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catalysis (20) 20
chemistry, organic (16) 16
chemistry, multidisciplinary (14) 14
ruthenium (13) 13
carbonylation (12) 12
catalysis, phase‐transfer catalysis (11) 11
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activation (4) 4
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iridium (4) 4
lighting (4) 4
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nitrogen (4) 4
pyridine derivatives (4) 4
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alkynes (3) 3
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organic chemistry, review (3) 3
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air-conditioning, air-humidification, ventilation, use of aircurrents for screening (2) 2
aldehyde (2) 2
aldehyde derivatives (2) 2
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amination, n‐alkylation, n‐arylation (2) 2
animals (2) 2
applying liquids or other fluent materials to surfaces, in general (2) 2
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arylation (2) 2
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bond activation (2) 2
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Journal of the American Chemical Society, ISSN 0002-7863, 11/2014, Volume 136, Issue 44, pp. 15509 - 15512
Oxidative coupling between C­(sp2)–H bonds and C­(sp3)–H bonds is achieved by the Ni­(II)-catalyzed reaction of benzamides containing an 8-aminoquinoline... 
H BOND ACTIVATION | FUNCTIONALIZATION | CATALYZED ORTHO-ARYLATION | FLUOROALKYLATION | C-C | PERFLUOROALKYL IODIDES | CHEMISTRY, MULTIDISCIPLINARY | SIMPLE ARENES | ALKYL-HALIDES
Journal Article
Organic letters, ISSN 1523-7060, 02/2019, Volume 21, Issue 6, pp. 1760 - 1765
Redox isomerization reaction wherein N-alkylpropargylamines are converted into N-alkylideneallylamines in the presence of rhenium(I) complexes as catalysts is... 
Journal Article
Nature Communications, ISSN 2041-1723, 12/2017, Volume 8, Issue 1, pp. 1448 - 8
Hydroarylation is an environmentally attractive strategy which incorporates all of the atoms contained in the substrates into the desired products. Almost all... 
Deuterium | Rhodium | Amides | Hydrogen atoms | Selectivity | Carboxylic acids | Catalysis | Substrates
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2009, Volume 131, Issue 20, pp. 6898 - 6899
A new type of carbonylation of the ortho C−H bonds in aromatic amides 1, in which the pyridin-2-ylmethylamino moiety functions as a bidentate directing group,... 
ALCOHOLS | DIRECT ARYLATION | CARBON-MONOXIDE | AMINES | BENZENE-RING | COMPLEXES | ARYL | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2011, Volume 133, Issue 21, pp. 8070 - 8073
The regioselective carbonylation of unactivated C(sp3)–H bonds of aliphatic amides was achieved using Ru3(CO)12 as a catalyst. The presence of a... 
HYDROGEN | ACTIVATION | CATALYTIC DEHYDROGENATION | ARYLATION | REGIOSPECIFIC FUNCTIONALIZATION | RHODIUM COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | ALKYL-GROUPS | ALKANES | Aminopyridines | Ruthenium | Chemical properties | Nitrogen | Carbon compounds
Journal Article
Chemistry Letters, ISSN 0366-7022, 05/2020, Volume 49, Issue X
The silylimination of alkynes with hydrosilanes and n-octyl isocyanide, and the subsequent 1,4-hydrosilylation of the resulting β-silyl-α,β-unsaturated imines,... 
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 12/2017, Volume 82, Issue 24, pp. 13649 - 13655
The iridium-catalyzed C­(sp3)–H silylation of 2-alkylpyridines with hydrosilanes at the benzylic position to afford 2-(1-silylalkyl)­pyridines is described.... 
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 03/2017, Volume 2017, Issue 12, pp. 1662 - 1665
The iridium‐catalyzed reaction of imidazoles with formates in the presence of hydrosilanes as coreactants led to the production of... 
Hydrolysis | Silanes | C–H activation | Iridium | Nitrogen heterocycles | H BOND ACTIVATION | FUNCTIONALIZATION | 2 HETEROARENES | BIS-INDOLE ALKALOIDS | NICKEL CATALYSIS | COUPLING REACTION | BENZIMIDAZOLE | THIAZOLE ALKALOIDS | MEMBRANES | CHEMISTRY, ORGANIC | HYDROHETEROARYLATION | Nitrogen
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 04/2016, Volume 81, Issue 8, pp. 3161 - 3167
The combination of TpRh­(C2H4)2 (Tp = tris­(pyrazol-1-yl)­borate) and P­(2-furyl)3 catalyzes the reaction of tertiary alkyl-substituted alkynes with... 
