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iridium (11) 11
enantiomers (10) 10
alkylation (9) 9
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chemistry, organic (8) 8
esters (8) 8
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-dihydroprotolichesterinic acid (2) 2
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Angewandte Chemie, ISSN 0044-8249, 12/2016, Volume 128, Issue 52, pp. 16326 - 16329
The development of the first enantio‐, diastereo‐, and regioselective iridium‐catalyzed allylic alkylation reaction of prochiral enolates to form an all‐carbon... 
Allylische Alkylierungen | Iridium | Quartäre Stereozentren | Enantioselektive Synthesen | Vicinale Stereozentren | Enolates | Utilities | Chlorides | Transformations | Selectivity | Nucleophiles | Alkylation | Bearing
Journal Article
Proceedings of the National Academy of Sciences of the United States of America, ISSN 0027-8424, 08/2018, Volume 115, Issue 33, pp. 8301 - 8306
Journal Article
Angewandte Chemie, ISSN 0044-8249, 2018, Volume 130, Issue 28, pp. 8800 - 8803
The development of the first enantioselective transition‐metal‐catalyzed allylic alkylation providing access to acyclic products bearing vicinal all‐carbon... 
Übergangsmetallkatalyse | Iridium | Quartäre Stereozentren | Enantioselektive Synthese | Allylische Alkylierung | Nitriles | Chemotherapy | Enantiomers | Cancer
Journal Article
Organic Letters, ISSN 1523-7060, 04/2017, Volume 19, Issue 7, pp. 1527 - 1529
The first enantioselective iridium-catalyzed allylic alkylation reaction of a masked acyl cyanide (MAC) reagent has been developed. The transformation allows... 
CROSS-COUPLINGS | REAGENTS | AMINO-ACID DERIVATIVES | ESTERS | CHEMISTRY, ORGANIC | CARBONYL-COMPOUNDS | ALDEHYDES | DIASTEREO
Journal Article
Angewandte Chemie, ISSN 0044-8249, 09/2017, Volume 129, Issue 38, pp. 11703 - 11706
The first highly enantioselective iridium‐catalyzed allylic alkylation that provides access to products bearing an allylic all‐carbon quaternary stereogenic... 
Allylische Alkylierungen | Umpolung | Iridium | Quartäre Stereozentren | Carbonsäurederivate | Stereoisomerism | Carboxylic Acids - chemical synthesis | Carboxylic Acids - chemistry | Allyl Compounds - chemistry | Molecular Structure | Catalysis | Iridium - chemistry | Alkylation
Journal Article
The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, ISSN 1089-5639, 01/2019, Volume 123, Issue 2, pp. 590 - 600
Gas-phase autoxidation – the sequential regeneration of peroxy radicals (RO2) via intramolecular hydrogen shifts (H-shifts) followed by oxygen addition – leads... 
ALKOXY RADICALS | MULTIFUNCTIONAL ORGANIC-COMPOUNDS | ORBITAL METHODS | H-ATOM TRANSFER | CONFORMATIONAL ENERGIES | OXIDIZED RO2 RADICALS | PHYSICS, ATOMIC, MOLECULAR & CHEMICAL | CHEMISTRY, PHYSICAL | BASIS-SETS | OXIDATION-PRODUCTS | PARTICLE FORMATION | MOLECULAR-FORCE FIELD
Journal Article
Tetrahedron Letters, ISSN 0040-4039, 08/2017, Volume 58, Issue 34, pp. 3341 - 3343
[Display omitted] •Rapid access to enantioenriched spirocycles possessing a 1,4-dicarbonyl moiety spanning an all-carbon quaternary stereogenic spirocenter was... 
Allylic alkylation | Spirocycle | Masked bromomethyl vinyl ketone | Palladium catalysis | Asymmetric catalysis | SCOPE | CONSTRUCTION | CHEMISTRY, ORGANIC | N-HETEROCYCLES | MOLECULES | Palladium | Synthesis | Catalysis | Enantiomers | Organic compounds
Journal Article
The Journal of Organic Chemistry, ISSN 0022-3263, 06/2018, Volume 83, Issue 11, pp. 5954 - 5968
A general protocol is described for inducing enantioselective halolactonizations of unsaturated carboxylic acids using novel bifunctional organic catalysts... 
KIBDELONE C | OLEFINIC ACIDS | ASYMMETRIC BROMOLACTONIZATION | GYPSY-MOTH | AMINO-THIOCARBAMATE CATALYST | CHEMISTRY, ORGANIC | DESYMMETRIZING BROMOLACTONIZATION | NUCLEOPHILIC ORGANOCATALYSTS | ELECTROPHILIC BROMINE | TETRAHYDROPYRAN SYSTEMS | CARBOXYLIC-ACIDS
Journal Article
Angewandte Chemie (International ed.), ISSN 1433-7851, 2017, Volume 56, Issue 38, pp. 11545 - 11548
The first highly enantioselective iridium‐catalyzed allylic alkylation that provides access to products bearing an allylic all‐carbon quaternary stereogenic... 
iridium | quaternary stereocenter | carboxylic acid derivatives | allylic alkylation | umpolung | SUBSTITUTION | REAGENTS | CHEMISTRY, MULTIDISCIPLINARY | CARBON STEREOGENIC CENTERS | DIASTEREO | ORIGINS | STEREOCENTERS | CONSTRUCTION | ESTERS | REGIO | ARYL
Journal Article
Tetrahedron, ISSN 0040-4020, 09/2015, Volume 71, Issue 37, p. 6361
Recent studies of diastereoselective conjugate additions of monoorganocuprates, Li[RCuI], to chiral γ-alkoxycrotonates and fumarates are disclosed. This... 
Journal Article
Synlett, ISSN 0936-5214, 12/2018, Volume 29, Issue 19, pp. 2481 - 2492
Abstract Our lab has long been interested in the development of methods for the creation of enantioenriched all-carbon quaternary stereocenters. Historically,... 
account | iridium | asymmetric catalysis | quaternary stereocenters | allylic alkylation | umpolung | enantioselective | ACID DERIVATIVES | ASYMMETRIC-SYNTHESIS | ENANTIO | MASKED ACYL CYANIDES | PHOSPHORAMIDITE LIGANDS | CHEMISTRY, ORGANIC | ENANTIOSELECTIVE CONSTRUCTION | DIASTEREO | ESTERS | REGIO
Journal Article
Angewandte Chemie (International ed. in English), ISSN 1433-7851, 9/2017, Volume 56, Issue 38, pp. 11545 - 11548
The first highly enantioselective iridium-catalyzed allylic alkylation providing access to products bearing an allylic all-carbon quaternary stereogenic center... 
Quaternary Stereocenter | Umpolung | Carboxylic Acid Derivatives | Allylic Alkylation | Iridium
Journal Article
Tetrahedron letters, ISSN 0040-4039, 04/2013, Volume 54, Issue 16, pp. 2074 - 2076
A diastereoselective conjugate addition of a variety of monoorganocuprates, Li[RCuI], to chiral fumarates to provide funtionalized succinates has been... 
Total Synthesis | Chiral Auxiliary | Conjugate addition | Succinate | Butyrolactone
Journal Article
Proceedings of the National Academy of Sciences - PNAS, ISSN 0027-8424, 08/2018, Volume 115, Issue 33, pp. 8301 - 8306
Dimeric compounds contribute significantly to the formation and growth of atmospheric secondary organic aerosol (SOA) derived from monoterpene oxidation.... 
secondary organic aerosol | synergistic oxidation | atmospheric accretion chemistry | Physical Sciences | dimer formation | monoterpenes
Journal Article