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chemistry, multidisciplinary (7) 7
alkanes (6) 6
catalysis (6) 6
chemistry (6) 6
copper (6) 6
carbenes (5) 5
silver (5) 5
chemical or physical processes, e.g. catalysis or colloidchemistry (4) 4
chemistry, physical (4) 4
complexes (4) 4
hydrogen (4) 4
insertion (4) 4
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methane (4) 4
performing operations (4) 4
physical or chemical processes or apparatus in general (4) 4
their relevant apparatus (4) 4
transporting (4) 4
acyclic, carbocyclic or heterocyclic compounds containingelements other than carbon, hydrogen, halogen, oxygen, nitrogen,sulfur, selenium or tellurium (3) 3
alkane (3) 3
analysis (3) 3
bonds (3) 3
c-h activation (3) 3
catalysis, phase‐transfer catalysis (3) 3
catalytic functionalization (3) 3
cyclopropanation (3) 3
esters (3) 3
hydrogen bonding (3) 3
hydrogen bonds (3) 3
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measurement (3) 3
nucleophiles (3) 3
organic chemistry (3) 3
rhodium (3) 3
activation (2) 2
amidation (2) 2
amination (2) 2
amination, n‐alkylation, n‐arylation (2) 2
avena sativa (2) 2
aziridination (2) 2
bipolaris sp (2) 2
bond functionalization (2) 2
bonding (2) 2
bovinos (2) 2
c-h-funktionalisierung (2) 2
cancer (2) 2
carbene insertion (2) 2
carbene transfer (2) 2
care and treatment (2) 2
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chemistry, organic (2) 2
chemotherapy (2) 2
claviceps purpurea (2) 2
cross-couplings (2) 2
crystal-structure (2) 2
c−h bond functionalization (2) 2
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electrophilicity (2) 2
elektrophilie (2) 2
fungo (2) 2
hematology, oncology and palliative medicine (2) 2
humans (2) 2
metal carbene complexes (2) 2
metall-carben-komplex (2) 2
nucleophilicity (2) 2
nucleophilie (2) 2
oncology (2) 2
puccinia coronata (2) 2
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reagents (2) 2
ring opening (2) 2
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substrates (2) 2
surface active agents (2) 2
system (2) 2
toxicoses (2) 2
1.2-dichloro-4,5-dinitrobenzene (1) 1
[chim.coor]chemical sciences/coordination chemistry (1) 1
abwasser (1) 1
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Chemistry – A European Journal, ISSN 0947-6539, 06/2019, Volume 25, Issue 34, pp. 8013 - 8017
Vinyl epoxides and styrene oxide can react with diborylmethide lithium salts through an exclusive SN2 borylmethylation/ring opening in a regio‐ and... 
SN2 mechanism | homoallylboronates | geminal diborylalkanes | diboronates | lithium salts | DEPROTONATION | INSERTION | GEM-SILYLBORYLATION | CARBANIONS | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | ALKYL-HALIDES | KETONES | S(N)2 mechanism | ESTERS | DIBORYLALKANES | ACCESS | Stereoselectivity | Salts | Styrene | Lithium | Epoxides | Ring opening | Substrates | Diols
Journal Article
ORGANIC & BIOMOLECULAR CHEMISTRY, ISSN 1477-0520, 7/2019, Volume 17, Issue 26, pp. 6317 - 6325
Journal Article
Organic Letters, ISSN 1523-7060, 11/2019
Journal Article
ISSN 1359-7345, 9/2019, Volume 55, Issue 75, pp. 11243 - 11246
The functionalization of methane in water as the reaction medium (where it is nearly insoluble) at room temperature using micellar catalysis is described.... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2018, Volume 57, Issue 42, pp. 13848 - 13852
Journal Article
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2019, Volume 55, Issue 75, pp. 11243 - 11246
The functionalization of methane in water as the reaction medium (where it is nearly insoluble) at room temperature using micellar catalysis is described.... 
Methane | Ethyl propionate | Materials information | Nuclear magnetic resonance--NMR | Concentrators | Reagents | Catalysis
Journal Article
Catalysis Communications, ISSN 1566-7367, 10/2013, Volume 40, pp. 63 - 65
Copper species highly dispersed on suitable inert oxide supports catalyze the amidation of the α-C H bond of cyclic ethers using a commercial, environmentally... 
Heterogeneous catalysis | Nitrene | Amination | Copper | C[sbnd]H activation | CH activation | Catalysts
Journal Article
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 09/2019, Volume 55, Issue 75, pp. 11243 - 11246
The functionalization of methane in water as the reaction medium (where it is nearly insoluble) at room temperature using micellar catalysis is described.... 
