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1. Full Text Dynamic display of biomolecular patterns throughanelastic creasing instability of stimuli-responsive hydrogels
by Kim, Jungwook and Yoon, Jinhwan and Hayward, Ryan C
Nature Materials, ISSN 1476-1122, 02/2010, Volume 9, Issue 2, pp. 159 - 164
Surfaces with physicochemical properties that can be modulated using external stimuli offer great promise for designing responsive or adaptive materials. Here,... 
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2. Full Text Liquid Crystal Elastomer Waveguide Actuators
by Kuenstler, Alexa S and Kim, Hyunki and Hayward, Ryan C
Advanced Materials, ISSN 0935-9648, 06/2019, Volume 31, Issue 24, pp. e1901216 - n/a
While most photomechanical materials developed to date have relied on free‐space illumination to drive actuation, this strategy fails when direct line‐of‐site... 
liquid crystal elastomers | photoresponsive materials | actuators | GOLD NANOPARTICLES | PHYSICS, CONDENSED MATTER | PHYSICS, APPLIED | MATERIALS SCIENCE, MULTIDISCIPLINARY | LIGHT | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY | CHEMISTRY, MULTIDISCIPLINARY | SILVER NANOPARTICLES | FILMS | Waveguides | Actuators | Elastomers | Nanoparticles | Chemical reduction | Gold | Organic chemistry | Deformation | Nanocomposites | Light | Actuation | Liquid crystals
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3. Photothermocapillary Oscillators
by Adam W Hauser and Subramanian Sundaram and Ryan C Hayward
Physical Review Letters, ISSN 0031-9007, 10/2018, Volume 121, Issue 15
We present a new class of tunable light-driven oscillators based on mm-scale objects adsorbed at fluid interfaces. A fixed light source induces photothermal... 
Luminous intensity | Hydrogels | Nanocomposites | Incident light | Surface tension | Curvature | Oscillators
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4. Full Text Enabling Robust Self‐Folding Origami by Pre‐Biasing Vertex Buckling Direction
by Kang, Ji‐Hwan and Kim, Hyunki and Santangelo, Christian D and Hayward, Ryan C
Advanced Materials, ISSN 0935-9648, 09/2019, Volume 31, Issue 39, pp. e0193006 - n/a
Self‐folding is a powerful approach to fabricate materials with complex 3D forms and advanced properties using planar patterning steps, but suffers from... 
origami | self‐folding | programmable deformation | hydrogels | stimuli responsive | PHYSICS, CONDENSED MATTER | COMPLEX | DESIGN | PHYSICS, APPLIED | self-folding | MATERIALS SCIENCE, MULTIDISCIPLINARY | CHEMISTRY, PHYSICAL | NANOSCIENCE & NANOTECHNOLOGY | CHEMISTRY, MULTIDISCIPLINARY | Automation | Hydrogels | Swelling | Manufacturing engineering | Actuation | Bifurcations | Metamaterials | Morphing | High temperature | Robotics | Complexity | Apexes | Folding
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5. Full Text Light-induced shape morphing of thin films
by Kuenstler, Alexa S and Hayward, Ryan C
Current Opinion in Colloid & Interface Science, ISSN 1359-0294, 04/2019, Volume 40, pp. 70 - 86
Shape transformation of thin two-dimensional sheets into three-dimensional structures using light is of great interest for remotely controlled fabrication,... 
Actuators | Photomechanics | Light-responsive materials | Shape morphing | Polymers | Soft materials | Thin film mechanics | Thin films | Dielectric films
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6. Full Text Effects of Randomly End-Linked Copolymer Network Parameters on the Formation of Disordered Cocontinuous Phases
by Zeng, Di and Hayward, Ryan C
Macromolecules, ISSN 0024-9297, 2019, Volume 52, Issue 7, pp. 2642 - 2650
Randomly end-linked copolymer networks (RECNs) provide a robust route to cocontinuous nanoscale structures, yielding opportunities to integrate desirable and... 