Journal Article
Chemistry Letters, ISSN 0366-7022, 01/2018, Volume 47, Issue 3, p. 385
The regioselective silylation of the α-C(sp3)–H bond in the 2-alkyl group in 2-alkyl-1,3-azole derivatives with hydrosilanes, catalyzed by the combination of... 
Hydrogen bonds | Heterocyclic compounds | Iridium
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2007, Volume 129, Issue 45, pp. 13792 - 13793
Journal Article
Journal of Organic Chemistry, ISSN 0022-3263, 04/2016, Volume 81, Issue 8, p. 3161
Journal Article
ACS Catalysis, ISSN 2155-5435, 05/2017, Volume 7, Issue 5, pp. 3152 - 3156
The regioselective silylation of C­(sp3)–H bonds at the benzylic position in 4-alkylpyridines with hydrosilanes is described. The reaction proceeds in the... 
4-alkylpyridine | hydrosilane | silylation | C-H functionalization | iridium catalyst | PALLADIUM | TRANSITION-METAL-COMPLEXES | ARENES | CHEMISTRY, PHYSICAL | PYRIDINES | AROMATIC-SUBSTITUTION | C-H SILYLATION | DIHYDROGEN COMPLEXES | FUNCTIONALIZATION | DEHYDROGENATIVE SILYLATION | BOND ACTIVATION
Journal Article
Pure and Applied Chemistry, ISSN 0033-4545, 03/2014, Volume 86, Issue 3, pp. 283 - 289
The rhenium-catalyzed reaction of terminal alkynes with imines gives -alkylideneallylamine derivatives. A diphenylmethyl group as the substituent on the imine... 
imines | rhenium | vinylidene metals | allylamines | alkynes | ACTIVATION | PRECATALYSTS | C-H BOND | CARBONYL GROUPS | COMPLEXES | PROPARGYLAMINES | CHEMISTRY, MULTIDISCIPLINARY | ALLYLIC AMINES | VINYLIDENE | CYCLOISOMERIZATION | GOLD-CATALYZED SYNTHESIS | Carbon-carbon composites | Deuterium | Vinylidene | Imines | Aromatic compounds | Catalysis | Rhenium | Derivatives | Nitrogen | Alkynes | Carbon | Catalysts | Hydrogen | Terminals
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2012, Volume 134, Issue 21, pp. 8762 - 8765
The reaction of terminal alkynes with imines using ReBr(CO)5 as a catalyst results in the production of N-alkylideneallylamines and not the conventional... 
VINYLIDENES | SHIFT | C-H BOND | CARBONYL GROUPS | COMPLEXES | PROPARGYLAMINES | CYCLOISOMERIZATION | DERIVATIVES | CHEMISTRY, MULTIDISCIPLINARY | CYCLIZATION | Usage | Amines | Analysis | Chemical bonds | Chemical properties | Catalysis | Rhenium
Journal Article
Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry, ISSN 0037-9980, 07/2009, Volume 67, Issue 7, pp. 735 - 750
Journal Article
Chemistry Letters, ISSN 0366-7022, 12/2013, Volume 42, Issue 12, pp. 1565 - 1567
A mixed-valence Ru(II)–Ru(III) complex was used to catalyze the skeletal reorganization of 1,6-enynes, leading to the production of 1-vinylcyclopentene... 
Journal Article
Chemistry Letters, ISSN 0366-7022, 3/2018, Volume 47, Issue 3, pp. 385 - 388
The regioselective silylation of the α-C(sp3)–H bond in the 2-alkyl group in 2-alkyl-1,3-azole derivatives with hydrosilanes, catalyzed by the combination of... 
Catalytic C-H Activation | 2-Alkyl-1 | 3-Azoles | C-H silylation | Hydrosilane | C-H Silylation | HYDROSILANES | HYDROSILYLATION | ARENES | CHEMISTRY, MULTIDISCIPLINARY | FUNCTIONALIZATION | REDUCTION | SI-H | BOND ACTIVATION | TRIALKYLSILANES | 2-Alkyl-1,3-azoles | PINCER COMPLEX
Journal Article
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