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Journal of the American Chemical Society, ISSN 0002-7863, 06/2017, Volume 139, Issue 21, p. 8082
Journal Article
Angewandte Chemie, ISSN 1433-7851, 05/2017, Volume 56, Issue 22, p. 6161
Treatment of alkenylstannanes with Cu(OAc)2/Et3N affords the corresponding enol esters or ketones under conditions that proved compatible with many common... 
Carbonyl compounds | Ketones | Lipids | Esters | Oxidation | Carbonyls
Journal Article
Angewandte Chemie, ISSN 1433-7851, 07/2013, Volume 52, Issue 29, p. 7532
  No leaving group needed: With an Ir(P,olefin) complex as catalyst, the direct enantioselective allylic alkynylation of secondary allylic alcohols with... 
Journal Article
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2015, Volume 54, Issue 26, pp. 7644 - 7647
Iridium‐catalyzed enantioselective allylic alkylation of branched racemic carbonates with functionalized alkylzinc bromide reagents is described. Enabled by a... 
enantioselectivity | iridium | alkylation | zinc | allylic compounds | Allylic compounds | Iridium | Enantioselectivity | Alkylation | Zinc | COMPLEXES | ALDEHYDES | SUBSTITUTION-REACTIONS | TERTIARY | CHEMISTRY, MULTIDISCIPLINARY | AMINATION | LIGANDS | REGIO | ALPHA-ALLYLATION | GRIGNARD-REAGENTS | CONJUGATE ADDITION | Synthesis | Carbonates | Enantiomers | Organic compounds | Utilities | Asymmetry | Bromides | Nucleophiles
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 02/2014, Volume 136, Issue 8, pp. 3006 - 3009
The direct Ir-catalyzed cross-coupling between branched, racemic allylic alcohols and simple olefins is described. This transformation is catalyzed by an... 
2,4-DISUBSTITUTED CYCLOPENTENONES | ORGANIC-SYNTHESIS | ATOM ECONOMY | ALKYLATION | SUBSTITUTIONS | CONSTRUCTION | COMPLEXES | INTERNAL OLEFINS | NUCLEOPHILE | CHEMISTRY, MULTIDISCIPLINARY | DEAROMATIZATION | Allylic compounds | Olefins | Influence | Chemical properties | Iridium | Catalysis | Research
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2013, Volume 52, Issue 29, pp. 7532 - 7535
No leaving group needed: With an Ir(P,olefin) complex as catalyst, the direct enantioselective allylic alkynylation of secondary allylic alcohols with... 
enantioselectivity | iridium | alkynyltrifluoroborates | allylic substitution | alkynes | SUBSTITUTION | CARBONYL GROUPS | ALKYLATION | ALLYLATION | ASYMMETRIC ADDITION | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | AMINATION | ESTERS | TRIFLUOROBORATE | CONJUGATE ADDITION | Enantiomers | Receptors | Level (quantity) | Synthesis | Catalysts | Potassium | Alcohols
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 09/2014, Volume 53, Issue 40, pp. 10759 - 10762
An enantioselective allyl–allylsilane cross‐coupling involving racemic branched allylic alcohols and allylsilanes is reported. An iridium‐(P,olefin)... 
enantioselectivity | iridium | 1,5‐diene | allylic substitution | allylsilane | 1 5-diene | SUBSTITUTION | ATOM ECONOMY | ALKYLATION | ALDEHYDES | CHEMISTRY, MULTIDISCIPLINARY | ALCOHOLS | AMINATION | 1,5-diene | CONSTRUCTION | REGIO | ALPHA-ALLYLATION | DEAROMATIZATION | Enantiomers | Insecticides | Analysis | Utilities | Synthesis | Asymmetry | Catalysts | Branched | Joining | Transformations | Alcohols
Journal Article
Journal of the American Chemical Society, ISSN 0002-7863, 06/2017, Volume 139, Issue 24, pp. 8082 - 8085
Iridium–(P,olefin) complex-catalyzed enantio- and diastereoselective formation of substituted spiroketals from racemic, allylic carbonates is reported, which... 
