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Dalton Transactions, ISSN 1477-9226, 5/2018, Volume 47, Issue 18, pp. 663 - 6631
The half-electron and CBC representations of the hydride-bridged complexes [M 2 Cp 2 (μ-H)(μ-PR 2 )(CO) 2 ] are analyzed. It is shown that the former gives a... 
Index Medicus
Journal Article
Dalton Transactions, ISSN 1477-9226, 2018, Volume 47, Issue 18, pp. 6630 - 6631
The half-electron and CBC representations of the hydride-bridged complexes [M2Cp2(μ-H)(μ-PR2)(CO)2] are analyzed. It is shown that the former gives a picture... 
Gold | Hydrides
Journal Article
Coordination Chemistry Reviews, ISSN 0010-8545, 01/2017, Volume 330, pp. 1 - 36
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2018, Volume 24, Issue 38, pp. 9504 - 9507
The high unsaturation of the title complex enabled it to react with a wide variety of molecules under mild conditions, whereby the agostic methyl ligand... 
metal-metal interactions | agostic complexes | alkyl ligands | molybdenum | phosphorus
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 34, pp. 13300 - 13303
Complex [W2Cp2(mu- l)(mu-PPh2)(NO)(2)] was prepared by reacting [W2Cp2(mu- I)(mu-PPh2)(CO)(2)] with NO at 233 K followed by decarbonylation in refluxing... 
REACTIVITY | TUNGSTEN | CRYSTAL | LIGAND | ELECTRONIC-STRUCTURE | HYDRIDE | CHEMISTRY, INORGANIC & NUCLEAR | Nitrosyls | Anions | Refluxing | Toluene | Acetonitrile | Clusters | Derivatives | Bonding
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 09/2017, Volume 56, Issue 18, pp. 11336 - 11351
A high-yield synthetic route for the preparation of the unsaturated anion [Mo2Cp2(μ-PtBu2)(μ-CO)2]- (2) was implemented, via two-electron reduction of the... 
Electron configuration | Research | Chemical properties | Coordination compounds | Molybdenum
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 10/2013, Volume 2013, Issue 28, pp. 4998 - 5008
Treatment of solutions of ammonia–borane (NH 3 · BH 3 , AB) with catalytic amounts (5 mol‐%) of the singly bonded dimers [M 2 Cp 2 (CO) 6 ] [M = Cr ( 1a ), Mo... 
Boranes | Amines | Group 6 elements | Dehydrogenation | Metal–metal bonds | Metal-metal bonds | ROOM-TEMPERATURE | BORON-NITROGEN BONDS | CATALYTIC DEHYDROCOUPLING/DEHYDROGENATION | HYDROGEN-STORAGE | SPENT FUEL | SIMPLE ROUTE | CHEMISTRY, INORGANIC & NUCLEAR | REDUCTION | TRANSITION-METAL | DIMETHYLAMINE-BORANE | LIGAND | Catalysts | Activation | Dimers | Catalysis | Bonding | Conversion | Adducts
Journal Article
Dalton Transactions, ISSN 1477-9226, 2016, Volume 45, Issue 12, pp. 5274 - 5289
The title compound reacted with p-tolylacetylene at room temperature to give the 32-electron sigma: pi-bound alkenyl complexes... 
DIIRON CENTERS | BU-T | CRYSTAL-STRUCTURE | BRIDGED DIMOLYBDENUM COMPLEXES | REACTIVITY | CHEMISTRY | BOND FORMATION | TUNGSTEN | ALKENYL | DERIVATIVES | CHEMISTRY, INORGANIC & NUCLEAR | Carbon-carbon composites | Tungsten | Unsaturated | Ligands | Joining | Hydrides | Isomers | Alkynes
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 10/2015, Volume 54, Issue 20, pp. 9810 - 9820
The title phosphinidene complex could be sequentially protonated with HBF4 center dot OEt2 or [H(OEt2)(2)](BAr'(4)) to give the phosphido-bridged derivatives... 
MULTICOMPONENT REACTIONS | TOTAL ENERGIES | LIGANDS | HETEROCYCLES | P-C | BONDS | SET MODEL CHEMISTRY | REACTIVITY | PHOSPHORUS CHEMISTRY | NONCOORDINATING ANIONS | CHEMISTRY, INORGANIC & NUCLEAR | Electron configuration | Research | Chemical properties | Molybdenum
Journal Article
Inorganic Chemistry, ISSN 0020-1669, 11/2015, Volume 54, Issue 22, pp. 10536 - 10538
Complex [Mo2Cp2(mu-PCy2)(mu-NO)-(NO)(2)] (1) was prepared by reacting [Mo2Cp2(mu-H)(mu-PCy2)(CO)(4)] with 2 equiv of [NO]BF4 and then treating the resulting... 
COMPLEXES | REACTIVITY | CHEMISTRY | HNO | IRON | X=1 | HYDRIDE | CHEMISTRY, INORGANIC & NUCLEAR | Degradation | Nitrosyls | Bridging | Ligands | Cleavage | Nanostructure | Derivatives | Bonding
Journal Article
Journal of Organometallic Chemistry, ISSN 0022-328X, 08/2019, Volume 893, pp. 61 - 71
The heterometallic hydride [MoWCp ( -H)( -PCy )(CO) ] was prepared in 30% yield through reaction of an equimolar mixture of [Mo Cp (CO) ] and [W Cp (CO) ] with... 
Agostic complexes | Carbyne complexes | Carbonylate complexes | Hydride complexes | Metal−metal interactions | Heterometallic complexes
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 37, pp. 4700 - 4703
Carbodiimides catalyse the reduction of CO2 with H-BBN or BH3 center dot SMe2 to give either mixtures of CH2(OBBN)(2) and CH3OBBN or (MeOBO)(3) and B(OMe)(3)... 
TRANSFORMATION | METHANOL | HYDROBORATION | ACTIVATION | HYDROGENATION | METAL-FREE REDUCTION | GUANIDINES | CHEMISTRY | FRUSTRATED LEWIS PAIRS | CARBON-DIOXIDE | CHEMISTRY, MULTIDISCIPLINARY | Chemical reduction | Boranes | Catalysis | Carbodiimides | Carbon dioxide
Journal Article