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1. Full Text Competition between hydrogen bonds and van der Waals forces in intermolecular structure formation of protonated branched-chain alcohol clustersElectronic supplementary information (ESI) available: Temperature-dependent relative population of H+(MeOH)n (n = 4-8). Temperature-dependent relative population of H+(2-PrOH)4. Temperature-dependent relative population of H+(t-BuOH)n (n = 4-8). Relative energies of structurally distinct isomers for H+(MeOH)4, H+(EtOH)4, H+(2-PrOH)4, and H+(t-BuOH)4. Simulated IR spectra of H+(MeOH)n (n = 4-8). Simulated IR spectra of H+(2-PrOH)4. Simulated IR spectra of H+(t-BuOH)n (n = 4-8). The minimum free energy strcutures of H+(2-PrOH)4 and H+(t-BuOH)n (n = 4-8). See DOI: 10.1039/c8cp05222k
by Sugawara, Natsuko and Hsu, Po-Jen and Fujii, Asuka and Kuo, Jer-Lai
ISSN 1463-9076, 10/2018, Volume 2, Issue 39, pp. 25482 - 25494
To investigate the influence of bulky alkyl groups on hydrogen-bonded (H-bonded) network structures of alcohols, infrared (IR) spectra of protonated clusters... 
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2. Competition between hydrogen bonds and van der Waals forces in intermolecular structure formation of protonated branched-chain alcohol clusters (Electronic supplementary information (ESI) available: Temperature-dependent relative population of H+(MeOH)n (n = 4–8). Temperature-dependent relative population of H+(2-PrOH)4. Temperature-dependent relative population of H+(t-BuOH)n (n = 4–8). Relative energies of structurally distinct isomers for H+(MeOH)4, H+(EtOH)4, H+(2-PrOH)4, and H+(t-BuOH)4. Simulated IR spectra of H+(MeOH)n (n = 4–8). Simulated IR spectra of H+(2-PrOH)4. Simulated IR spectra of H+(t-BuOH)n (n = 4–8). The minimum free energy strcutures of H+(2-PrOH)4 and H+(t-BuOH)n (n = 4–8). See DOI: 10.1039/c8cp05222k)
by Natsuko Sugawara and Po-Jen Hsu and Asuka Fujii and Jer-Lai Kuo
Physical Chemistry Chemical Physics : PCCP, ISSN 1463-9076, 01/2018, Volume 20, Issue 39, pp. 25482 - 25494
To investigate the influence of bulky alkyl groups on hydrogen-bonded (H-bonded) network structures of alcohols, infrared (IR) spectra of protonated clusters... 
Temperature dependence | Butyl alcohol | Infrared spectroscopy | Computer simulation | Van der Waals forces | Chain branching | Alcohol | Infrared spectra | Isomers | Hydrogen bonding | Superposition (mathematics) | Dispersion | Free energy | Alcohols | Ring structures | Hydrogen bonds | Clusters | Population | Density functional theory | Preferences | Quantitative analysis
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3. Full Text Cooperative Polar/Steric Strategy in Achieving Site‐Selective Photocatalyzed C(sp3)−H Functionalization
by Yamada, Keiichi and Fukuyama, Takahide and Fujii, Saki and Ravelli, Davide and Fagnoni, Maurizio and Ryu, Ilhyong
Chemistry – A European Journal, ISSN 0947-6539, 06/2017, Volume 23, Issue 36, pp. 8615 - 8618
Synergistic control over the SH2 transition states of hydrogen ion exploiting polar and steric effects provides a promising cooperative strategy for... 
C−H functionalization | steric effects | decatungstate | site-selectivity | photocatalysis | HYDROGEN-ATOM TRANSFER | ALKYLATION | BENZYLATION | ALIPHATIC NITRILES | C-H functionalization | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | CHALLENGES | PHOTOREDOX CATALYSIS | BROMINE | DECATUNGSTATE PHOTOCATALYSIS | RADICALS | Catalysis | Lactones | Ketones | Hydrogen bonds | Cyclohexanone | Hydrogen | Photocatalysis | Chemical bonds | Strategy | Steric effects | Bearing | Methylene
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4. Full Text Double CH Functionalization in Sequential Order: Direct Synthesis of Polycyclic Compounds by a Palladium‐Catalyzed CH Alkenylation–Arylation Cascade
by Ohno, Hiroaki and Iuchi, Mutsumi and Kojima, Naoto and Yoshimitsu, Takehiko and Fujii, Nobutaka and Tanaka, Tetsuaki
Chemistry – A European Journal, ISSN 0947-6539, 04/2012, Volume 18, Issue 17, pp. 5352 - 5360
Palladium‐catalyzed cascade CH alkenylation and arylation provides convenient access to polycyclic aromatic compounds. Treatment of 3‐bromoaniline derivatives... 