ENANTIOSELECTIVE ALLYLIC SUBSTITUTION | ASYMMETRIC-SYNTHESIS | ACID | NATURAL-PRODUCTS | ALKYLATION | BIOSYNTHESIS | ALLYLATION | REGIO | SPIROACETALS | CHEMISTRY, MULTIDISCIPLINARY | DEAROMATIZATION REACTION
Journal Article
Angewandte Chemie, ISSN 0044-8249, 05/2017, Volume 129, Issue 22, p. 6257
Treatment of alkenylstannanes with Cu(OAc)2/Et3N affords the corresponding enol esters or ketones under conditions that proved compatible with many common... 
Carbonyl compounds | Ketones | Lipids | Esters | Oxidation | Carbonyls
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 05/2017, Volume 56, Issue 22, pp. 6161 - 6165
Treatment of alkenylstannanes with Cu(OAc)2/Et3N affords the corresponding enol esters or ketones under conditions that proved compatible with many common... 
synthesis | cross-coupling | natural products | copper | tin oxidation | TRANS-HYDROMETALATION | CUPRIC ACETATE | ORGANIC-SYNTHESIS | C-N | TERMINAL ALKYNES | BOND FORMATION | INTERNAL ALKYNES | ARYLBORONIC ACID | CHEMISTRY, MULTIDISCIPLINARY | OXIDATIVE CLEAVAGE | 2-ALKYLIDENE OXETANES | Synthesis | Ketones | Acetates | Methods | Organic compounds
Journal Article
Angewandte Chemie, ISSN 0044-8249, 06/2015, Volume 127, Issue 26, p. 7754
  Iridium-catalyzed enantioselective allylic alkylation of branched racemic carbonates with functionalized alkylzinc bromide reagents is described. Enabled by... 
Journal Article
Organic Syntheses, ISSN 0078-6209, 2016, Volume 92, pp. 1 - 12
Journal Article
Alcohol, ISSN 0741-8329, 2008, Volume 42, Issue 5, pp. 349 - 361
Abstract This report is a summary of the symposium on Alcohol, Intestinal Bacterial Growth, Intestinal Permeability to Endotoxin, and Medical Consequences,... 
Psychiatry | Bacterial growth | Alcohol | Endotoxin | Nitric oxide | Intestinal permeability | Acetaldehyde | alcohol | ACETALDEHYDE-INDUCED INCREASE | nitric oxide | EPITHELIAL TIGHT JUNCTIONS | CROHNS-DISEASE | NITRIC-OXIDE SYNTHASE | SUBSTANCE ABUSE | PARACELLULAR PERMEABILITY | bacterial growth | INDUCED LIVER-INJURY | CHAIN KINASE EXPRESSION | intestinal permeability | INFLAMMATORY-BOWEL-DISEASE | HEPATIC STELLATE CELLS | TOLL-LIKE RECEPTOR-4 | PHARMACOLOGY & PHARMACY | TOXICOLOGY | acetaldehyde | endotoxin | Endotoxins - blood | Intestines - drug effects | Acetaldehyde - metabolism | Zinc - metabolism | Humans | Glutamine - metabolism | Intestines - metabolism | Gram-Negative Bacteria - metabolism | Bacterial Translocation - drug effects | Intestinal Mucosa - drug effects | Liver Diseases, Alcoholic - etiology | Receptor, Epidermal Growth Factor - metabolism | Ethanol - adverse effects | Burns - metabolism | Alcohol Drinking - metabolism | Avena - metabolism | Endotoxins - metabolism | Permeability | Alcohol Drinking - adverse effects | Liver Diseases, Alcoholic - metabolism | Gram-Negative Bacteria - drug effects | Animals | Intestines - microbiology | Gram-Negative Bacteria - growth & development | Probiotics - therapeutic use | Nitric Oxide - metabolism | Studies | Respiratory distress syndrome | Small intestine | Alcoholism | Rodents | Index Medicus
Journal Article
Angewandte Chemie, ISSN 0044-8249, 09/2014, Volume 126, Issue 40, p. 10935
  An enantioselective allyl-allylsilane cross-coupling involving racemic branched allylic alcohols and allylsilanes is reported. An iridium-(P,olefin)... 
Journal Article
Angewandte Chemie, ISSN 0044-8249, 07/2013, Volume 125, Issue 29, pp. 7680 - 7683
Journal Article
Angewandte Chemie, ISSN 0044-8249, 07/2013, Volume 125, Issue 29, p. 7680
Journal Article