CROSS-COUPLINGS | CHEMISTRY, MULTIDISCIPLINARY | BONDS | ALKANES
Journal Article
ChemCatChem, ISSN 1867-3880, 10/2015, Volume 7, Issue 20, pp. 3254 - 3260
The functionalization of the primary sites of alkanes is one of the more challenging areas in catalysis. In this context, a novel effect has been discovered... 
copper | silver | C−H activation | carbene transfer | supercritical fluids | C-H activation | CATALYTIC FUNCTIONALIZATION | MOLECULAR-ORBITAL METHODS | CRYSTAL-STRUCTURE | COMPLEXES | CYCLOPROPANATION | CHEMISTRY, PHYSICAL | METHANE | CARBENE INSERTION | BASIS-SET | Hydrogen | Carbon dioxide | Catalysis
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2018, Volume 57, Issue 42, pp. 13693 - 13693
The relative reactivity of a series of alkane C−H bonds towards silver, copper, and rhodium carbene complexes acting as electrophiles has been studied. In... 
nucleophilicity | metal carbene complexes | alkanes | C−H bond functionalization | electrophilicity
Journal Article
ChemCatChem, ISSN 1867-3880, 08/2014, Volume 6, Issue 8, pp. 2206 - 2210
The reaction of esters with ethyl diazoacetate catalyzed by the complex [F27–Tp 4 Bo,3 CF 2CF 3Ag(acetone)] generates α‐(acyloxy)acetates in moderate to high... 
carbenes | silver | zwitterions | diazo compounds | ester functionalization | REARRANGEMENT | SYSTEM | INSERTION | CHEMISTRY, PHYSICAL | CARBON-HYDROGEN BONDS | ALKANES | Diazo compounds | Esters | Surface active agents | Acetates
Journal Article
ACS Catalysis, ISSN 2155-5435, 06/2015, Volume 5, Issue 6, pp. 3726 - 3730
The copper complex Tp(CF3)2,BrCu­(NCMe) (1, Tp(CF3)2,Br = hydrotris­((3,5-bis­(trifluoromethyl)-4-bromo)-pyrazol-1-yl)­borate) catalyzes the insertion of the... 
methane activation | copper catalysis | supercritical carbon dioxide | carbene insertion | C-H activation | CATALYTIC FUNCTIONALIZATION | OXIDATION | ACTIVATION | HYDROCARBONS | COMPLEXES | CHEMISTRY, PHYSICAL | DIAZO-COMPOUNDS | PROPANE | LIGHT ALKANES | CHEMISTRY
Journal Article
ACS Catalysis, ISSN 2155-5435, 05/2017, Volume 7, Issue 5, pp. 3707 - 3711
A series of alkanes CnH2n+2 have been functionalized in water as the reaction medium, using a silver-based catalyst, upon the insertion of carbene (CHCO2Et... 
catalysis in water | copper and silver catalysts | C-H activation | Alkane functionalization | carbene transfer | ROOM-TEMPERATURE | INSERTION | AQUEOUS-MEDIA | ORGANIC-REACTIONS | COMPLEXES | BOND FUNCTIONALIZATION | CHEMISTRY, PHYSICAL | ETHYL DIAZOACETATE | CROSS-COUPLINGS | ASYMMETRIC CYCLOPROPANATION | CARBENOID TRANSFER
Journal Article
Angewandte Chemie, ISSN 0044-8249, 10/2018, Volume 130, Issue 42, pp. 14044 - 14048
We report quantitative measurements of the relative reactivities of a series of C−H bonds of gaseous or liquid CnH2n+2 alkanes (n=1–8, 29 different C−H bonds)... 
C-H-Funktionalisierung | Metall-Carben-Komplex | Nucleophilie | Alkane | Elektrophilie | Measurement | Methane | Silver | Hydrogen | Analysis | Bonds | Reactivity | Rhodium | Hydrogen bonds | Alkanes | Nucleophiles | Carbenes | Bonding | Hydrogen bonding
Journal Article
Angewandte Chemie, ISSN 0044-8249, 10/2018, Volume 130, Issue 42, pp. 13885 - 13885
Die relative Reaktivität der C‐H‐Bindungen von Alkanen als Nucleophile gegenüber mehreren Silber‐, Kupfer‐ und Rhodium‐Carben‐Komplexen als starke Elektrophile... 
C-H-Funktionalisierung | Metall-Carben-Komplex | Nucleophilie | Alkane | Elektrophilie | Measurement | Hydrogen | Alkanes | Rhodium | Hydrogen bonds | Nucleophiles | Hydrogen bonding
Journal Article
Applied Organometallic Chemistry, ISSN 0268-2605, 07/2014, Volume 28, Issue 7, pp. 512 - 516
Journal Article
Applied Organometallic Chemistry, ISSN 0268-2605, 07/2014, Volume 28, Issue 7, pp. 512 - 516
Copper complexes with chiral iminopyridine ligands were screened for their catalytic efficiency in carbene (cyclopropanation) and nitrene transfer reactions... 
copper | iminopyridine ligands | amination | cyclopropanation | aziridination | MILD | LIGANDS | AMIDATION | TERMINAL ALKYNES | CHEMISTRY, APPLIED | CONJUGATE ADDITION | CHEMISTRY, INORGANIC & NUCLEAR | Catalysts | Metalorganic compounds | Ligands | Catalysis | Copper | Carbenes | Alkynes
Journal Article
CERN IdeaSquare Journal of Experimental Innovation, 06/2019, Volume 3, Issue 1, pp. 33 - 39
n past decades the usage of plastic has seen a tremendous increment. This raise is mainly caused by industrial development and by the spread of this material... 
Plastic recycling | smart-bin | recycling experience | franchising recycling system
Journal Article
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