POLYMERS | ORDER | POLYMER SCIENCE | BLOCK-COPOLYMERS | BEHAVIOR | CONETWORKS | SOL-GEL | POLYDISPERSITY | NANOPOROUS MATERIALS | MICROPHASE SEPARATION | SCATTERING
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7. Full Text Biasing Buckling Direction in Shape‐Programmable Hydrogel Sheets with Through‐Thickness Gradients
by Zhou, Ying and Duque, Carlos M and Santangelo, Christian D and Hayward, Ryan C
Advanced Functional Materials, ISSN 1616-301X, 11/2019, Volume 29, Issue 48, pp. 1905273 - n/a
A photocrosslinkable poly(N, N′‐diethylacrylamide) copolymer allows for the photolithographic fabrication of hydrogel sheets with nonuniform crosslinking... 
photolithography | shape morphing | hydrogels | temperature responsiveness | curvature
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8. Full Text Hierarchically Structured Microparticles Formed by Interfacial Instabilities of Emulsion Droplets Containing Amphiphilic Block Copolymers
by Zhu, Jintao and Hayward, Ryan C
Angewandte Chemie International Edition, ISSN 1433-7851, 02/2008, Volume 47, Issue 11, pp. 2113 - 2116
Blooming block copolymers! Uniform droplets of solvent that contain amphiphilic polystyrene–poly(ethylene oxide) diblock copolymers are prepared using a... 
block copolymers | electron microscopy | microparticles | emulsions | microfluidics | Emulsions | Electron microscopy | Block copolymers | Microfluidics | Microparticles | DIBLOCK COPOLYMERS | POLYMERS | DRUG-DELIVERY | VESICLES | STABILITY | MORPHOLOGIES | CHEMISTRY, MULTIDISCIPLINARY | OF-THE-ART | SOLVENT | SPONTANEOUS EMULSIFICATION | Particle Size | Emulsions - chemistry | Solvents - chemistry | Micelles | Surface Properties | Water - chemistry | Polyethylene Glycols - chemistry | Polymers - chemistry | Surface-Active Agents - chemistry | Polystyrenes - chemistry
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9. Full Text Orthogonal Ambipolar Semiconductors with Inherently Multi-Dimensional Responses for the Discriminative Sensing of Chemical Vapors
by Huang, Weiguo and Hayward, Ryan C
ACS Applied Materials & Interfaces, ISSN 1944-8244, 10/2018, Volume 10, Issue 39, pp. 33353 - 33359
Numerous examples of field-effect transistor (FET) biosensors and chemical sensors with good sensitivity and selectivity have now been developed. However,... 
Research | artificial olfactory system | chemical sensing | eight dimensional responses | chemical discrimination | orthogonal ambipolar semiconductor | CHEMIRESISTIVE SENSORS | MATERIALS SCIENCE, MULTIDISCIPLINARY | SENSITIVITY | NANOSCIENCE & NANOTECHNOLOGY | NANOSTRUCTURES | FIELD-EFFECT TRANSISTORS | LABEL-FREE DETECTION | CARBON NANOTUBES | GROWTH | SELECTIVE DETECTION | NANOWIRES | WATER
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10. Random photografting of polymers to nanoparticles for well-dispersed nanocomposites
by Hauser, Adam W and Hayward, Ryan C
Journal of Polymer Science, Part B: Polymer Physics, ISSN 0887-6266, 01/2016, Volume 54, Issue 2, pp. 152 - 158
A simple method to achieve dispersion of nanoparticles (NPs) within polymer matrices by solution-state photografting of benzophenone (BP)-containing random... 
nanoparticles | dispersions | photochemistry | nanocomposites | GOLD NANOPARTICLES | ATTACHMENT | POLYMER SCIENCE | BEHAVIOR | NANOCRYSTALS | GRAFTED-NANOPARTICLES | SIMULATION | COMPOSITES PHASE-STABILITY | BENZOPHENONE | MORPHOLOGY | SURFACES | Nanoparticles | Particulate composites | Ligands | Attachment | Dispersions | Chains (polymeric) | Polymers | Grafting
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11. Functional polymers for growth and stabilization of CsPbBr3 perovskite nanoparticles (Electronic supplementary information (ESI) available: Detailed synthesis procedure and characterizations. See DOI: 10.1039/c8cc09343a)
by Hyunki Kim and Soonyong So and Alexander Ribbe and Yao Liu and Weiguo Hu and Volodimyr V Duzhko and Ryan C Hayward and Todd Emrick
Chemical Communications : Chem Comm, ISSN 1359-7345, 01/2019, Volume 55, Issue 12, pp. 1833 - 1836
We introduce an approach to synthesize polymer-stabilized CsPbBr3 perovskite nanoparticles (NPs) using ammonium bromide-functionalized polymers as both bromide... 
