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Angewandte Chemie International Edition, ISSN 1433-7851, 05/2019, Volume 58, Issue 22, pp. 7357 - 7360
The reaction of the halocarbyne [W(≡CBr)(CO)2(Tp*)] (Tp*=hydrotris(3,5‐dimethylpyrazol‐1‐yl)borate) with trimethylsilyl‐butadiyne, mediated by [Pd(PPh3)4] and... 
polymetallic species | carbon wires | pentadiynylidyne | tungsten | carbynes | CARBON CHAINS | CARBYNE LIGANDS | STRUCTURAL-ANALYSIS | TUNGSTEN COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | BRIDGING CARBENE | ONE-DIMENSION | POLYNUCLEAR METAL-COMPLEXES | BIS(TRICARBIDO) COMPLEX | ALKYLIDYNE COMPLEXES | TRICARBIDO COMPLEXES | Borates
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2018, Volume 54, Issue 87, pp. 12373 - 12376
Sequential treatment of [M(CBr)(CO)2(Tp*)] (M = Mo, W; Tp* = hydrotris(dimethylpyrazolyl)borate) with nBuLi, RPCl2 and LiCCSiMe3 affords... 
Journal Article
Chemical Communications, ISSN 1359-7345, 10/2019, Volume 55, Issue 82, pp. 12400 - 12403
Reactions of the lithiocarbyne [W]CLi ([W] = W(CO)2(Tp*); Tp* = tris(dimethylpyrazolyl)borate) with divalent platinum complexes [PtCl(terpy)]PF6,... 
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 06/2019, Volume 58, Issue 24, pp. 8044 - 8048
The lithiocarbyne [W(≡CLi)(CO)2(Tp*)] (Tp*=hydrotris(3,5‐dimethylpyrazol‐1‐yl)borate) reacts with [PtCl2(L2)] (L2=1,5‐cyclo‐octadiene, norbornadiene) to... 
bis(carbyne)s | dicarbido ligands | polymetallic compounds | carbynes | carbido ligands | CARBON-MONOXIDE CLEAVAGE | CARBYNE LIGANDS | CHEMISTRY, MULTIDISCIPLINARY | RAY CRYSTAL-STRUCTURE | BRIDGING CARBENE | POLYNUCLEAR METAL-COMPLEXES | PERMETHYLTITANOCENE | CHEMISTRY | ALKYLIDYNE COMPLEXES | CLUSTER | PERMETALATED ETHENE | Borates | Dienes | Platinum | Spine
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 45, pp. 5708 - 5711
The sterically accessible carbide complex, (Cy3P)Cl3Ru?C-PtCl(py)(2), acts as a synthon for terminal and bridging carbide fragments that relocate to pincer and... 
DIMOLYBDENUM COMPLEXES | DONOR LIGANDS | OLEFIN METATHESIS REACTIONS | CARBON-ATOM TRANSFER | STRUCTURAL-CHARACTERIZATION | INTERSTITIAL CARBON | BOND FORMATION | RUTHENIUM | METAL CENTER | CHEMISTRY, MULTIDISCIPLINARY | AMMONIA FORMATION | Organic chemistry | Carbides
Journal Article
Chemical Communications, ISSN 1359-7345, 02/2019, Volume 55, Issue 12, pp. 1734 - 1737
The reaction of [Rh2(μ-C)Cl2(PPh3)4] with bis(diphenylphosphino)methane (dppm) affords the A-frame μ-carbido complex [Rh2(μ-C)Cl2(μ-dppm)2], halide metathesis... 
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 14, pp. 1702 - 1705
The tellurocarbonylates [M(CTe)(CO)(2)(Tp*)](-) (M = Mo, W; obtained from [M(equivalent to CBr)(CO)(2)(Tp*)] and Li2Te or [M(equivalent to CLi)(CO)(2)(Tp*)]... 
TELLURIUM | TE-125 | CHEMICAL-SHIFTS | MOLYBDENUM | CHEMISTRY | ALKYLIDYNE COMPLEXES | TELLUROFORMALDEHYDE | FORMALDEHYDE | CHEMISTRY, MULTIDISCIPLINARY | THIOCARBONYL | Tellurides | Intermetallic compounds | Oxidation
Journal Article
Chemical Communications, ISSN 1359-7345, 2018, Volume 54, Issue 87, pp. 12373 - 12376
Journal Article
Angewandte Chemie (International ed. in English), ISSN 1433-7851, 10/2019, Volume 58, Issue 43, pp. 15354 - 15357
Synthetic routes to dimetallated C carbon wires in which two metals are separated by a linear carbon chain involving terminal metal-carbon triple bonds are... 
