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1. Full Text Dehydrogenation of n‑Alkanes by Solid-Phase Molecular Pincer-Iridium Catalysts. High Yields of α‑Olefin Product
by Kumar, Akshai and Zhou, Tian and Emge, Thomas J and Mironov, Oleg and Saxton, Robert J and Krogh-Jespersen, Karsten and Goldman, Alan S
Journal of the American Chemical Society, ISSN 0002-7863, 1900, Volume 137, Issue 31, pp. 9894 - 9911
We report the transfer-dehydrogenation of gas-phase alkanes catalyzed by solid-phase, molecular, pincer-ligated iridium catalysts, using ethylene or propene as... 
H BOND ACTIVATION | ORBITAL METHODS | ALKENE ISOMERIZATION | ETHANE DEHYDROGENATION | CATALYTIC DEHYDROGENATION | EFFECTIVE CORE POTENTIALS | COMPLEXES | BASIS-SETS | ACTIVE CATALYSTS | DFT CALCULATIONS | CHEMISTRY, MULTIDISCIPLINARY | Dehydrogenation | Olefins | Alkanes | Chemical properties | Research | Catalysis | Iridium
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2. Full Text Discovery of betrixaban (PRT054021), N-(5-chloropyridin-2-yl)-2-(4-( N, N-dimethylcarbamimidoyl)benzamido)-5-methoxybenzamide, a highly potent, selective, and orally efficacious factor Xa inhibitor
by Zhang, Penglie and Huang, Wenrong and Wang, Lingyan and Bao, Liang and Jia, Zhaozhong J and Bauer, Shawn M and Goldman, Erick A and Probst, Gary D and Song, Yonghong and Su, Ting and Fan, Jingmei and Wu, Yanhong and Li, Wenhao and Woolfrey, John and Sinha, Uma and Wong, Paul W and Edwards, Susan T and Arfsten, Ann E and Clizbe, Lane A and Kanter, James and Pandey, Anjali and Park, Gary and Hutchaleelaha, Athiwat and Lambing, Joseph L and Hollenbach, Stanley J and Scarborough, Robert M and Zhu, Bing-Yan
Bioorganic & Medicinal Chemistry Letters, ISSN 0960-894X, 2009, Volume 19, Issue 8, pp. 2179 - 2185
Systematic SAR studies of in vitro factor Xa inhibitory activity around compound 1 were performed by modifying each of the three phenyl rings. A class of... 
IN-VITRO | CHEMISTRY, MEDICINAL | VENOUS THROMBOEMBOLISM | TORSADE-DE-POINTES | THROMBOSIS | DRUG DEVELOPMENT | PREVENTION | CHEMISTRY, ORGANIC | ANTITHROMBOTIC AGENT | QT INTERVAL PROLONGATION | THIOPHENE-ANTHRANILAMIDES | HERG CHANNELS | Catalytic Domain - drug effects | Cell Line | Rabbits | Pyridines - administration & dosage | Anticoagulants - administration & dosage | Factor Xa Inhibitors | Administration, Oral | Humans | Pyridines - chemical synthesis | Macaca fascicularis | Rats | Drug Discovery - methods | ERG1 Potassium Channel | Ether-A-Go-Go Potassium Channels - genetics | Benzamides - chemical synthesis | Factor Xa - metabolism | Anticoagulants - chemical synthesis | Dose-Response Relationship, Drug | Benzamides - administration & dosage | Animals | Anticoagulants - pharmacology | Dogs | Benzamides - pharmacology | Pyridines - pharmacology
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3. Full Text Polarization dependence of n = 2 positronium transition rates to Stark-split n = 30 levels via crossed-beam spectroscopy
by Jones, A.C.L and Hisakado, T.H and Goldman, H.J and Tom, H.W.K and Mills, A.P
Journal of Physics B: Atomic, Molecular and Optical Physics, ISSN 0953-4075, 02/2016, Volume 49, Issue 6, pp. 64006 - 64012
We produce Rydberg Ps by a two-step laser excitation from 1(3)S -> 2(3)P and from 2(3)P to states of principal quantum level n = 30 +/- 1 that are Stark split... 
positronium | rydberg | tof spectroscopy | stark effect | RYDBERG CONSTANT | HYDROGEN | STATES | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | OPTICS | Spectroscopy | Polarization | Splitting | Lasers | Excitation | Light levels | Electric fields | Walls
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4. Full Text Kinetics of N‑Nitrosopiperazine Formation from Nitrite and Piperazine in CO2 Capture
by Goldman, Mark J and Fine, Nathan A and Rochelle, Gary T
Environmental Science & Technology, ISSN 0013-936X, 04/2013, Volume 47, Issue 7, pp. 3528 - 3534
Piperazine (PZ) is an efficient amine for carbon capture systems, but it can form N-nitrosopiperazine (MNPZ), a carcinogen, from nitrogen oxides (NO x ) in... 
