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Coordination Chemistry Reviews, ISSN 0010-8545, 2011, Volume 255, Issue 11, pp. 1252 - 1267
This review summarizes the rapid developments in the chemistry of phosphonium-stabilized group 1 and 2 methandiides, i.e. that of alkali and alkaline-earth... 
Carbanions | Metal carbenes | Alkali metals | Alkaline-earth metals | METHANDIIDE | ALKALI-METAL LI | CRYSTAL-STRUCTURE | STRUCTURAL-CHARACTERIZATION | COORDINATION | PLANAR | CHEMISTRY, INORGANIC & NUCLEAR | BOND LENGTH | MAGNESIUM | LIGANDS | CARBENE COMPLEXES
Journal Article
ISSN 1359-7345, 10/2012, Volume 48, Issue 91, pp. 11165 - 11177
.../chemcomm FEATURE ARTICLE Molecular early main group metal hydrides: synthetic challenge, structures and applicationsw Sjoerd Harder*z Received 14th May 2012, Accepted... 
Journal Article
Chemical Communications, ISSN 1359-7345, 11/2011, Volume 47, Issue 43, pp. 11945 - 11947
Journal Article
Dalton Transactions, ISSN 1477-9226, 9/2018, Volume 47, Issue 36, pp. 12491 - 12492
Welcome to this issue of Dalton Transactions featuring the themed issue 'Organometallic and Coordination Chemistry of the s -Block Metals'. 
STRONG BASES | CATALYSIS | COMPLEX | REAGENTS | ALKALI-METALS | ALKYL | ARYL DERIVATIVES | LITHIUM | CHEMISTRY, INORGANIC & NUCLEAR | Organic chemistry
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2019, Volume 58, Issue 44, pp. 15736 - 15741
Preference for the binding mode of the CN− ligand to Mg (Mg−CN vs. Mg−NC) is investigated. A monomeric Mg complex with a terminal CN ligand was prepared using... 
magnesium | cyanide | alkaline-earth metal | DFT calculations | isocyanide | INFRARED-SPECTRA | CRYSTAL-STRUCTURE | ISOMERIZATION | CHEMISTRY | ATOMS | CHEMISTRY, MULTIDISCIPLINARY | SOLID-STATE | Cyanides | Magnesium | Structure | Isomerization | Crystals | Cyanide | Nuclear magnetic resonance--NMR | Mathematical analysis | Ligands | Coordination compounds | Dimerization | Crystal structure | Communications | Communication
Journal Article
Chemistry – A European Journal, ISSN 0947-6539, 12/2019, Volume 25, Issue 70, pp. 16141 - 16147
The efficient catalytic reduction of imines with phenylsilane is achieved by using the potassium, calcium and strontium based catalysts [(DMAT)K (THF)]∞,... 
hydrosilylation | density functional calculations | imines | potassium | alkaline earth metals | Metal hydrides | Barium | Calcium | Catalysts | Amides | Hydrosilylation | Substrates | Intermediates | Strontium | Imines | Aromatic compounds | Potassium | Functional groups | Full Paper | Full Papers
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2019, Volume 58, Issue 43, pp. 15496 - 15503
The low‐valent ß‐diketiminate complex (DIPPBDI)Al is stable in benzene but addition of catalytic quantities of [(DIPPBDI)CaH]2 at 20 °C led to (DIPPBDI)Al(Ph)H... 
Oxidative addition | Aluminium | C−H bond activation | Calcium | Paraxylene | Toluene | Bonds | Iodides | Catalysts | Aluminum | Activation | Hydrides | Selectivity | Zinc | Dipping | Hydrogen bonds | Benzene | Xylene | Magnesium | Electron density
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2018, Volume 57, Issue 24, pp. 7156 - 7160
Imine‐to‐amine conversion with catalytic instead of stoichiometric quantities of LiAlH4 is demonstrated (85 °C, catalyst loading≥2.5 mol %, pressure≥1 bar).... 
