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Chemistry – A European Journal, ISSN 0947-6539, 09/2017, Volume 23, Issue 50, pp. 12233 - 12242
Owing to the highly electron‐withdrawing C 2 F 5 groups, the tris(pentafluoroethyl)germane (C 2 F 5 ) 3 GeH represents an interesting Brønsted acidic compound.... 
germane | Tolman electronic parameter | pentafluoroethyl | fluorine | transition-metal complexes | SPECTRA | CHEMISTRY, MULTIDISCIPLINARY | Stereoisomers | Solid state | Naphthalene | Molecular structure | X-ray diffraction | Chemical bonds | Acidity | Coordination compounds | Metal complexes | Substrates | Alkynes
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 07/2017, Volume 56, Issue 29, pp. 8578 - 8582
Tris[tetrafluoro‐4‐(trifluoromethyl)phenyl]borane (BTolF) was prepared by treating boron tribromide with tetrameric F 3 CC 6 F 4 ‐Cu I . The F 3 CC 6 F 4 ‐Cu I... 
tris(perfluorotolyl)borane | Lewis superacid | tris(pentafluorophenyl)borane | gas-phase electron diffraction | HYDROGENATION | HETEROLYTIC ACTIVATION | OLEFIN POLYMERIZATION | GAS ELECTRON-DIFFRACTION | CHEMISTRY, MULTIDISCIPLINARY | DIHYDROGEN | RESONANCE | METAL-FREE | ACIDITY | PAIRS | Single crystals | Boron | Fluoride | Diffraction | Electron diffraction | Crystals | X-ray diffraction
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2015, Volume 54, Issue 45, pp. 13416 - 13419
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2019, Volume 58, Issue 26, pp. 8938 - 8942
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2018, Volume 57, Issue 17, pp. 4765 - 4768
One‐electron reduction of C2‐arylated 1,3‐imidazoli(ni)um salts (IPr Ar )Br (Ar=Ph, 3 a ; 4‐DMP, 3 b ; 4‐DMP=4‐Me 2 NC 6 H 4 ) and (SIPr Ar )I (Ar=Ph, 4 a ;... 
X-ray diffraction | density functional calculations | radicals | EPR spectroscopy | N-heterocyclic carbenes | PERSISTENT | BORON | CATALYZED DIRECT C2-ARYLATION | NHC | IMIDAZOLIUM | CHEMISTRY, MULTIDISCIPLINARY | MAIN-GROUP CHEMISTRY | LIGANDS | DIRADICALS | CYCLIC (ALKYL)(AMINO) CARBENES | IMIDAZOL-2-YLIDENES | Heterocyclic compounds | Salts | Aromatic compounds | Carbenes | Radicals
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 07/2017, Volume 23, Issue 38, pp. 9044 - 9047
Four‐membered biradicaloid compounds containing a N 2 E 2 (E=main group element) framework have been thoroughly investigated; however, the synthesis of stable... 
carbenes | heterocycles | vinylidenes | phosphorus | NON-KEKULE | CARBENE | CHEMISTRY, MULTIDISCIPLINARY | VALENCE ISOMERIZATION | LIGANDS | DIRADICALS | SNAPSHOTS | 1,3-DIPHOSPHACYCLOBUTANE-2,4-DIYL | 4-MEMBERED RING | RADICALS | ACCESS | Heterocyclic compounds | Vinylidene | Phosphorus | Nuclear magnetic resonance--NMR | Temperature effects | Diamagnetism
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 12/2016, Volume 55, Issue 52, pp. 16156 - 16160
Tris(pentafluoroethyl)silane, which is conveniently accessible by the treatment of Si(C 2 F 5 ) 3 X (X=Cl, Br) with Bu 3 SnH, was successfully employed for... 
hydrosilylation | silanes | silanides | perfluoroalkyl compounds | fluorine | SILICON | COMPLEXES | REACTIVITY | STEP | TRICHLOROSILANE | CHEMISTRY, MULTIDISCIPLINARY | CHEMISTRY | METAL SILANIDES | BOND
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 02/2018, Volume 24, Issue 8, pp. 1838 - 1843
Pentafluoroethyllithium, LiC 2 F 5 , has been established as an efficient and versatile reagent for the transfer of the pentafluoroethyl unit to a number of... 
lithium | gas-free | perfluoroalkylation | tin–lithium exchange | fluorine | REAGENT | IMINES | NUCLEOPHILIC PERFLUOROALKYLATION | CUPRATION | ALDEHYDES | C-H FUNCTIONALIZATION | BROMIDES | CHEMISTRY, MULTIDISCIPLINARY | KETONES | HETEROARENES | tin-lithium exchange | TRIFLUOROMETHYLATION | Salts | Chemical synthesis | Commercialization | Butyllithium
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 08/2019, Volume 2019, Issue 30, pp. 3462 - 3475
The reaction of [GaCl 3 (OEt 2 ) n ] with LiC 2 F 5 surprisingly leads to the formation of the anion [Ga(C 2 F 5 ) 3 Cl] – . The obtained lithium and... 
Fluorinated ligands | Lewis acids | Gallium | Fluorine | Weakly coordinating anions | LEWIS ACIDITY | DERIVATIVES | INDIUM | CHEMISTRY, INORGANIC & NUCLEAR | Infrared spectroscopy | Anions | Nuclear magnetic resonance--NMR | Hydrogen chlorides | Gallium chloride | Lithium | Mass spectrometry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2015, Volume 54, Issue 46, pp. 13764 - 13768
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 09/2018, Volume 2018, Issue 35, pp. 3960 - 3970
The treatment of phenyl‐protected pentafluoroethylstannanes, Sn(C 2 F 5 ) 4– n Ph n ( n = 1–3), with anhydrous HF results in the formation of the corresponding... 
Pentafluoroethyl | Perfluoroalkyl | Fluorine | Hypervalent compounds | Tin fluorides | ANION | MOLECULAR-STRUCTURE | SN-119 | COORDINATION | FLUORIDE COMPLEXES | RAY CRYSTAL-STRUCTURE | CHEMISTRY, INORGANIC & NUCLEAR | CHEMISTRY | Tin | Cesium | Cesium fluorides | Fluorides | Stannates | Lithium fluoride
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 09/2018, Volume 2018, Issue 35, pp. 3971 - 3977
In this contribution the syntheses of transition metal complexes of the electron‐withdrawing Sn(C 2 F 5 ) 3 ligand are presented. The reaction of HSn(C 2 F 5 )... 
Fluorinated ligands | Tin | Transition metals | Coordination modes | CATALYSIS | CO-ORDINATION COMPLEXES | MOLYBDENUM | CRYSTAL STRUCTURE | STANNYL GROUPS | CHEMISTRY, INORGANIC & NUCLEAR | ORGANOMETALLIC CHEMISTRY | BONDS | METAL | DERIVATIVES | Organic chemistry | Nickel carbonyl | Transition metal compounds | Organometallic compounds | Ligands | Iron | Metal carbonyls | Coordination compounds | Fluorination | Molybdenum | Zinc
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 04/2019, Volume 58, Issue 15, pp. 5114 - 5118
Journal Article