NITROSODIMETHYLAMINE FORMATION | ENVIRONMENTAL SCIENCES | ENGINEERING, ENVIRONMENTAL | AMINES | NITROSATION | PRODUCT | NITROSAMINE | CARBON-DIOXIDE | NDMA | Carbon Dioxide - chemistry | Temperature | Models, Chemical | Nitrosamines - chemistry | Piperazines - chemistry | Catalysis | Kinetics | Nitrites - chemistry | Nitrosation | Carbamates - chemistry | Hydrogen-Ion Concentration | Index Medicus
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5. Full Text Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes
by Ahuja, Ritu and Punji, Benudhar and Findlater, Michael and Supplee, Carolyn and Schinski, William and Brookhart, Maurice and Goldman, Alan S
Nature Chemistry, ISSN 1755-4330, 02/2011, Volume 3, Issue 2, pp. 167 - 171
Aromatic hydrocarbons are among the most important building blocks in the chemical industry. Benzene, toluene and xylenes are obtained from the high... 
DEHYDROCYCLIZATION | DEHYDROGENATION | ALKYLATION | OLEFINS | FISCHER-TROPSCH PROCESS | AROMATIZATION | CHEMISTRY, MULTIDISCIPLINARY | HYDROARYLATION | ZEOLITE | METATHESIS | HEXANE | Hydrocarbons, Aromatic - chemistry | Octanes - chemistry | Ligands | Hexanes - chemistry | Molecular Structure | Catalysis | Hydrocarbons, Aromatic - chemical synthesis | Alkanes - chemistry | Hydrogen - chemistry | Iridium - chemistry
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6. Full Text Bi-enhanced N incorporation in GaAsNBi alloys
by Occena, J and Jen, T and Rizzi, E. E and Johnson, T. M and Horwath, J and Wang, Y. Q and Goldman, R. S and Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Applied Physics Letters, ISSN 0003-6951, 06/2017, Volume 110, Issue 24, p. 242102
We have examined the influence of bismuth (Bi) and nitrogen (N) fluxes on N and Bi incorporation during molecular-beam epitaxy of GaAs1-x-yNxBiy alloys. The... 
PHYSICS, APPLIED | MOLECULAR-BEAM EPITAXY | GROWTH | BISMUTH | GAAS1-XNX | NITROGEN INCORPORATION | LAYERS | Material Science | MATERIALS SCIENCE
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7. Full Text Exploring Site-Specific N‑Glycosylation Microheterogeneity of Haptoglobin Using Glycopeptide CID Tandem Mass Spectra and Glycan Database Search
by Chandler, Kevin Brown and Pompach, Petr and Goldman, Radoslav and Edwards, Nathan
Journal of Proteome Research, ISSN 1535-3893, 08/2013, Volume 12, Issue 8, pp. 3652 - 3666
Glycosylation is a common protein modification with a significant role in many vital cellular processes and human diseases, making the characterization of... 
