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Angewandte Chemie (International ed.), ISSN 1433-7851, 2013, Volume 52, Issue 14, pp. 3963 - 3966
A palladium‐catalyzed insertion copolymerization of vinyl chloride (VC) and ethylene gave chlorinated polyethylene with CH3CHCl(CH2)n units (see scheme; C... 
polymerization | palladium | insertion | homogeneous catalysis | vinyl compounds | POLYOLEFINS | MONOMERS | LINEAR POLYETHYLENE | ACRYLONITRILE | COMPLEXES | PALLADIUM-CATALYZED COPOLYMERIZATION | ACRYLATE | CHEMISTRY, MULTIDISCIPLINARY | FLUORIDE | ETHYLENE | MECHANISTIC INSIGHTS | Polymerization | Palladium | Vinyl chloride | Analysis | Polyethylenes | Chlorination | Ethylene | Insertion | Copolymerization | Hydrides
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 05/2017, Volume 139, Issue 20, pp. 6823 - 6826
PhS- and PhNH-functionalized dienes are copolymerized efficiently with butadiene to stereoregular copolymers by [(mesitylene)­Ni­(allyl)]­[BArF 4] (Ni-1).... 
POLAR | ETHYLENE | VINYL MONOMERS | MECHANISTIC INSIGHTS | COMPLEXES | PROPYLENE | ACRYLATE | LIGAND | COPOLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | Polymerization | Research | Chemical properties | Catalysis | Alkadienes
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2015, Volume 137, Issue 46, pp. 14819 - 14828
To date, an inconclusive and partially contradictive picture exists on the behavior of neutral Ni­(II) insertion polymerization catalysts toward methyl... 
CHELATE LIGANDS | MECHANISM | (METH)ACRYLATES | COMPLEXES | PALLADIUM-CATALYZED COPOLYMERIZATION | POLAR VINYL MONOMERS | CARBON BOND-CLEAVAGE | TRANSITION-METALS | CHEMISTRY, MULTIDISCIPLINARY | POLYETHYLENE | DEACTIVATION | Polymerization | Research | Chemical properties | Methyl methacrylate | Ethylene | Chemical Sciences
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2014, Volume 136, Issue 5, pp. 2078 - 2085
The neutral κ2 N,O-salicylaldiminato Ni(II) complexes [κ2 N,O-{(2,6-(3′,5′-R2C6H3)2C6H3-NC(H)-(3,5-I2-2-O-C6H2)}]NiCH3(pyridine)] (1a-pyr, R = Me; 1b-pyr, R =... 
TANDEM CATALYSIS | POLYETHYLENES | MONOMERS | CATALYTIC POLYMERIZATION | REMOTE SUBSTITUENTS | COMPLEXES | RUTHENIUM | COPOLYMERS | CHEMISTRY, MULTIDISCIPLINARY | LINEAR ALPHA-OLEFINS | CHAIN TRANSFER | Oligomers | Research | Hydrogenation | Analysis | Ethylene
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2009, Volume 131, Issue 2, pp. 422 - 423
Multiple insertions of acrylate in copolymerization with ethylene, and an insertion homo-oligomerization of methyl acrylate were observed for the first time.... 
ALTERNATING COPOLYMERIZATION | ETHYLENE | VINYL MONOMERS | LIGANDS | CARBON-MONOXIDE | COMPLEXES | PALLADIUM-CATALYZED COPOLYMERIZATION | ETHENE | BOND | METHYL ACRYLATE | CHEMISTRY, MULTIDISCIPLINARY | Chemical properties | Catalysis | Analysis | Acrylic resins
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 01/2018, Volume 140, Issue 4, pp. 1305 - 1312
A combined theoretical and experimental study shows how weak attractive interactions of a neighboring group can strongly promote chain walking and chain... 
ETHYLENE | INSERTION POLYMERIZATION | REMOTE SUBSTITUENTS | COMPLEXES | ISOMERIZATION | OLEFINS | COPOLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | MICROSTRUCTURE | POLYMERIZATION CATALYSIS | Salicylic acid | Chemical properties
Journal Article
Chemistry : a European journal, ISSN 0947-6539, 2013, Volume 19, Issue 50, pp. 17131 - 17140
The synthesis of unsymmetrical diphosphine ligands (3 a–g) with an o‐tolyl backbone and tert‐butyl, adamantyl, cyclohexyl and isopropyl substituents on the... 
phosphines | palladium | renewable resources | carbonylation | isomerisation | POLYESTERS | MONOMERS | PLANT OILS | COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | FATTY-ACID ESTERS | CARBON-MONOXIDE | PHOSPHINE-LIGANDS | BITE ANGLE | ETHENE | METHOXYCARBONYLATION | Telomerase | Isomerization | Palladium | Productivity | Catalysts | Diesters | Formations | Hydrides | Selectivity | Catalysis | Conversion
Journal Article
Journal Article
Macromolecules, ISSN 0024-9297, 11/2017, Volume 50, Issue 21, pp. 8464 - 8468
Neodymium based Ziegler–Natta systems catalyze the 1,4-cis selective copolymerization of isoprene and 1,3-butadiene with different R2N- and RS-functionalized... 