palladium | CH bond activation | domino reactions | heterocycles | polycycles | C-H bond activation | NITROGEN-CONTAINING HETEROCYCLES | ACTIVATION | C?H bond activation | BOND FUNCTIONALIZATION | EFFICIENT SYNTHESIS | PALLADIUM-CATALYZED TANDEM CYCLIZATION | CHEMISTRY, MULTIDISCIPLINARY | BIOLOGICAL EVALUATION | DIRECT CONSTRUCTION | FUSED POLYCYCLES | ARYL IODIDES | Benzofurans - chemistry | Polycyclic Compounds - chemistry | Cyclization | Hydrogen Bonding | Polycyclic Compounds - chemical synthesis | Catalysis | Palladium - chemistry | Alkylation | Construction | Benzothiophene | Aniline | Aromatic compounds | Cascades | Indoles | Derivatives | Substrates
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5. Full Text Infrared photodissociation spectroscopy of H+(H 2O)6·Mm (M = Ne, Ar, Kr, Xe, H 2, N2, and CH4): Messenger-dependent balance between H3O+ and H5O2+ core isomers
by Mizuse, Kenta and Fujii, Asuka
Physical Chemistry Chemical Physics, ISSN 1463-9076, 04/2011, Volume 13, Issue 15, pp. 7129 - 7135
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6. Full Text Contiguous radical pivaloyloxymethylation–directed C(sp3)–H iodination of N-tosyl cycloalkanecarbaldimine
by Fujii, Shintaro and Nakano, Mayu and Yamaoka, Yousuke and Takasu, Kiyosei and Yamada, Ken-ichi and Tomioka, Kiyoshi
Tetrahedron Letters, ISSN 0040-4039, 06/2015, Volume 56, Issue 23, pp. 3086 - 3089
A reaction of -tosyl cycloalkanecarbaldimines with iodomethyl pivalate was initiated by triethylborane to give pivaloyloxymethylated products bearing... 
Aminyl radical generation | C[sbnd]C bond formation | Radical reactions | C[sbnd]H functionalization | Cascade reactions | CH functionalization | CC bond formation | DIMETHYLZINC | IMINES | CHEMISTRY, ORGANIC | CARBON-HYDROGEN BONDS | C-H functionalization | ALKYL IODIDES | C-H BONDS | DIRECT ETHYNYLATION | C-C bond formation | PALLADIUM-CATALYZED ARYLATION | CARBOXYLIC-ACID DERIVATIVES | PHOTOCHEMICAL REACTION | CONJUGATE ADDITION | Schiff bases
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7. Full Text Influence of the microsolvation on hemibonded and protonated hydrogen sulfide: infrared spectroscopy of [(H 2 S) n (X) 1 ] + and H + (H 2 S) n (X) 1 (n = 1 and 2, X = water, methanol, and ethanol)
by Hattori, Keigo and Wang, Dandan and Fujii, Asuka
Physical chemistry chemical physics : PCCP, ISSN 1463-9076, 07/2019, Volume 21, Issue 29, pp. 16064 - 16074
Changes of the excess charge accommodation motif in hemibonded and protonated hydrogen sulfide by microsolvation are studied by infrared spectroscopy of... 
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8. Full Text The CODATA 2017 values of h, e, k, and N-A for the revision of the SI
by Newell, DB and Cabiati, F and Fischer, J and Fujii, K and Karshenboim, SG and Margolis, HS and de Mirandes, E and Mohr, PJ and Nez, F and Pachucki, K and Quinn, TJ and Taylor, BN and Wang, M and Wood, BM and Zhang, Z
METROLOGIA, ISSN 0026-1394, 02/2018, Volume 55, Issue 1, pp. L13 - L16
Sufficient progress towards redefining the International System of Units (SI) in terms of exact values of fundamental constants has been achieved. Exact values... 
AVOGADRO CONSTANT | PHYSICS, APPLIED | fundamental constants | CRYSTAL | BALANCE | BOLTZMANN CONSTANT | ACOUSTIC THERMOMETRY | SI redefinition | KILOGRAM | INSTRUMENTS & INSTRUMENTATION | international system of units | GAS | PLANCK CONSTANT | FUNDAMENTAL PHYSICAL CONSTANTS | RECOMMENDED VALUES
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9. Full Text Tuning of the Internal Energy and Isomer Distribution in Small Protonated Water Clusters H+(H2O)4–8: An Application of the Inert Gas Messenger Technique
by Mizuse, Kenta and Fujii, Asuka
The Journal of Physical Chemistry A, ISSN 1089-5639, 05/2012, Volume 116, Issue 20, pp. 4868 - 4877
Infrared spectroscopy of gas-phase hydrated clusters provides us much information on structures and dynamics of water networks. However, interpretation of... 