Glycopeptide Identification | Glycan Microheterogeneity | Glycoproteomics | Glycan Structure Databases | Collision-Induced Dissociation | Tandem Mass-Spectrometry | BIOCHEMICAL RESEARCH METHODS | TISSUE-SPECIFIC EXPRESSION | SELECTIVE IDENTIFICATION | HYDROPHILIC INTERACTION CHROMATOGRAPHY | LINKED OLIGOSACCHARIDES | DIGESTS | LC-MS | ANNOTATION | GLYCOMICS | PROTEIN GLYCOSYLATION | SPECTROMETRY | Amino Acid Sequence | Haptoglobins - chemistry | Humans | Molecular Sequence Data | Glycosylation | Polysaccharides - analysis | Peptide Fragments - analysis | Artifacts | Tandem Mass Spectrometry | Algorithms | Proteolysis | Chromatography, Liquid | Software | Trypsin - chemistry | Databases, Factual
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8. Full Text Dehydrogenation of n-Alkanes Catalyzed by Iridium “Pincer” Complexes:  Regioselective Formation of α-Olefins
by Liu, Fuchen and Pak, Esther B and Singh, Bharat and Jensen, Craig M and Goldman, Alan S
Journal of the American Chemical Society, ISSN 0002-7863, 04/1999, Volume 121, Issue 16, pp. 4086 - 4087
SATURATED-HYDROCARBONS | FUNCTIONALIZATION | CYCLOALKANES | ACTIVATION | MECHANISM | POLYHYDRIDE SYSTEM | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | CARBON-HYDROGEN | TRANSITION-METAL COMPLEX | Dehydrogenation | Olefins | Alkanes | Research | Catalysis | Iridium | Coordination compounds
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9. Bi-enhanced N incorporation in GaAsNBi alloys
by Occena J and Jen T and Rizzi E E and Johnson T M and Horwath J and Wang Y Q and Goldman R S
Applied Physics Letters, ISSN 0003-6951, 06/2017, Volume 110, Issue 24
We have examined the influence of bismuth (Bi) and nitrogen (N) fluxes on N and Bi incorporation during molecular-beam epitaxy of GaAs1-x-yNxBiy alloys. The... 
Incorporation | Channeling | Arsenic | Computer simulation | Bismuth | Molecular dynamics | Molecular beam epitaxy | Lattice sites | Fluxes | Nitrogen
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10. Full Text Catalytic Synthesis of n‑Alkyl Arenes through Alkyl Group Cross-Metathesis
by Dobereiner, Graham E and Yuan, Jian and Schrock, Richard R and Goldman, Alan S and Hackenberg, Jason D
Journal of the American Chemical Society, ISSN 0002-7863, 08/2013, Volume 135, Issue 34, pp. 12572 - 12575
n-Alkyl arenes were prepared in a one-pot tandem dehydrogenation/olefin metathesis/hydrogenation sequence directly from alkanes and ethylbenzene. Excellent... 
ACTIVATION | DEHYDROGENATION | ALKANE METATHESIS | IRIDIUM | OLEFIN METATHESIS | PYRROLIDE MAP COMPLEXES | OXIDATIVE ADDITION | CHEMISTRY, MULTIDISCIPLINARY | C-H BONDS | HYDROARYLATION | Measurement | Catalysis | Analysis | Surface energy | Metathesis
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11. Full Text Birational 2D Free-Form Deformation of degree 1×n
by Sederberg, Thomas W and Goldman, Ronald N and Wang, Xuhui
Computer Aided Geometric Design, ISSN 0167-8396, 05/2016, Volume 44, pp. 1 - 9
This paper shows that generic 2D-Free-Form Deformations of degree can be made birational by a suitable assignment of weights to the Bézier or B-spline control... 
Free-Form Deformation | Birational map | Algebra | Maps | Deformation | Bezier | Nonlinearity | Mapping | Two dimensional | Computer aided design
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12. Full Text Assessment of the Electronic Factors Determining the Thermodynamics of “Oxidative Addition” of C–H and N–H Bonds to Ir(I) Complexes
by Wang, David Y and Choliy, Yuriy and Haibach, Michael C and Hartwig, John F and Krogh-Jespersen, Karsten and Goldman, Alan S
Journal of the American Chemical Society, ISSN 0002-7863, 01/2016, Volume 138, Issue 1, pp. 149 - 163
A study of electronic factors governing the thermodynamics of C–H and N–H bond addition to Ir­(I) complexes was conducted. DFT calculations were performed on... 
D6 ML5 COMPLEXES | TRANSITION-METAL-COMPLEXES | MOLECULAR-ORBITAL METHODS | EFFECTIVE CORE POTENTIALS | PINCER LIGANDS | CARBON-HYDROGEN BOND | BASIS-SETS | REDUCTIVE ELIMINATION | IRIDIUM COMPLEX | PHOSPHINE COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY
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13. Full Text Transition-Metal-Mediated Release of Nitric Oxide (NO) from S‑Nitroso‑N‑acetyl-d-penicillamine (SNAP): Potential Applications for Endogenous Release of NO at the Surface of Stents Via Corrosion Products
by McCarthy, Connor W and Guillory, Roger J and Goldman, Jeremy and Frost, Megan C
ACS Applied Materials & Interfaces, ISSN 1944-8244, 04/2016, Volume 8, Issue 16, pp. 10128 - 10135
Nitric oxide (NO), identified over the last several decades in many physiological processes and pathways as both a beneficial and detrimental signaling... 