Nanoparticles | Optoelectronics | Perovskites | Polymers | Ammonium bromides
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12. Full Text Spontaneous Generation of Amphiphilic Block Copolymer Micelles with Multiple Morphologies through Interfacial Instabilities
by Zhu, Jintao and Hayward, Ryan C
Journal of the American Chemical Society, ISSN 0002-7863, 06/2008, Volume 130, Issue 23, pp. 7496 - 7502
We introduce a method for the formation of block copolymer micelles through interfacial instabilities of emulsion droplets. Amphiphilic... 
Polystyrenes - chemical synthesis | Nanoparticles - chemistry | Micelles | Spectrometry, Fluorescence | Polyethylene Glycols - chemistry | Polyethylene Glycols - chemical synthesis | Polymethyl Methacrylate - chemical synthesis | Magnetics | Polymethyl Methacrylate - chemistry | Polystyrenes - chemistry | Hydrophobic effect | Emulsions | Research | Analysis
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13. Full Text Tailored Assemblies of Block Copolymers in Solution: It Is All about the Process
by Hayward, Ryan C and Pochan, Darrin J
Macromolecules, ISSN 0024-9297, 04/2010, Volume 43, Issue 8, pp. 3577 - 3584
Block copolymers have the capacity to self-organize into a myriad of aggregate structures when placed in selective solvents, offering great promise for the... 
DIBLOCK COPOLYMERS | TETRABLOCK COPOLYMER | POLYMER SCIENCE | MULTIPLE MORPHOLOGIES | MULTICOMPARTMENT MICELLES | DRUG-DELIVERY | SPONTANEOUS EMULSIFICATION | ABC TRIBLOCK COPOLYMER | OF-THE-ART | POLYMER VESICLES | INTERFACIAL INSTABILITIES
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14. Full Text Multiaddressable Photochromic Architectures: From Molecules to Materials
by Nie, Hui and Self, Jeffrey L and Kuenstler, Alexa S and Hayward, Ryan C and Read de Alaniz, Javier
Advanced Optical Materials, ISSN 2195-1071, 08/2019, Volume 7, Issue 16, pp. 1900224 - n/a
Multiaddressable architectures comprising light‐responsive photochromic molecules and different stimuli‐responsive components are appealing platforms for... 
orthogonal control | multiaddressable systems | photoswitches | stimuli‐responsive components | photoacids | PHOTOINDUCED ORIENTATION | MATERIALS SCIENCE, MULTIDISCIPLINARY | ANNIHILATION UP-CONVERSION | STIMULI-RESPONSIVE POLYMERS | stimuli-responsive components | AZOBENZENE GROUPS | VISIBLE-LIGHT | SWITCHES | DIARYLETHENE | REDOX | ENERGY-TRANSFER | PHOTO | OPTICS | Molecular machines | Organic chemistry | Photochromism | Crosstalk | Smart materials
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15. Formation of high aspect ratio wrinkles and ridges on elastic bilayers with small thickness contrast (Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sm01345d)
by Anesia Auguste and Jiawei Yang and Lihua Jin and Dayong Chen and Zhigang Suo and Ryan C Hayward
Soft Matter, ISSN 1744-683X, 01/2018, Volume 14, Issue 42, pp. 8545 - 8551
An elastic bilayer composed of a stiff film bonded to a soft substrate forms wrinkles under compression. While these uniform and periodic wrinkles initially... 