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10. Full Text Structures of protonated hydrogen sulfide clusters, H + (H 2 S) n , highlighting the nature of sulfur-centered intermolecular interactions
by Wang, Dandan and Fujii, Asuka
Physical chemistry chemical physics : PCCP, ISSN 1463-9076, 01/2017, Volume 19, Issue 3, pp. 2036 - 2043
Unique intermolecular structures of protonated hydrogen sulfide clusters, H (H S) , are revealed by infrared spectroscopy and ab initio calculations. The... 
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11. Full Text Dual Gold Catalysis: Synthesis of Polycyclic Compounds via CH Insertion of Gold Vinylidenes
by Wieteck, Marcel and Tokimizu, Yusuke and Rudolph, Matthias and Rominger, Frank and Ohno, Hiroaki and Fujii, Nobutaka and Hashmi, A. Stephen K
Chemistry – A European Journal, ISSN 0947-6539, 12/2014, Volume 20, Issue 49, pp. 16331 - 16336
New and interesting polycyclic compounds have been synthesized from non‐conjugated diyne systems by dual gold catalysis. A quaternary carbon center in the... 
gold | CH insertion | vinylidene ligands | alkynes | polycycles | Vinylidene ligands | Gold | Polycycles | C-H insertion | Alkynes | CH insertion | ACTIVATION | PRECATALYSTS | CHEMISTRY, MULTIDISCIPLINARY | CARBOCYCLES | CYCLIZATIONS | HETEROCYCLES | HOMOGENEOUS CATALYSIS | 3-SILYLOXY-1,5-ENYNES | DERIVATIVES | HYDROARYLATION | Gold - chemistry | Polycyclic Compounds - chemistry | Alkynes - chemistry | Catalysis | Polycyclic Compounds - chemical synthesis | Backbone | Synthesis | Insertion | Activation | Carbon
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12. Full Text Innate production of T(H)2 cytokines by adipose tissue-associated c-Kit(+)Sca-1(+) lymphoid cells
by Moro, K and Yamada, T and Tanabe, M and Takeuchi, T and Ikawa, T and Kawamoto, H and Furusawa, J and Ohtani, M and Fujii, H and Koyasu, S
NATURE, ISSN 0028-0836, 01/2010, Volume 463, Issue 7280, pp. 540 - U160
Innate immune responses are important in combating various microbes during the early phases of infection. Natural killer (NK) cells are innate lymphocytes... 
NATURAL-KILLER-CELLS | ROR-GAMMA-T | EXPULSION | MULTIDISCIPLINARY SCIENCES | GENERATION | DIFFERENTIATION | IL-33 | EXPRESSION | MICE LACKING | INDUCER CELLS | LYMPHOCYTES | B-Lymphocytes - cytology | Cell Proliferation | Membrane Proteins - genetics | Humans | Mice, Inbred C57BL | Antigens, Ly - genetics | Gene Expression Regulation | Adipose Tissue - cytology | Membrane Proteins - immunology | Th2 Cells - immunology | Adipose Tissue - immunology | Proto-Oncogene Proteins c-kit - immunology | Nematoda - physiology | Animals | B-Lymphocytes - immunology | Lymphocytes - immunology | Antigens, Ly - immunology | Mesentery - immunology | Antigens, Ly - metabolism | Proto-Oncogene Proteins c-kit - genetics | Mice | Nematode Infections - immunology | Cytokines - immunology
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13. Full Text Acid–Base Formalism in Dispersion-Stabilized S–H···Y (YO, S) Hydrogen-Bonding Interactions
by Bhattacherjee, Aditi and Matsuda, Yoshiyuki and Fujii, Asuka and Wategaonkar, Sanjay
The Journal of Physical Chemistry A, ISSN 1089-5639, 02/2015, Volume 119, Issue 7, pp. 1117 - 1126
The role of sulfhydryl (S–H) group as hydrogen bond donor is not as well studied as that of hydroxyl (O–H). In this work we report on the hydrogen-bonding... 
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14. Full Text Spectral Characterization of Three-Electron Two-Center (3e–2c) Bonds of Gaseous CH3S∴S(H)CH3 and (CH3SH)2 + and Enhancement of the 3e–2c Bond upon Protonation
by Xie, Min and Shen, Zhitao and Wang, Dandan and Fujii, Asuka and Lee, Yuan-Pern
The Journal of Physical Chemistry Letters, ISSN 1948-7185, 07/2018, Volume 9, Issue 13, pp. 3725 - 3730
The three-electron two-center (3e–2c) bond plays an important role in structures and electron communication in biological systems involving cationic sulfur... 