POLYMERS | POLAR | POLYMER SCIENCE | FREE-RADICAL POLYMERIZATION | DIENE-BASED MATERIALS | STYRENE | METHYLALUMINOXANE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 11/2010, Volume 132, Issue 46, pp. 16623 - 16630
Polymerization of ethylene by complexes [{(P^O)PdMe(L)}] (P^O = κ2-(P,O)-2-(2-MeOC6H4)2PC6H4SO3)) affords homopolyethylene free of any methyl methacrylate... 
ALTERNATING COPOLYMERIZATION | TRANSITION-METAL COMPLEXES | VINYL MONOMERS | LIGANDS | PALLADIUM-CATALYZED COPOLYMERIZATION | OLEFIN POLYMERIZATION | ETHENE | ETHYLENE POLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | ALKYL COMPLEXES | POLYETHYLENE | Thermal properties | Polymethylmethacrylate | Thiols | Chemical properties | Structure | Ethylene
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 03/2010, Volume 132, Issue 12, pp. 4418 - 4426
Complexes [{(P∧O)PdMe} n ] (1 n ; P∧O = κ2-P,O-Ar2 PC6H4SO2 O with Ar = 2-MeOC6H4) are a single-component precursor of the (P∧O)PdMe fragment devoid of... 
POLAR MONOMERS | ALTERNATING COPOLYMERIZATION | ALPHA-OLEFINS | TO-TAIL DIMERIZATION | VINYL MONOMERS | UNUSUAL FUNCTIONALITY | PALLADIUM-CATALYZED COPOLYMERIZATION | METHYL ACRYLATE | CHEMISTRY, MULTIDISCIPLINARY | ALKYL COMPLEXES | NONALTERNATING COPOLYMERIZATION | Density functionals | Acrylates | Usage | Chemical properties | Chelates
Journal Article
Macromolecules, ISSN 0024-9297, 12/2016, Volume 49, Issue 23, pp. 8825 - 8837
High molecular weight linear polyethylene, in the form of 7 nm thin single-lamella nanocrystals with a diameter of up to 200 nm, is generated via aqueous... 
POLYMERS | DISPERSIONS | POLYMER SCIENCE | POLYETHYLENE NANOPARTICLES | COMPLEXES | CRYSTALS | ETHYLENE POLYMERIZATION | CATALYSTS | N-ALKANES | WATER | DEACTIVATION
Journal Article
ACS Macro Letters, ISSN 2161-1653, 06/2016, Volume 5, Issue 6, pp. 777 - 780
[(Mesitylene)­nickel­(allyl)+]­[BArF 4 –] (Ni-1) catalyzes the 1,4-cis selective copolymerization of isoprene and 1,3-butadiene with 15 (RO)3Si-, R2N-, RSO2-,... 
POLYMERS | POLAR | POLYMER SCIENCE | COMPLEXES | FREE-RADICAL POLYMERIZATION | DIENE-BASED MATERIALS | STYRENE
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2006, Volume 128, Issue 24, pp. 7708 - 7709
Water-soluble single-component (κ2-N,O)-salicylaldiminato nickel−methyl complexes 1−4-L (L = TPPTS, TPPDS, H2N-PEG-OMe) allow for the catalytic polymerization... 
CRYSTALLIZATION | ALPHA-OLEFINS | DISPERSIONS | ROUTE | MELT | NICKEL | CATALYTIC POLYMERIZATION | EMULSION | COPOLYMERIZATION | CHEMISTRY, MULTIDISCIPLINARY | POLYETHYLENE
Journal Article
Advanced synthesis & catalysis, ISSN 1615-4150, 2007, Volume 349, Issue 14-15, pp. 2307 - 2316
A series of (κ2‐N,O)salicylaldiminato nickel methyl pyridine complexes 8a–h‐pyr bearing 2,6‐di‐(4‐R′‐phenyl)phenyl groups on the imine nitrogen and varying in... 
nickel | polymerization | catalyst design | electronic structure | Polymerization | Electronic structure | Nickel | Catalyst design | ALPHA-OLEFINS | COMPLEXES | OLEFIN POLYMERIZATION | CHEMISTRY, ORGANIC | STRUCTURAL-CHARACTERIZATION | IRON | ETHYLENE POLYMERIZATION | LIGANDS | METAL CATALYSTS | CHEMISTRY, APPLIED | OLIGOMERIZATION
Journal Article
Organometallics, ISSN 0276-7333, 04/2007, Volume 26, Issue 9, pp. 2348 - 2362
A series of (κ2-N,O)-salicylaldiminato Ni(II)−methyl pyridine complexes 7-pyr and 8-pyr derived from 3,5-diiodosalicyaldehyde (3a) and... 
Journal Article
Organometallics, ISSN 0276-7333, 12/2012, Volume 31, Issue 23, pp. 8388 - 8406
13C-Labeled ethylene polymerization (pre)­catalysts [κ2-(anisyl)2 P,O]­Pd­(13CH3)­(L) (1- 13 CH 3 -L) (L = pyridine, dmso) based on di­(2-anisyl)­phosphine... 
INSERTION POLYMERIZATION | VINYL MONOMERS | CARBON-MONOXIDE | MECHANISTIC INSIGHTS | SELECTIVE REDUCTIONS | OXIDATIVE-ADDITION | CHEMISTRY, ORGANIC | DENSITY-FUNCTIONAL THEORY | X-RAY CRYSTAL | BOND-CLEAVAGE | ALKYL-HALIDES | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article