Research | nitric oxide | S-nitrosothiol | thrombosis | biodegradable stent | transition metal | MATERIALS SCIENCE, MULTIDISCIPLINARY | NANOSCIENCE & NANOTECHNOLOGY | BLOOD | Animals | S-Nitroso-N-Acetylpenicillamine | Corrosion | Nitric Oxide - chemistry | Nitric Oxide - chemical synthesis | Rats | Penicillamine | Stents
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14. Full Text Semi-Automated Identification of N-Glycopeptides by Hydrophilic Interaction Chromatography, nano-Reverse-Phase LC–MS/MS, and Glycan Database Search
by Pompach, Petr and Chandler, Kevin B and Lan, Renny and Edwards, Nathan and Goldman, Radoslav
Journal of Proteome Research, ISSN 1535-3893, 03/2012, Volume 11, Issue 3, pp. 1728 - 1740
Glycoproteins fulfill many indispensable biological functions, and changes in protein glycosylation have been observed in various diseases. Improved analytical... 
oxonium ions | detached glycans | GlycoPeptideSearch software | Q-TOF | hemopexin | HILIC chromatography | mass spectrometry | haptoglobin | MASS-SPECTROMETRY DATA | PROTEIN | LASER-DESORPTION | PANCREATIC-CANCER | BIOCHEMICAL RESEARCH METHODS | SERUM | GLYCOSYLATION SITES | HEPATOCELLULAR-CARCINOMA | HIGH-SENSITIVITY | LIQUID-CHROMATOGRAPHY | AFFINITY-CHROMATOGRAPHY | Carbohydrate Sequence | Amino Acid Sequence | Chromatography, Reverse-Phase - methods | Haptoglobins - chemistry | Peptide Fragments - isolation & purification | Humans | Molecular Sequence Data | Peptide Mapping - methods | Haptoglobins - isolation & purification | Protein Isoforms - isolation & purification | Hemopexin - isolation & purification | Tandem Mass Spectrometry | Peptide Fragments - chemistry | Polysaccharides - isolation & purification | Protein Isoforms - chemistry | Proteolysis | Databases, Protein | Glycoproteins - isolation & purification | Hydrophobic and Hydrophilic Interactions | Polysaccharides - chemistry | Software | Hemopexin - chemistry | Glycoproteins - chemistry | Haptoglobin | Detached glycans | Hemopexin | Oxonium ions | Mass spectrometry | Glycopeptide search software
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15. Full Text N-linked glycosylation and its impact on the electrophoretic mobility and function of the human proton-coupled folate transporter ( HsPCFT)
by Selcuk Unal, Ersin and Zhao, Rongbao and Qiu, Andong and Goldman, I. David
BBA - Biomembranes, ISSN 0005-2736, 2008, Volume 1778, Issue 6, pp. 1407 - 1414
The human proton-coupled folate transporter ( PCFT, SLC46A1) mediates intestinal absorption of folates and transport of folates into the liver, brain and other... 
PCFT, proton-coupled folate transporter | Intestinal folate absorption | SLC46A1 | PCFT secondary structure | Hereditary folate malabsorption (HFM) | HCP1 | PCFT glycosylation | PCFT/HCP1 | Folate transport | TOPOLOGY | intestinal folate absorption | PROTEIN | VESICLES | BIOCHEMISTRY & MOLECULAR BIOLOGY | PCFF/HCP1 | hereditary folate malabsorption (HFM) | CARRIER | HEMAGGLUTININ EPITOPE INSERTION | BIOPHYSICS | HELA-CELLS | folate transport | MALABSORPTION | INFLUENZA-VIRUS | BRUSH-BORDER MEMBRANE | POLYACRYLAMIDE-GEL | Molecular Weight | Folate Receptors, GPI-Anchored | Electrophoresis, Polyacrylamide Gel | Humans | Receptors, Cell Surface - metabolism | Glycosylation | Mutation, Missense | Blotting, Western | Membrane Transport Proteins - chemistry | Carrier Proteins - genetics | Carrier Proteins - metabolism | Biological Transport, Active - physiology | Membrane Transport Proteins - genetics | Folic Acid - metabolism | Carrier Proteins - chemistry | Membrane Transport Proteins - metabolism | Receptors, Cell Surface - chemistry | HeLa Cells | Proton-Coupled Folate Transporter | Amino Acid Substitution | Intestinal Absorption - physiology | Receptors, Cell Surface - genetics | Folic acid
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16. Full Text Optimized Fragmentation for Quantitative Analysis of Fucosylated N-Glycoproteins by LC-MS-MRM
by Yuan, W and Wei, RHZ and Goldman, R and Sanda, M
ANALYTICAL CHEMISTRY, ISSN 0003-2700, 07/2019, Volume 91, Issue 14, pp. 9206 - 9212
Quantitative analysis of site specific glycoforms of proteins is technically challenging but highly desirable; resolution of the fucosylated glycoforms is of... 