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15. Full Text The natural flavonoid myricetin inhibits gastric H+, K+-ATPase
by Miyazaki, Yuu and Ichimura, Atsuhiko and Sato, Shun and Fujii, Takuto and Oishi, Shinya and Sakai, Hideki and Takeshima, Hiroshi
European Journal of Pharmacology, ISSN 0014-2999, 02/2018, Volume 820, pp. 217 - 221
Myricetin (3,3’,4’,5,5’,7-hexahydroxyflavone), a major flavonoid in berries and red wine, has been recently used as a health food supplement based on its... 
H+, K+-ATPase | Gastric acid secretion | Myricetin | Flavonoid | K | ATPase | POLYPHENOLS | PROTEIN | ACID-SECRETION | OMEPRAZOLE | PROTON PUMP INHIBITORS | PHARMACOLOGY & PHARMACY | ASSOCIATION | BINDING
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16. Full Text Tuning of the Internal Energy and Isomer Distribution in Small Protonated Water Clusters H+(H2O)(4-8): An Application of the Inert Gas Messenger Technique
by Mizuse, K and Fujii, A
JOURNAL OF PHYSICAL CHEMISTRY A, ISSN 1089-5639, 05/2012, Volume 116, Issue 20, pp. 4868 - 4877
Infrared spectroscopy of gas-phase hydrated clusters provides us much information on structures and dynamics of water networks. However, interpretation of... 
VIBRATIONAL PREDISSOCIATION SPECTRA | DENSITY | IR-SPECTRA | PHASE | COMPLEXES | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | AB-INITIO CALCULATIONS | CHEMISTRY, PHYSICAL | MICROSOLVATED HYDRONIUM | CATIONS INFRARED-SPECTROSCOPY | SHARED PROTON | ION-TRAP | Measurement | Infrared spectroscopy | Usage | Molecular spectra | Internal energy (Physics) | Analysis | Spectra | Research | Chemical properties | Hydration (Chemistry) | Gases, Rare
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17. Full Text Hydrogen-bonded ring closing and opening of protonated methanol clusters H+(CH3OH)n (n = 4-8) with the inert gas taggingElectronic supplementary information (ESI) available. Confirmation of the accuracy of B3LYP relative energy evaluation. The number of stable isomers of H+(MeOH)n optimized with B3LYP/6-31G(d). IR spectra of H+(MeOH)4 with one and two Ar and N2. Temperature dependence of simulated spectra of H+(MeOH)n (n = 5-8) and their comparison with bare and Ne/Ar-tagged spectra. Binding energies of Ar and Ne to H+(MeOH)n (n = 3-5). See DOI: 10.1039/c5cp03379a
by Li, Ying-Cheng and Hamashima, Toru and Yamazaki, Ryoko and Kobayashi, Tomohiro and Suzuki, Yuta and Mizuse, Kenta and Fujii, Asuka and Kuo, Jer-Lai
ISSN 1463-9076, 8/2015, Volume 17, Issue 34, pp. 2242 - 2253
The preferential hydrogen bond (H-bond) structures of protonated methanol clusters, H + (MeOH) n , in the size range of n = 4-8, were studied by size-selective... 
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18. Full Text Photoionization-induced π ↔ H site switching dynamics in phenol+-Rg (Rg = Ar, Kr) dimers probed by picosecond time-resolved infrared spectroscopy
by Miyazaki, Mitsuhiko and Sakata, Yuri and Schütz, Markus and Dopfer, Otto and Fujii, Masaaki
Physical Chemistry Chemical Physics, ISSN 1463-9076, 2016, Volume 18, Issue 35, pp. 24746 - 24754
The ionization-induced π↔ H site switching reaction in phenol(+)-Rg (PhOH(+)-Rg) dimers with Rg = Ar and Kr is traced in real time by picosecond time-resolved... 
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19. Full Text Direct Observation of Primary C−H Bond Oxidation by an Oxido‐Iron(IV) Porphyrin π‐Radical Cation Complex in a Fluorinated Carbon Solvent
by Morimoto, Yuma and Shimaoka, Yuki and Ishimizu, Yuri and Fujii, Hiroshi and Itoh, Shinobu
Angewandte Chemie International Edition, ISSN 1433-7851, 08/2019, Volume 58, Issue 32, pp. 10863 - 10866
Oxido‐iron(IV) porphyrin π‐radical cation species are involved in a variety of heme‐containing enzymes and have characteristic oxidation states consisting of a... 
oxidation | porphyrinoids | iron | kinetics | reactive intermediates | Anions | Hydroxylation | Hydrogen bonds | Cyclohexane | Heme | Alkanes | Oxidation | Iron | Cations | Fluorination | Substrates
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