hydrides | aluminium | lithium | reduction | sustainability | FORMIC-ACID | HYDROBORATION | METAL-CATALYSTS | COMPLEXES | CARBONYL-COMPOUNDS | CHEMISTRY, MULTIDISCIPLINARY | FRUSTRATED LEWIS PAIR | DEHYDROGENATION | SOLUBLE CALCIUM HYDRIDE | LITHIUM ALUMINUM-HYDRIDE | CHEMISTRY | Hydrogenation | Catalysis | Pressure effects | Catalysts | Temperature effects | Lithium aluminum hydrides | Pressure | Catalytic converters | Substrates
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2011, Volume 50, Issue 18, pp. 4156 - 4160
Big can be small: The largest ligand‐stabilized magnesium hydride cluster, containing 8 Mg2+ and 10 H− ions, is a model for the smallest sub‐nanometer‐sized... 
hydrides | AMMONIA | COMPLEXES | REACTIVITY | magnesium | BORANE | ADDUCT | hydrogen storage | NANOPARTICLES | cluster compounds | CALCIUM | BONDS | CHEMISTRY | CATALYSTS | H-1 | CHEMISTRY, MULTIDISCIPLINARY
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 01/2015, Volume 54, Issue 1, pp. 201 - 206
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 11/2018, Volume 57, Issue 46, pp. 15177 - 15182
Alkaline earth metal amides (AeN′′2: Ae=Ca, Sr, Ba, N′′=N(SiMe3)2) catalyze alkene hydrogenation (80–120 °C, 1–6 bar H2, 1–10 mol % cat.), with the activity... 
alkenes | hydrogenation | alkaline earth metals | DFT calculations | CALCIUM | BIS(TRIMETHYLSILYL)AMIDES | CATION | CHEMISTRY, MULTIDISCIPLINARY | HYDRIDE | Oligomers | Metal catalysts | Olefins | Bonds | Polymerization | Amides | Chemical properties | Hydrogenation | Barium | Oligomerization | Catalysts | Calcium | Alkenes | Metals | Cyclohexene | Strontium | Alkaline earth metals | Styrenes | Mathematical analysis | Styrene | Protonation | Catalysis | Bonding | Stilbene
Journal Article
European Journal of Inorganic Chemistry, ISSN 1434-1948, 11/2019, Volume 2019, Issue 41, pp. 4433 - 4439
The reaction of Mg[N(SiMe3)2]2 with PhSiH3 in benzene at room temperature gave a white precipitate of approximate constitution MgH1.5N′′0.5. This undefined... 
Alkaline earth metals | Hydrides | Solvation | Magnesium | DFT calculations | Mathematical analysis | Enthalpy | Benzene | Crystallization | Ligands | Charge transfer | Coordination compounds | Room temperature | Structural analysis
Journal Article
ISSN 1477-9226, 7/2010, Volume 39, Issue 29, pp. 6677 - 6681
The use and coordination modes of the dianionic bora-amidinate ligand in lanthanide( iii ) chemistry is explored. Synthetic routes to complexes of the type... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2017, Volume 56, Issue 24, pp. 6906 - 6910
An anionic N‐heterocyclic olefin ligand was serendipitously obtained by reaction of an amidinate calcium hydride complex with 1,3‐dimethyl‐2‐methyleneimidazole... 
hydrides | N-heterocyclic olefin | calcium | carbene ligands | CARBENE | REAGENTS | MAIN-GROUP | COMPLEXES | COORDINATION | CHEMISTRY, MULTIDISCIPLINARY | DONOR LIGANDS | CHEMISTRY | METAL | DERIVATIVES | CATALYSTS | Surface active agents | Heterocyclic compounds | Olefins | Calcium | Ligands
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 03/2019, Volume 58, Issue 13, pp. 4248 - 4253
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2018, Volume 57, Issue 43, pp. 14169 - 14173
Attempted synthesis of the donor–acceptor complex (BDI)Ca+←AlI(BDI) complex by reaction of (BDI)Ca+ in the form of its B(C6F5)4− salt with (BDI)AlI in benzene... 
aluminium | calcium | low-valent metals | structure elucidation | dearomatization | Chemical properties | Benzene | Olefins | Aluminum oxide | Lewis acid | Calcium | Hydrocarbons | Anions | Acids | Bonding strength | Coordination compounds | Lewis base | Chelates | Calcium ions | Metal ions
Journal Article