Journal Article
CHEMICAL COMMUNICATIONS, ISSN 1359-7345, 07/2018, Volume 54, Issue 55, pp. 7649 - 7652
The synthesis and characterization of the first examples of bimetallic bis(alkylidynyl) arsines, [RAs{CRM(CO)(2)(Tp*)}(2)] (M = Mo, R = Ph, Me; M = W, R = Ph,... 
PHOSPHONIUM CARBYNE | PHOSPHONIOCARBYNE COMPLEXES | TP-ASTERISK | METHYLIDYNE COMPLEXES | CRYSTAL-STRUCTURE | CARBENE TUNGSTEN COMPLEXES | ALKYLIDYNE COMPLEXES | CARBYNE COMPLEXES | CHEMISTRY, MULTIDISCIPLINARY | COMPLETE SET | METAL-CARBON BONDS | Bimetals | Tungsten
Journal Article
Dalton Transactions, ISSN 1477-9226, 2019, Volume 48, Issue 7, pp. 2367 - 2376
The reactions of 1-tert butyl-5-thiotetrazole (Htt(tBu)) with Na[BH4] provides Na[H2B(tt(tBu))(2)] (Na[1]) or Na[HB(tt(tBu))(3)] (Na[2]) in refluxing THF or... 
H BOND | HYDRIDE MIGRATION | PALLADIUM COMPLEXES | BU-T | DATIVE SIGMA-BOND | TRIS(METHIMAZOLYL)BORANE COMPLEXES | METAL | AMBIPHILIC LIGAND | BORANE | POLYAZOLYL CHELATE CHEMISTRY | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 08/2019, Volume 48, Issue 31, pp. 11715 - 11723
The reaction of alkynylselenolatoalkylidynes [W(CSeCCR)(CO)(2)(Tp*)] (R = SiMe3, (SiPr3)-Pr-i, Ph, p-tolyl, Bu-t, CPh3, SiPh3, GePh3; Tp* =... 
POLYNUCLEAR METAL-COMPLEXES | FINE-STRUCTURES | CARBYNE LIGANDS | RAY CRYSTAL-STRUCTURES | CHEMISTRY | ALKYLIDYNE COMPLEXES | TUNGSTEN | BRIDGING CARBENE | GOLD BONDS | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Dalton Transactions, ISSN 1477-9226, 2018, Volume 47, Issue 29, pp. 9570 - 9574
The reaction of [RhCl(CS)(PPh3)2] with excess catecholborane affords the cumulenic carbido complex [Rh2(μ-C)Cl2(PPh3)4] which undergoes phosphine and halide... 
Substitution reactions | Rhodium compounds
Journal Article
Chemical Communications, ISSN 1359-7345, 2019, Volume 55, Issue 12, pp. 1734 - 1737
The reaction of [Rh2(μ-C)Cl2(PPh3)4] with bis(diphenylphosphino)methane (dppm) affords the A-frame μ-carbido complex [Rh2(μ-C)Cl2(μ-dppm)2], halide metathesis... 
Journal Article
DALTON TRANSACTIONS, ISSN 1477-9226, 05/2019, Volume 48, Issue 19, pp. 6596 - 6610
The reactions of [W(?CBr)(CO)(2)(Tp*)] (Tp* = hydrotris(dimethylpyrazolyl)borate) with a range of terminal alkynes (RC?CH), mediated by [Pd(PPh3)(4)] and CuI,... 
POLYNUCLEAR METAL-COMPLEXES | MOLYBDENUM | CARBYNE LIGANDS | BIS(TRICARBIDO) COMPLEX | TRANSITION-METAL | CHEMISTRY | ALKYLIDYNE COMPLEXES | TRICARBIDO COMPLEXES | TUNGSTEN COMPLEXES | BRIDGING CARBENE | CHEMISTRY, INORGANIC & NUCLEAR
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2019, Volume 58, Issue 43, pp. 15349 - 15353
The first examples of bi‐ and polynuclear tellurocarbonyl complexes were obtained from the reactions of [W(≡CTe)(CO)2(Tp*)]NEt4... 
carbyne | carbon chalcogenide | isocarbonyl | tellurocarbonyl | Technical education | Borates | Copper | Gold
Journal Article
Angewandte Chemie International Edition, ISSN 1433-7851, 10/2019, Volume 58, Issue 43, pp. 15354 - 15357
Synthetic routes to dimetallated Cx carbon wires in which two metals are separated by a linear carbon chain involving terminal metal–carbon triple bonds are... 
carbyne | tungsten | carbon | bis(carbyne) | Carbon | Metals | Carbyne | Molecular chains
Journal Article