LIVER-CIRRHOSIS | CHEMISTRY, ANALYTICAL | QUANTIFICATION | HAPTOGLOBIN | GLYCOSYLATION | BINDING | FIBRIN | Fractionation | Liver | Workflow | Glycoproteins | Fragmentation | Proteins | Cirrhosis | Plasma proteins | Etiology | Fibrinogen | Glycopeptides | Liver cirrhosis | Quantitative analysis
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17. Full Text Synthesis and Characterization of the Novel Nitric Oxide (NO) Donating Compound, S‑nitroso-N-acetyl-D-penicillamine Derivatized Cyclam (SNAP-Cyclam)
by McCarthy, Connor W and Goldman, Jeremy and Frost, Megan C
ACS Applied Materials & Interfaces, ISSN 1944-8244, 03/2016, Volume 8, Issue 9, pp. 5898 - 5905
Nitric oxide (NO) has been heavily studied over the past two decades due to its multitude of physiological functions and its potential therapeutic promise. Of... 
Research | macrocycle | controlled release | nitric oxide | poly(l -lactic acid) | long-term | POLYMERS | MATERIALS SCIENCE, MULTIDISCIPLINARY | NANOSCIENCE & NANOTECHNOLOGY | RELEASE | poly(L-lactic acid) | Polyesters - chemistry | Nitric Oxide Donors - chemistry | Heterocyclic Compounds - chemistry | Chromatography, High Pressure Liquid | Kinetics | Nitric Oxide Donors - chemical synthesis | S-Nitroso-N-Acetylpenicillamine - chemistry | Nitric Oxide - metabolism | Spectroscopy, Fourier Transform Infrared | Nitric Oxide - analysis | Spectrophotometry, Ultraviolet | S-Nitroso-N-Acetylpenicillamine - chemical synthesis
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18. Full Text N-Glycosylation is required for secretion of the precursor to brain-derived neurotrophic factor (proBDNF) carrying sulfated LacdiNAc structures
by Benicky, J and Sanda, M and Kennedy, ZB and Goldman, R
JOURNAL OF BIOLOGICAL CHEMISTRY, ISSN 0021-9258, 11/2019, Volume 294, Issue 45, pp. 16816 - 16830
Brain-derived neurotrophic factor (BDNF) is generated by proteolytic cleavage of a prodomain from the proBDNF precursor either intracellularly by furin-like... 
CELLS | DIFFERENTIAL EXPRESSION | BDNF | BIOCHEMISTRY & MOLECULAR BIOLOGY | brain-derived neurotrophic factor (BDNF) | TRAFFICKING | glycosylation | RECEPTOR | LacdiNAc | HAPTOGLOBIN | N121Q | LIVER-CIRRHOSIS | maturation | SITE-SPECIFIC GLYCOFORMS | glycoprotein | sulfation | MOLECULAR-CLONING | neurotrophin | SORTILIN | mass spectrometry (MS)
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19. Full Text 13 C and 15 N fractionation of CH 4 /N 2 mixtures during photochemical aerosol formation: Relevance to Titan
by Sebree, Joshua A and Stern, Jennifer C and Mandt, Kathleen E and Domagal-Goldman, Shawn D and Trainer, Melissa G
Icarus, ISSN 0019-1035, 05/2015, Volume 270, p. 421
The ratios of the stable isotopes that comprise each chemical species in Titan's atmosphere provide critical information towards understanding the processes... 
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