARYLBORONIC ACIDS | INSIGHTS | Synthesis (chemistry) | Stability | Catalysts | Analogue | Dehydrogenation | Chemical reactions | Derivatives | Catalysis
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2015, Volume 51, Issue 48, pp. 9797 - 9800
The FLP species 1-BR -2-NMe -C H (R = 2,4,6-Me C H , 2,4,5-Me C H ) reacts H /CO to give formyl, acetal and methoxy-derivatives. The FLP species 1-BR -2-NMe -C... 
HOMOGENEOUS HYDROGENATION | TRANSFORMATION | N-HETEROCYCLIC CARBENE | METHANOL | HYDROBORATION | CATALYTIC-REDUCTION | CONVERSION | CO2 | HYDROSILYLATION | CARBOXYLATION | CHEMISTRY, MULTIDISCIPLINARY | Reduction | Hydrogen storage | Activation | Hydrogenation | Carbon dioxide
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2011, Volume 47, Issue 39, pp. 11131 - 11133
Species R(2)PCH(2)AlMe(2) (R = Me, Ph) are stable Lewis adducts but still react with CO(2) both in solution and in the solid state. The CO(2) adducts undergo a... 
Journal Article
Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences, ISSN 1471-2962, 2017, Volume 375, Issue 2101, p. 20170004
In this concept article, we consider the notion of 'frustrated Lewis pairs' (FLPs). While the original use of the term referred to steric inhibition of dative... 
Main group chemistry | Segregation of lewis acid and base | Frustrated Lewis pair chemistry | ACTIVATION | HYDROGENATION | MULTIDISCIPLINARY SCIENCES | REACTIVITY | CARBONYL-COMPOUNDS | BORANE | main group chemistry | segregation of Lewis acid and base | HETEROARENES | DIHYDROGEN | frustrated Lewis pair chemistry | PHOSPHINES | CHEMISTRY | BORYLATION | 143 | Review | 1002
Journal Article
Chemical communications (Cambridge, England), ISSN 1359-7345, 2014, Volume 50, Issue 77, pp. 11362 - 11365
The hydroboration of carbon dioxide into methoxyboranes by borane–dimethylsulfide using different base catalysts, including notably non-nucleophilic proton... 
HYDROBORATION | METHANOL | REDUCTION | CO2 | 1,8-BIS(DIMETHYLAMINO)NAPHTHALENE | BOROHYDRIDE | CHEMISTRY, MULTIDISCIPLINARY | CHELATING BIDENTATE LIGANDS | DIBORANE | HYDRIDE | Catalysts | Ion pairs | Carbon dioxide | Activation | Sponges | Transformations | Catalysis | Lewis base
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 04/2011, Volume 17, Issue 15, pp. 4254 - 4265
The influence of pore surface functionalities in mesoporous SBA‐15 silica on the stability of a model olefin metathesis catalyst, namely Grubbs I, is... 
olefin metathesis | phosphines | surface chemistry | heterogeneous catalysis | Grubbs catalyst | mesoporous materials | MCM-41 SILICAS | OLEFIN METATHESIS CATALYSTS | RECYCLABILITY | ADSORPTION | CHEMISTRY, MULTIDISCIPLINARY | NMR | RUTHENIUM CARBENES | DIENE | HOVEYDA-GRUBBS | CONDENSATION | Stability | Catalysts | Olefins | Decomposition reactions | Metathesis | Porosity | Catalysis | Silicon dioxide
Journal Article