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Organic Letters, ISSN 1523-7060, 07/2011, Volume 13, Issue 13, pp. 3450 - 3453
Using a readily available secondary aminoalkyne as starting material, a powerful strategy was discovered to prepare precursors of biologically important... 
ROUTE | NITROGEN-HETEROCYCLES | TERTIARY-AMINES | CHEMISTRY, ORGANIC | CATALYZED OXIDATIVE CYANATION | HIGHLY EFFICIENT | CYCLIZATION | Amino Acids, Cyclic - chemistry | Heterocyclic Compounds - chemical synthesis | Molecular Structure | Amination | Cyanides - chemistry | Fluorine Compounds - chemistry
Journal Article
Journal of Fluorine Chemistry, ISSN 0022-1139, 03/2018, Volume 207, p. 45
Catalytic hydrogenation is one of the most powerful transformations available in synthetic chemistry; there have been three Nobel Laureates rewarded for their... 
Studies | Chemistry | Transformation | Fluorine | Fluorides | Catalysis | Enantiomers | Hydrogenation | Substrates
Journal Article
Green Chemistry, ISSN 1463-9262, 01/2019, Volume 21, Issue 9, pp. 2224 - 2228
A solid anhydrous hydrogen fluoride equivalent was prepared by mixing HF gas with an inexpensive anion exchange resin (A26-HF, HF content 30% wt/wt). This... 
Fluoroamines | Alkenes | Column packings | Selectivity | Ion exchange resins | Fluorides | Ion exchanging | Anion exchange | Fluoride | Hydrofluorination | Reagents | Anion exchanging | Hydrogen fluoride | Ion exchange | Fluorination | Hydrogen ion concentration
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2017, Volume 23, Issue 71, p. n/a
One of the most important interactions in Nature, that is, hydrogen bonding, can be utilized for regulating nucleophilic fluorination using two readily... 
fluorination | hydrogen bonding | fluorides | alkali metals | nucleophiles | Hydrogen | Fluorides | Fluorine | Alkali metals | Metals | Hydrogen bonding | Fluoride | Metal fluorides | Hafnium | Bonding strength | Chemical bonds | Hydrogen fluoride | Fluorination | Basicity | Bonding | Hydrogen ion concentration
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2017, Volume 23, Issue 71, pp. 17850 - 17861
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 03/2014, Volume 20, Issue 11, pp. 3113 - 3119
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2014, Volume 53, Issue 17, pp. 4456 - 4459
Gold catalysts capable of promoting reactions at low‐level loadings under mild conditions are the exception rather than the norm. We examined reactions where... 
phosphine ligand | biaryl | gold catalysis | 1,6-ENYNES | C BOND FORMATION | COMPLEXES | HYDROAMINATION | ALKYNES | CHEMISTRY, MULTIDISCIPLINARY | HYDRATION | LIGANDS | CARBENES | CYCLOISOMERIZATION | Ligands | Gold | Catalysts | Cationic | Isomerization | Electron density | Phosphines | Constraining | Alkynes
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 04/2016, Volume 358, Issue 9, pp. 1478 - 1481
In the gold(I) (e. g. L‐Au‐OTf) catalyzed hydration of alkynes, the steric hindrance of ligands has a significant influence on the kinetics of the reaction,... 
electronic effects | sterically hindered phosphine ligands | low loading | gold catalyzed hydration | ROOM-TEMPERATURE | ANTI-MARKOVNIKOV HYDRATION | ACETYLENIC-COMPOUNDS | ACID | COMPLEXES | REACTIVITY | CHEMISTRY, ORGANIC | TERMINAL ALKYNES | KETONES | CHEMISTRY, APPLIED | CHLORIDE | WATER | Gold | Hydration | Reaction kinetics | Ligands | Steric hindrance | Substrates | Alkynes | Synthesis | Chemical reactions | Catalysis | Phosphines
Journal Article
European Journal of Organic Chemistry, ISSN 1434-193X, 09/2018, Volume 2018, Issue 34, pp. 4705 - 4708
We report a novel method for the chlorothiolation of alkenes using HCl and sulfoxides to achieve the 1,2‐difunctionalization of unactivated alkenes. The... 
Regioselective | Sulfoxides | Chlorothiolation | Alkenes | Difunctionalization | REAGENT | INTRAMOLECULAR CARBOSULFENYLATION | DMSO | CHEMISTRY, ORGANIC | ALKYNES | COUPLING REACTION | BETA-CHLOROALKYL SULFIDES | OLEFINS | DIMETHYL-SULFOXIDE | METHYL SULFIDES | SULFENYL CHLORIDES | Olefins | Organosulfur compounds | Alkene
Journal Article
Green Chemistry, ISSN 1463-9262, 01/2018, Volume 20, Issue 3, pp. 680 - 684
A combined acid HCl/DMPU-acetic acid catalytic system was used in the hydrochlorination of a wide range of unactivated alkenes. This hydrochlorination strategy... 
Hazardous wastes | Alkenes | Acids | Regioselectivity | Metals | Reagents | Toxic wastes | Catalysis | Acetic acid | Hydrochlorination
Journal Article
Advanced Synthesis & Catalysis, ISSN 1615-4150, 10/2018, Volume 360, Issue 19, pp. 3667 - 3671
Diverse alkenylboronic acids react smoothly with various sp3‐carbon electrophiles such as unactivated alkyl triflates in the presence of mild bases such as... 
cross-coupling | alkenylboronic acids | sp3-carbon electrophiles | Transition metal-free | carbon electrophiles | Transition metal compounds | Substitution reactions | Potassium phosphates | Carbon | Functional groups
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2018, Volume 57, Issue 11, pp. 2924 - 2928
Journal Article
Accounts of chemical research, ISSN 0001-4842, 05/2019, Volume 52, Issue 5, p. 1275
Homogeneous gold catalysis is regarded as a landmark addition to the field of organic synthesis. It is the most effective way to activate alkynes for the... 
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 09/2017, Volume 23, Issue 52, pp. 12739 - 12743
HBr and DMPU (1,3‐dimethyl‐3,4,5,6‐tetrahydro‐2‐pyrimidinone) form a room‐temperature‐stable complex that provides a mild, effective, and selective... 
hydrohalogenation | hydrogen | halides | bromide | organic halide | CROSS-METATHESIS | REAGENTS | VINYL CATIONS | ACETIC-ACID | CHEMISTRY, MULTIDISCIPLINARY | VISIBLE-LIGHT | ALKENES | ALKYL CHLORIDES | COUPLING REACTIONS | ANTI-MARKOVNIKOV HYDROBROMINATION | CARBOXYLIC-ACIDS | Hydrogen | Halides | Alkenes | Bromination | Reagents | Alkynes | Hydrogen bromide
Journal Article