Finite element method | High aspect ratio | Compression | Broken symmetry | Amplitudes | Bifurcations | Period doubling | Ridges | Substrates
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16. Full Text Using origami design principles to fold reprogrammable mechanical metamaterials
by Silverberg, Jesse L and Evans, Arthur A and McLeod, Lauren and Hayward, Ryan C and Hull, Thomas and Santangelo, Christian D and Cohen, Itai
Science, ISSN 0036-8075, 08/2014, Volume 345, Issue 6197, pp. 647 - 650
Although broadly admired for its aesthetic qualities, the art of origami is now being recognized also as a framework for mechanical metamaterial design.... 
PROGRAMMABLE MATTER | MULTIDISCIPLINARY SCIENCES | Origami | Nanoparticles | Synthetic products | Usage | Materials research | Design and construction | Materials science | Mechanical engineering | Robots | Design engineering | Unit cell | Tunnels (transportation) | Buildings | Flats | Metamaterials | Folding
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17. Full Text Corrigendum: Origami structures with a critical transition to bistability arising from hidden degrees of freedom
by Silverberg, Jesse L and Na, Jun-Hee and Evans, Arthur A and Liu, Bin and Hull, Thomas C and Santangelo, Christian D and Lang, Robert J and Hayward, Ryan C and Cohen, Itai
Nature materials, ISSN 1476-1122, 05/2015, Volume 14, Issue 5, p. 540
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18. Full Text Mimicking dynamic in vivo environments with stimuli-responsive materials for cell culture
by Kim, Jungwook and Hayward, Ryan C
Trends in Biotechnology, ISSN 0167-7799, 2012, Volume 30, Issue 8, pp. 426 - 439
Traditional synthetic substrates and matrices for cell culture have proven to be of only limited utility in efforts to understand and control cell behavior, in... 
Internal Medicine | 3-DIMENSIONAL HYDROGELS | SPATIOTEMPORAL CONTROL | SURFACE-TOPOGRAPHY | DRUG-DELIVERY | BIOTECHNOLOGY & APPLIED MICROBIOLOGY | GROWTH-FACTORS | MECHANICAL STIMULATION | EXTRACELLULAR MATRICES | GEOMETRIC CONTROL | MESENCHYMAL STEM-CELLS | NONLINEAR ELASTICITY | Animals | Extracellular Matrix | Models, Biological | Humans | Cell Physiological Phenomena | Cell Culture Techniques - methods | Tissue Engineering | Environmental engineering | Bioengineering | Cell culture | Temperature | Peptides | Surface chemistry | Mechanical properties | Cell adhesion & migration | Signal transduction | Biomedical materials | Adsorption | Synthetic products | Behavior | Deoxyribonucleic acid--DNA
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19. Overcurvature induced multistability of linked conical frusta: how a ‘bendy straw’ holds its shape (Electronic supplementary information (ESI) available: SI text, Fig. S1–S7 and Movies M1–M5. See DOI: 10.1039/c8sm01355a)
by Nakul P Bende and Tian Yu and Nicholas A Corbin and Marcelo A Dias and Christian D Santangelo and James A Hanna and Ryan C Hayward
Soft Matter, ISSN 1744-683X, 01/2018, Volume 14, Issue 42, pp. 8636 - 8642
We study the origins of multiple mechanically stable states exhibited by an elastic shell comprising multiple conical frusta, a geometry common to... 
Angles (geometry) | Deformation | Conical shells | Stability | Bistability | Straw | Computed tomography | Deformation analysis | Deformation effects | Elastic shells | Curvature | Residual stress | Reconfigurable control systems
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20. Full Text Designing Responsive Buckled Surfaces by Halftone Gel Lithography
by Jungwook Kim and James A. Hanna and Myunghwan Byun and Christian D. Santangelo and Ryan C. Hayward
Science, ISSN 0036-8075, 3/2012, Volume 335, Issue 6073, pp. 1201 - 1205
Self-actuating materials capable of transforming between three-dimensional shapes have applications in areas as diverse as biomedicine, robotics, and tunable... 
Spherical caps | Copolymers | Composite materials | Swelling | Gels | Lithography | REPORTS | Materials | Polymers | Curvature | Buckling | MECHANICS | BEHAVIOR | MULTIDISCIPLINARY SCIENCES | LEAVES | FABRICATION | ACTUATORS | SHEETS | THIN | Amides | Composition | Usage | Advanced materials | Production processes | Materials science | Offset printing | Hydrogels
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